“…Intriguing chemical properties and reactions were observed for the C(20)-diterpenoid alkaloids: (a) specific selective nucleophilic addition of the carbonyl (C-12) in 1 with CD(3)OD; (b) interconversion between 1 and 2 in D(2)O; (c) stereo- and/or regioselective deuterations of H-11α in 1–3 and both H-11α and H-11β in aconicarmisulfonine A (4); (d) TMSP-2,2,3,3-d(4) promoted cleavage of the C-12−C-13 bond of 4 in D(2)O; (e) dehydrogenation of 4 in pyridine-d(5), and (f) Na(2)SO(3)-assisted dehydrogenation and N-deethylation of songorine (5, a putative precursor of 1–4). …”
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“…In contrast, an increase of the atomic O/C ratio in RB, 0.51 delineated high breakdown of the cellulosic component, which is favorable for biofuel purpose. 13.98% SiO(2) reduction in RB confirmed ash content minimization and better quality of fuel properties. …”
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“…In the classical optimization yeast peptone dextrose medium, inoculum size of two discs, incubation period of 6 days, production temperature of 25 ºC and pH 7 was best supportive for optimal growth and antimicrobial activity whereas maltose and ammonium nitrate were the best carbon and nitrogen sources, respectively. …”
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“…Here the albite-omphacite assemblage is in local equilibrium at least on 1 mm length scale, during cooling, below ~ 600 ºC and ~ 1 GPa, within the amphibolite facies conditions. …”
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“…After extrusion, kibbles were dried at 115.5 ºC to less than 10% moisture. Dried kibbles were coated with chicken fat and flavor enhancer. …”
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“…The color of each restoration was measured using a portable digital spectrophotometer (Easyshade-Vita) according to the CIELab system, and then the teeth were submerged in red wine for 07 days, kept in a biological oven at 37ºC. New color registration was performed to measure the ΔE index of color variation. …”
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“…In this case, several parameters of occipito-cervical alignment such as the occipito-C2 angle (O-C2 angle), swallowing line (S-line), C2-C7 angle, and pharyngeal inlet angle, which are recognized as predictors of postoperative dysphagia after occipito-cervical fusion surgery, were adequate to prevent postoperative dysphagia. …”
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“…The beginning of thermal decomposition took a place at lower temperature ca. 30 ºC) and lower rate than the MDI-PU based materials. …”
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“…The inter­molecular N—H⋯O, C—H⋯O/F hydrogen bonds of the complex form a network structure, which looks like a seamless floral lace pattern.…”
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“…The complexes [L(tBu)Ni(OCO‐κ (2) O,C)]M(3)[N(SiMe(3))(2)](2) (M=Li, Na, K), synthesized by deprotonation of a nickel formate complex [L(tBu)NiOOCH] with the corresponding amides M[N(SiMe(3))(2)], feature a Ni(II)−CO(2) (2−) core surrounded by Lewis‐acidic cations (M(+)) and the influence of the latter on the behavior and reactivity was studied. …”
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“…The XPS spectrum of the as-prepared composites confirmed the presence of Fe-O-C bonds between β-FeOOH and biochar, which could be conducive to transfer photo-generated electrons. …”
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“…Results showed that recombinant ToxA was overexpressed in soluble fraction at 37(o)C with 1mM IPTG. Purification by affinity chromatography was able to isolate recombinant ToxA with the purity up to 94.49%. …”
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“…By combining the concept of “coordination sphere engineering”, relying on bulky quinoline donors, with reversible photoswitching between the ligand’s open (o-L(a)) and closed (c-L(a)) forms, a [Pd(2)(o-L(a))(4)] cage (o-C) and a [Pd(2)(c-L(a))(3)] bowl (c-B) were obtained, respectively. …”
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“…X‐ray analysis revealed the presence of various non‐covalent interactions including I ⋅⋅⋅ I, I ⋅⋅⋅ N, N−H ⋅⋅⋅ O, C−H ⋅⋅⋅ O, and H−C ⋅⋅⋅ H−C contacts. The preference of halogen bonding (I ⋅⋅⋅ I or I ⋅⋅⋅ N) in BCP 1–4 strictly depends upon the electronic nature and angle between bridgehead substituents. …”
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“…In general, successful low-temperature cell preservation consists of the addition of a CPA (commonly 10% DMSO), alone or in combination with additional permeating or non-permeating agents, cooling rates of approximately 1ºC/min, and storage in either liquid or vapor phase nitrogen. …”
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“…Furthermore, the antifungal activities were assessed by the presence or absence of inhibition zones after the plates were incubated at 28(o)C for 7 days. RESULTS: F3 has the greatest inhibitory power than F1 and F2 (P < 0.05). …”
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“…She came to our emergency department complaining of back pain, myalgia, asthenia, and a fever of 40.2ºC. No other symptoms were noted upon her admission. …”
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“…The neurofibroma was resected by durotomy and intradural neurofibromas were extirpated through O-C6 laminectomy. Anterior fusion with VFG was performed 6 months later, and bone union was confirmed after 4 months. …”
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“…There are seven viral serotypes of foot-and-mouth disease virus (FMDV): A, O, C, Asia 1, and Southern African Territories 1, 2, and 3 (SAT 1–3). …”
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