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2761“…The hydroxy and methoxy substituents are coplanar with the benzene ring to which they are attached, with an r.m.s. deviation of 0.0116 (3) Å for the nine non-H atoms [C(methyl)—O—C—C torsion angle = −0.8 (4)°]. In the crystal, the cations and anions are stacked by π–π interactions, with centroid–centroid distances of 3.7818 (19) and 3.9004 (17) Å. …”
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2762
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2763“…It was shown to form compact polar C(2)-symmetric dimers with intermolecular O–H⋅⋅⋅O=C bonds, while sacrificing the corresponding intramolecular hydrogen bonds. …”
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2764por Kim, Tae-Hee, Lee, Hae-Hyeog, Kim, Jun-Mo, Ryu, Ae-Li, Chung, Soo-Ho, Seok Lee, Woo“…For two cases, UAE complication was associated with fever (>38.5(o)C). Five patients had problems that required admission to the intensive care unit (ICU). …”
Publicado 2013
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2765“…To this end, we have quantum chemically investigated the competition between elimination and substitution pathways in H(2)O+C(2)H(5)OH(2)(+) and OH(−)+C(2)H(5)OH, that is, two related model systems that represent, in a generic manner, the same reaction under acidic and basic conditions, respectively. …”
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2766“…Each glucose unit in a cellulose chain is joined to the next by a covalent C–O–C linkage flanked by two hydrogen bonds. This geometry suggests some form of cooperativity between covalent and hydrogen bonding. …”
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2767por Chantrapromma, Suchada, Boonnak, Nawong, Horkaew, Jirapa, Quah, Ching Kheng, Fun, Hoong-Kun“…All methoxy substituents lie close to the plane of the attached benzene rings [the C(methyl)—O—C—C torsion angles range from −4.0 (12) to 3.9 (2)°]. …”
Publicado 2014
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2768“…However, the imide unit itself is not planar, the dihedral angle between the two O=C—N components being 34.6 (1)°. The dihedral angle between the two chlorobenzene rings is 40.50 (7)°, while the angles between these rings and the imide moiety are 54.6 (1) and 58.2 (1)°, respectively. …”
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2769por Xiao, Zeyun, Sun, Kuan, Subbiah, Jegadesan, Ji, Shaomin, Jones, David J., Wong, Wallace W. H.“…The amide containing small molecule can form intermolecular hydrogen bonding between N-H…O = C of the amide group. The photovoltaic properties and active layer morphologies of the two molecules in bulk heterojunction solar cells are compared to study the influence of hydrogen bonding on the active layer morphology. …”
Publicado 2014
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2770por Guo, Mengzhe, Pan, Youlu, Zhang, Rong, Cao, Yang, Chen, Jianzhong, Pan, Yuanjiang“…With the help of this hydrogen bond interaction, the ring structure preferentially opens in lactone linkage rather than O-C bond of the ester-group to produce alcohol and ketene. …”
Publicado 2014
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2771por Khosravi Zanjani, Mohammad Ali, Ghiassi Tarzi, Babak, Sharifan, Anousheh, Mohammadi, Nima“…In this study Lactobacillus casei (ATCC 39392) and Bifidobacterium bifidum (ATCC 29521) were encapsulated using calcium alginate-gelatinized starch, chitosan coating and inulin via emulsion technique, and were incubated in simulated gastric juice (along with pepsin, pH=1.5) and simulated intestinal juice (along with pancreatin and bile salts, pH = 8) for 2 hours at 37 (o)C. The morphology and size of microcapsules were measured by scanning electron and optical microscopy. …”
Publicado 2014
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2772“…The results indicated that modification process caused lower micropore quantity and volume capacity of semicoke; the C-Cl functional groups, C=O bond and delocalized electron π on the surface of Cl-SC, the amorphous higher valency Mn(x+), and O=C–OH functional groups on the surface of Mn-H-SC were the active sites for oxidation and adsorption of gaseous Hg(0). …”
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2773“…The methoxy substituents lie close to the plane of the attached benzene rings. The C(ar)—C(ar)—O—C(Me) torsion angles are −2.4 (7) and 7.5 (6)°. …”
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2774por MACHADO, Adriana Gadotti, KOMIYAMA, Edson Yukio, dos SANTOS, Silvana Soléo Ferreira, JORGE, Antonio Olavo Cardoso, BRIGHENTI, Fernanda Lourenção, KOGA-ITO, Cristiane Yumi“…Suspensions of C. albicans (10(6) cells/mL) and epithelial cells (10(5) cells/mL) were mixed and incubated at 37ºC for 1 h. The number of yeasts adhered to 25 epithelial cells was counted. …”
Publicado 2011
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2775por Estrada-Soto, Samuel, Sánchez-Recillas, Amanda, Navarrete-Vázquez, Gabriel, Tlahuext, Hugo“…Similarly, the coumarin ring system and the 7-propoxy substituent are close to being coplanar [C—C—O—C torsion angles = 2.9 (2) and 1.4 (2)° for molecules A and B, respectively]. …”
Publicado 2014
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2776“…The mechanism for the high sensitivity of the photodetectors has been attributed to the enhanced carrier-separation at the ZnO/C interface.…”
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2777“…In the title compound, C(21)H(16)ClN(3)O(2), the pyrazolone ring and the O=C—C=C—N mean plane [maximum deviation = 0.022 (2) Å] are nearly coplanar, making a dihedral angle 4.56 (8)°, while the phenyl and pyrazole rings subtend a dihedral angle of 19.75 (8)°. …”
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2778“…The title compound, C(12)H(11)NO(3), is essentially planar, with the mean plane of the acetate side chain [–C—C(=O)—O—C] being inclined to the mean plane of the indole ring system by 12.49 (7)°. …”
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2779por Mohamed, Shaaban K., Mague, Joel T., Akkurt, Mehmet, Abdu-Allah, Hajjaj H. M., Albayati, Mustafa R.“…These dimers are linked to the B molecules via N—H.·O, C—H⋯O and C—H⋯S hydrogen bonds forming corrugated sheets lying parallel to (102).…”
Publicado 2015
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2780“…The microbial analysis showed that Moringa oleifera did not negatively affect the growth of Lactobacillus rhamnosus GR-1 in MRS, milk or yogurt, although a significant decrease was found after 5 weeks of storage at 4 (o)C.…”
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