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2281por Viji, A. J., Sarveswari, S., Vijayakumar, V., Tan, Kong Wai, Tiekink, Edward R. T.“…Further, the chalcone residue is approximately perpendicular to the quinolinyl residue [C(q)—C(q)—C(c)—O(c) torsion angle = −104.5 (3)°, where q = quinolinyl and c = chalcone]. …”
Publicado 2010
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2282por Khan, F. Nawaz, Roopan, S. Mohana, Kumar, Rajesh, Hathwar, Venkatesha R., Akkurt, Mehmet“…In the crystal, molecules are interlinked by weak C—H⋯O, C—H⋯π and π–π stacking [centroid–centroid distances = 3.7453 (10) and 3.7557 (9) Å] interactions.…”
Publicado 2010
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2283por Mitsui, Ryosuke, Nagasawa, Atsushi, Watanabe, Shoji, Okamoto, Akiko, Yonezawa, Noriyuki“…In each molecule, an intramolecular O—H⋯O=C hydrogen bond generates a six-membered ring. …”
Publicado 2010
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2284por Jasinski, Jerry P., Braley, Adam N., Samshuddin, S., Narayana, B., Yathirajan, H. S.“…These groups are slightly twisted around the ethoxymethane unit [C—C—O—C torsion angle = 177.64 (15)°]. The crystal packing is stabilized by N—H⋯O, O—H⋯N and O—H⋯O hydrogen-bond interactions involving the water molecules. …”
Publicado 2010
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2285por Ray, Jayanta Kumar, Barman, Gopa, Canle L., M., Fernández P., M. I., Santaballa, J. A.“…In the title compound, C(23)H(25)NO(5), the lactam ring adopts an envelope conformation and both ethoxycarbonyl side chains show an s-cis conformation: one is nearly planar, the dihedral angle between CO(2) and OCH(2)CH(3) groups being 7.95 (14)° and the other is almost orthogonal, the C—O—C—C torsion angle being 85.33 (9)°. Dimers related by inversion symmetry are stabilized by C—H⋯O hydrogen bonds. …”
Publicado 2010
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2286“…The crystal structure is stabilized by N—H⋯O, C—H⋯O and C—H⋯Cl hydrogen bonds and π–π stacking interactions [centroid–centroid distance = 3.5469 (16) Å] between the pyridyl and benzene rings. …”
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2287por Trigunait, Ankur, Malathy, P., Ramachandiran, K., Perumal, P. T., Gunasekaran, K.“…The indole ring system is planar within 0.021 (2) Å and the ester group [–C(=O)—O—C–] is almost coplanar with it [dihedral angle = 3.0 (2)°]. …”
Publicado 2010
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2288“…In the title complex, [Ni(C(27)H(27)N(7))(C(3)H(7)NO)(H(2)O)](C(6)H(2)N(3)O(7))(2), the Ni(II) ion is coordinated in a slightly distorted octahedral coordination evironment by an NiN(4)O(2) ligand set. …”
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2289por Sachdeva, Nikhil, Dolzhenko, Anton V., Tan, Geok Kheng, Koh, Lip Lin, Chui, Wai Keung“…The amino group adopts a trigonal-planar configuration and forms an intramolecular resonance-assisted N—H⋯O=C hydrogen bond with the carbonyl group. In the crystal, molecules are linked via intermolecular N—H⋯N hydrogen bonds into chains of C (2) (2)(6)[R (2) (2)(6)] motif. …”
Publicado 2010
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2290“…The two Sn—O—C—C—C—O chelate rings in the title compound, [Sn(C(15)H(11)O(2))(2)Cl(2)]·0.5C(7)H(8), adopt envelope conformations, with the Sn atom deviating from the least-squares plane passing through the C and O atoms by 0.626 (1) Å in one ring and by 0.690 (1) Å for the other. …”
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2291por Nasir, Shah Bakhtiar, Abdullah, Zanariah, Fairuz, Zainal A., Ng, Seik Weng, Tiekink, Edward R. T.“…The –NO(2) [O—N—C—C = −26.1 (3)°] and –OMe [C—O—C—C = 166.5 (2)°] substituents are not coplanar with their respective aromatic rings. …”
Publicado 2010
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2292“…In the title chalcone [systemetic name 1-(2,4-dimethoxyphenyl)-3-(3,4,5-trimethoxyphenyl)prop-2-en-1-one], C(20)H(22)O(6), the dihedral angle between the plane of the two benzene rings is 7.03 (4)° with all but one of the methoxy groups essentially co-planar with these rings [C—C—O—C torsion angles = −76.1 (2), −0.7 (3), 1.8 (3), −6.2 (3), 2.0 (3)°]. …”
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2293“…The crystal packing is stabilized by O—H⋯O, C—H⋯π and π–π interactions [centroid–centroid distance = 3.664 (11) Å]. …”
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2294por Kato, Yuichi, Nagasawa, Atsushi, Kataoka, Kotaro, Okamoto, Akiko, Yonezawa, Noriyuki“…The bridging carbonyl C—C(=O)—C plane makes dihedral angles of 47.07 (6)° with the naphthalene ring system and 24.20 (10)° with the benzene ring. …”
Publicado 2010
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2295“…In the title molecular salt, C(8)H(13)N(2)O(+)·C(7)H(3)N(2)O(7) (−)·H(2)O, the pyrimidinium cation is essentially planar, with a maximum deviation of 0.009 (1) Å. …”
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2296por Shahani, Tara, Fun, Hoong-Kun, Ragavan, R. Venkat, Vijayakumar, V., Sarveswari, S.“…The pyrazolone and water molecules are further linked by intermolecular N—H⋯O, C—H⋯O and O—H⋯O hydrogen bonds into two-dimensional sheets parallel to the bc plane.…”
Publicado 2010
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2297“…In the crystal, pairs of molecules are interconnected by pairs of Cl⋯Cl interactions [3.564 (5) Å], forming dimers, which are further peripherally connected through intermolecular C—H⋯O=C and π–π interactions [centroid–centroid distances = 4.134 (7), 4.134 (6) and 4.238 (7) Å], forming a two-dimensional network.…”
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2298“…A one-dimensional structure is formed by π–π intermolecular interactions and a supramolecular aggregation is determined by intermolecular C—H⋯O, C—H⋯Cl, C—H⋯π(arene) hydrogen bonds and CO⋯π(arene) interactions [O⋯centroid distances = 3.485 (4) and 3.722 (3) Å].…”
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2299por Dutkiewicz, Grzegorz, Narayana, B., Veena, K., Yathirajan, H. S., Kubicki, Maciej“…In the crystal, weak intermolecular C—H⋯O, C—H⋯F and C—H⋯π interactions join molecules into a three-dimensional structure.…”
Publicado 2011
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2300“…The near coplanarity of the aromatic ring, the amide group and the carbonyl group of the butanoyl fragment [N—C—C—C = −179.65 (17) and O—C—C—C = −178.34 (17)°] results from the intramolecular O—H⋯O and C—H⋯O hydrogen bonds. …”
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