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2681“…In the neutral title compound, [Re(C(6)H(5)NO)(C(13)H(9)NO(2))(CH(3)O)(C(18)H(15)P)], an 18-valence-electron complex, the Re(V) ion lies in an octahedral coordination geometry with the tridentate dianionic Schiff base 2-(2-oxidobenzylideneamino)phenolate ligand occupying three equatorial coordination sites, and with the triphenylphosphine ligand situated trans to the imine N atom. …”
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2682“…The crystal structure is governed by C—H⋯O, C—H⋯Br and Zn—Br⋯Cg(π-ring) interactions.…”
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2683“…Two N atoms and the Cl atom are in equatorial positions while the remaining two N atoms occupy apical sites, the equatorial Cu—N bonds being significantly longer than the two apical Cu—N bonds. The N=C—O—C torsion angles involving the four ethoxy groups are in the range 161.5 (8) to 177.0 (5)°. …”
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2684“…In the crystal packing, molecules are linked into supramolecular chains via weak C—H⋯O, C—H⋯N and C—H⋯S interactions, and C—H⋯π and N—O⋯π links also occur.…”
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2685por Yalçın, Şerife Pınar, Akkurt, Mehmet, Jarrahpour, Aliasghar, Ebrahimi, Edris, Büyükgüngör, Orhan“…In the title isomer, the methoxy group is slightly twisted out of the plane of the attached benzene ring, with a C—O—C—C torsion angle of 31.5 (2)°. Its β-lactam ring is essentially planar, with a maximum deviation of −0.021 (1) Å. …”
Publicado 2009
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2686“…In the crystal structure, there are no classical hydrogen bonds: interactions comprise a short C(6)—H⋯π(C(6)) interaction involving substituted benzene rings and two C—H⋯O=C interactions per molecule.…”
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2687por Chantrapromma, Suchada, Suwunwong, Thitipone, Karalai, Chatchanok, Fun, Hoong-Kun“…The three methoxy groups are oriented in two different conformations whereby two methoxy groups are coplanar, whereas the third is twisted with respect to the attached benzene ring [C—O—C—C torsion angles of −2.84 (18), −2.80 (18) and −9.31 (18)°]. …”
Publicado 2009
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2688por Suwunwong, Thitipone, Chantrapromma, Suchada, Pakdeevanich, Paradorn, Fun, Hoong-Kun“…The three methoxy groups have two different conformations; two methoxy groups are coplanar [C—O—C—C torsion angles = −1.38 (12) and 0.47 (12)°] whereas the third is (-)-synclinal with the benzene ring. …”
Publicado 2009
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2689por Narendra Babu, Shivanagere Nagojappa, Abdul Rahim, Aisyah Saad, Abd Hamid, Shafida, Jebas, Samuel Robinson, Fun, Hoong-Kun“…The crystal packing is further strengthened by short intermolecular O⋯O=C [2.655 (4) Å] contacts.…”
Publicado 2009
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2690“…In the crystal structure, intermolecular N—H⋯O, C—H⋯O and C—H⋯F interactions link the molecules into chains. π–π contacts between the quinoline and benzene rings [centroid–centroid distance = 3.918 (3) Å] may further stabilize the structure. …”
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2691por Parrish, Damon, Tivitmahaisoon, Parcharee, Rehberg, Gretchen M., Kastner, Margaret E.“…The crystal structure also has short Br⋯O=C intermolecular contacts with distances of 2.843 (4) and 2.852 (4) Å.…”
Publicado 2009
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2692por Kurochkina, Nadezhda M., Kuzovlev, Andrey S., Puryaeva, Tamara P., Velikodny, Yurii A., Chernyshev, Vladimir V.“…The cations are associated into columns along the a axis through π–π interactions between the pyridine and benzene rings, with a centroid–centroid distance of 3.72 (5) Å. Intermolecular O—H⋯O, C—H⋯O and C—H⋯F hydrogen bonds consolidate the crystal packing.…”
Publicado 2009
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2693por Zhang, Zheyu“…In the title compound, {[Ag(C(10)H(14)N(4))(H(2)O)](C(14)H(8)O(4))(0.5)·2H(2)O}(n), the Ag(I) ion is three-coordinated by two N atoms from two independent 1,1′-(butane-1,4-diyl)di-1H-imidazole (BBI) ligands and one water O atom in a distorted T-shaped coordination geometry. …”
Publicado 2009
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2694por Gurbanov, Atash V., Nikitina, Eugeniya V., Sorokina, Elena A., Zubkov, Fedor I., Khrustalev, Victor N.“…The dispositions of the carboxylate substituents relative to each other are determined by both steric reasons and intermolecular C—H⋯O hydrogen bonding and attractive antiparallel C=O⋯C=O interactions [C⋯O = 2.995 (2) Å].…”
Publicado 2009
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2695“…The structure is held together by van der Waals forces [electrostatic interactions between dipoles, O⋯C = 3.002 (2) Å] between molecules and by weak π–π stacking between symmetry-related molecules, with an interplanar distance of 3.579 Å and a centroid–centroid distance of 3.800 (1) Å. …”
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2696“…The asymmetric unit of the title polymeric complex, {[Sn(2)=(C(6)H(5))(6)(C(3)H(2)O(4))(H(2)O)]·C(3)H(6)O}(n), comprises of two Sn cations, one malonate anion and a non-coordinating acetone solvent molecule. …”
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2697“…In the structure of the title compound, 2[Ag(C(10)H(8)N(2))(H(2)O)](C(7)H(6)NO(2))(NO(3))·H(2)O, the Ag(I) atom is three-coordinated in a T-shaped configuration by two N atoms from two symmetry-related 4,4′-bipyridine (bipy) ligands at short distances and by one water O atom at a longer distance. …”
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2698por Novaković, Sladjana B., Drašković, Bojana M., Vojinović-Ješić, Ljiljana S., Češljević, Valerija I., Leovac, Vukadin M.“…These components are interconnected in the crystal structure by an extensive network of O—H⋯O, N—H⋯O, C—H⋯O, O—H⋯N, O—H⋯Cl, N—H⋯Cl and C—H⋯Cl hydrogen bonds. …”
Publicado 2010
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2699por Fun, Hoong-Kun, Hemamalini, Madhukar, Shetty, Divya N., Narayana, B., Yathirajan, H. S.“…In the crystal structure, cations and anions are connected by intermolecular N—H⋯O, O—H⋯O, C—H⋯O and C—H⋯F hydrogen bonds, forming a three-dimensional network. …”
Publicado 2010
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2700por Watanabe, Shoji, Nakaema, Kosuke, Nishijima, Takahiro, Okamoto, Akiko, Yonezawa, Noriyuki“…The dihedral between the naphthalene ring system and the bridging carbonyl C—C(=O)—C plane is 54.68 (6)°, far larger than that [12.54 (7)°] between the phenyl group and the bridging carbonyl group. …”
Publicado 2010
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