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2261“…The methoxy group is coplanar with the attached benzene ring [C—O—C—C = 0.1 (2)°]. The molecule adopts a trans configuration with respect to the C=N double bond. …”
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2262“…One of the methoxy groups is coplanar with the attached benzene ring within 0.052 (3) Å, whereas the other is slightly twisted [C—O—C—C = 6.3 (3)°]. The molecule adopts a trans configuration with respect to the C=N bond. …”
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2263“…The OCHF(2) group is twisted away from the plane of the benzene ring, as shown by the C—O—C—C torsion angle of 145.8 (2)°. The conformation is stabilized by an intermolecular N—H⋯N hydrogen bond. …”
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2264por Caracelli, Ignez, Zukerman-Schpector, Julio, Singh, Fateh V., Stefani, Hélio A., Tiekink, Edward R. T.“…Two independent pseudo-enantiomeric molecules comprise the asymmetric unit in the title compound, C(15)H(14)O(2). While the central O—C—C—C residue approaches planarity [torsion angles = −15.8 (3) (molecule a) and 15.4 (3)° (molecule b)], the benzene rings are approximately orthogonal [the dihedral angles formed between the benzene rings are 62.89 (12) (molecule a) and 80.15 (12)° (molecule b)]. …”
Publicado 2010
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2265por Bera, Hriday, Dolzhenko, Anton V., Tan, Geok Kheng, Koh, Lip Lin, Chui, Wai Keung“…The molecular structure of the title compound, C(13)H(18)N(4)O(3)S, (systematic name: ethyl N-{2-[4-(dimethylamino)benzoyl]hydrazinethiocarbonyl}carbamate) is stabilized by intramolecular N—H⋯O=C hydrogen bonding arranged in an S(6) graph-set motif. …”
Publicado 2010
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2266por Shahani, Tara, Fun, Hoong-Kun, Sarveswari, S., Vijayakumar, V., Ragavan, R.Venkat“…The quinoline ring system and the ethoxyphenyl ring are oriented at dihedral angles of 79.5 (1) and 17.6 (3)°, respectively, with respect to the almost planar [r.m.s. deviation= 0.037 (3) Å] –C(=O)—C=C– linkage. In the crystal, the inversion-related molecules exist as C—H⋯O hydrogen-bonded R (2) (2)(8) dimers.…”
Publicado 2010
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2267“…The methoxyphenyl–amide segment of the molecule is almost planar, with a dihedral angle of 5.10 (7)° between the benzene ring and the C—N—C(O)—C fragment. A weak intramolecular N—H⋯O contact forms an S(5) ring and contributes to the planarity of this portion of the molecule. …”
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2268por Sharif, Shahzad, Akkurt, Mehmet, Khan, Islam Ullah, Salariya, Manan Ayub, Ahmad, Sarfraz“…Intermolecular C—H⋯S, N—H⋯O, C—H⋯O and O—H⋯O hydrogen-bonding interactions stabilize the crystal structure, forming a three-dimensional network. …”
Publicado 2009
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2269por Fun, Hoong-Kun, Suwunwong, Thitipone, Chantrapromma, Suchada, Karalai, Chatchanok“…The three methoxy groups are almost coplanar with their attached benzene ring [C—C—O—C torsion angles = 2.07 (17), −5.04 (17) and 2.85 (16)°]. …”
Publicado 2010
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2270por Fun, Hoong-Kun, Goh, Jia Hao, Das, Nirmal Kumar, Sen, Debabrata, Goswami, Shyamaprosad“…In the crystal structure, molecules are interconnected into sheets parallel to the ac plane by N—H⋯O, C—H⋯Br, C—H⋯O and C—H⋯N hydrogen bonds. The structure is further stabilized by weak intermolecular C—H⋯π interactions.…”
Publicado 2010
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2271“…Successive chains are rotated by 90° around the c axis. One C—H⋯O=C close contact, involving the carboxyl group, exists.…”
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2272“…In the crystal, molecules are linked by N—H⋯N and N—H⋯O hydrogen bonds, generating a chain running the a axis. Weak C—H⋯O, C—H⋯N and C—H⋯π interactions are also observed.…”
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2273“…In the title complex, [Co(C(16)H(15)N(2)O)(C(10)H(9)O(2))(N(3))], the Co(II) atom adopts an octahedral coordination geometry by a tridentate Schiff base, a bidentate benzoylacetonate and an azide ligand. …”
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2274por Kim, Hee-Joon“…In the crystal, molecules are linked into dimers via N—H⋯O=C hydrogen bonds. These dimers are packed through π⋯π interactions between neighboring pyrrole rings with a separation between the mean planes of symmetry-related pyrrole rings of 3.61 (2) Å and a centroid–centroid distance of 4.33 Å. …”
Publicado 2010
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2275“…The dihedral angles between the coumarin ring system, the phenyl ring and the C=N—O—C plane of the oxime unit are 35.83 (6), 35.8 (2) and 69.99 (15)°, respectively. …”
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2276“…The packing is stabilized by C—H⋯O, C—H⋯N, weak π–π stacking [centroid–centroid distances = 3.7985 (16) and 3.7662 (17) Å] and C—H⋯π interactions.…”
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2277“…The V(V) atom in the title compound, [V(C(8)H(9)N(2)O)(C(17)H(14)N(2)O(3))O]·CH(3)OH, is N,O-chelated by the benzoylhydrazidate anion and O,N,O′-chelated by the (benzoylhydrazono)propionate dianion. …”
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2278“…In the crystal, the water molecule links the molecules into chains through O—H⋯N hydrogen bonds. Weak N—H⋯O, C—H⋯N and C—H⋯O interactions further stabilize the crystal structure.…”
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2279“…The four-atom –O–CH(2)–C(=O)–O– linkage between the aromatic ring and the tert-butyl group assumes a (−)anti-periplanar conformation for one substituent and a (−)syn-periplanar conformation for the other substituent; the O–C–C–O torsion angles are −173.7 (2) and −10.2 (3)°.…”
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2280“…The four-atom –O–CH(2)–C(=O)–O– chain between the p-phenylene ring and the tert-butyl group assumes a more regular W-shaped conformation for one substituent [O—C—C—C torsion angle = 171.9 (2)°] but a less regular W-shaped conformation for the other [torsion angle = 147.4 (2)°].…”
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