“…Three new Schiff bases of N-substituted isatin L(I), L(II,) and L(III) = Schiff base of N-acetylisatin, N-benzylisatin, and N-benzoylisatin, respectively, and their metal complexes C(1a,b) = [Co(2)(L(I))(2)Cl(3)]Cl, C(2) = [Ni(L(I))(2)Cl(2)]0.4BuOH, C(3) = [CuL(I)Cl(H(2)O)]Cl ⋅ 0.5BuOH, C(4) = [Pd(L(I))(2)Cl]Cl, C(5) = [Pt(L(1))(2)Cl(2)]Cl(2) ⋅ 1.8EtOH.H(2)O, C(6a) = [CoL(II)Cl]Cl ⋅ 0.4H(2)O ⋅ 0.3DMSO, C(6b) = [CoL(II)Cl]Cl ⋅ 0.3H(2)O ⋅ 0.1BuOH, C(7) = [NiL(II)Cl(2)], C(8) = [CuL(II)]Cl(2) ⋅ H(2)O , C(9) = [Pd(L(II))(2)]Cl(2), C(10) = [Pt(L(II))(2.5)Cl]Cl(3), C(11a) = [Co(L(III))]C(12) ⋅ H(2)O, C(11b) = [Co(L(III))]Cl(2) ⋅ 0.2H(2)O, and C(12) = [Ni(L(III))(2)]Cl(2), C(13) = [Ni(L(III))(2)]Cl(2) were reported. …”
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“…Here, we show that the heat stress (HS) used to inactivate ts alleles (25 ºC to 37 ºC shift) causes rDNA loop condensation in metaphase-arrested wild type cells, a result that can also be mimicked by other stresses that inhibit the TORC1 pathway. …”
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“…HGP was also induced by 8CPT‐cAMP, 8CPT‐2‐Methyl‐O‐cAMP and NBMPR; however, in each case this was resistant to suppression by AICAR but not by metformin. …”
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“…However, we found that Ae. albopictus could survive for several hours’ exposure to -9 to -19 (o)C so long as it was exposed with water. Median lethal time (LT(50)) of Ae. albopictus exposed to -15 and -19 (o)C with water increased by more than 100 times compared to those exposed to the same subzero temperature without water. …”
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“…In each of the salts, i.e., C(11)H(17)N(2)O(+)·C(7)H(3)N(2)O(6) (−), (II), C(11)H(17)N(2)O(+)·C(6)H(2)N(3)O(7) (−), (III), and C(11)H(17)N(2)O(+)·C(7)H(6)NO(2) (−)·H(2)O, (IV), the effectively planar 4-meth­oxy­phenyl substituent again occupies an equatorial site on the piperazine ring. …”
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“…Crystal structures for a series of bis­(acetyl­acetonato)oxovanadium(IV) complexes containing N-donor pyridyl ligands are reported, namely, bis­(acetyl­acetonato-κ(2) O,O′)oxido(pyridine-κN)vanadium(IV), [V(C(5)H(7)O(2))(2)O(C(5)H(5)N)], 1, bis­(acetyl­acetonato-κ(2) O,O′)oxido(pyridine-4-carbo­nitrile-κN)vanadium(IV), [V(C(5)H(7)O(2))(2)O(C(6)H(4)N(2))], 2, and bis­(acetyl­acetonato-κ(2) O,O′)(4-meth­oxy­pyridine-κN)oxidovanadium(IV), [V(C(5)H(7)O(2))(2)O(C(6)H(7)NO)], 3, Compounds 1–3 have the formulae VO(C(5)H(7)O(2))(2) L, where L = pyridine (1), 4-cyano-pyridine (2), and 4-meth­oxy­pyridine (3). …”
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“…The crystal structures of sorafenib hydrochloride trihydrate (Sor·HCl.3H(2)O), 4-(4-{3-[4-chloro-3-(trifluoro-methyl)phenyl]ureido}phenoxy)-2-(N-methylcarbamoyl) pyridinium hydrochloride trihydrate, C(21)H(17)ClF(3)N(4)O(3)(+)·Cl(−).3H(2)O (I), sorafenib hydrochloride monohydrate (Sor·HCl.H(2)O), C(21)H(17)ClF(3)N(4)O(3)(+)·Cl(−).H(2)O (II), its solvated form (sorafenib hydrochloride monohydrate monotetrahydrofuran (Sor·HCl.H(2)O.THF), C(21)H(17)ClF(3)N(4)O(3)(+)·Cl(−).H(2)O.C(4)H(8)O (III)), sorafenib hydrobromide (Sor·HBr), 4-(4-{3-[4-chloro-3-(trifluoro-methyl)phenyl]ureido}phenoxy)-2-(N-methylcarbamoyl) pyridinium hydrobromide, C(21)H(17)ClF(3)N(4)O(3)(+)·Br(−) (IV) and sorafenib hydrobromide monohydrate (Sor·HBr.H(2)O), C(21)H(17)ClF(3)N(4)O(3)(+)·Br(−).H(2)O (V) were analysed. …”
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“…The results revealed the catalysts’ effectiveness in FFA decarbonylation and decarboxylation, as evidenced by significant changes in the van Krevelen space, with the lowest O/C ratio values for BOMoCo and BOMoNi (O/C = 0–0.10) in relation to the BOWCSO (O/C = 0.10–0.20), and by a decrease in the presence of oxygenated compounds in the catalytic bio-oils.…”
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“…Three cyclo­penta­dienylmolybdenum(II) propionyl complexes featuring tri­aryl­phosphine ligands with different para substituents, namely, dicarbon­yl(η(5)-cyclo­penta­dien­yl)propion­yl(tri­phenyl­phosphane-κP)molybdenum(II), [Mo(C(5)H(5))(C(3)H(5)O)(C(18)H(15)P)(CO)(2)], (1), dicarbon­yl(η(5)-cyclo­penta­dien­yl)propion­yl[tris­(4-fluoro­phen­yl)phosphane-κP]molybdenum(II), [Mo(C(5)H(5))(C(3)H(5)O)(C(18)H(12)F(3)P)(CO)(2)], (2), and dicarbon­yl(η(5)-cyclo­penta­dien­yl)propion­yl[tris­(4-meth­oxy­phen­yl)phosphane-κP]molybdenum(II) dichloromethane solvate, [Mo(C(5)H(5))(C(3)H(5)O)(C(21)H(21)O(3)P)(CO)(2)]·CH(2)Cl(2), (3), have been prepared from the corresponding ethyl complexes via phosphine-induced migratory insertion. …”
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“…In addition, TG-MS-coupled experiments were carried out with 7 proving that decomposition occurs by M–O, C–O, C–N and C–C bond cleavages, as evidenced from the detection of fragments such as CH(4)N(+), C(2)H(4)N(+), C(2)H(5)N(+), CH(2)O(+), C(2)H(2)O(+) and C(2)H(3)O(+). …”
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“…There was a reduction of 43.8% (450º), 45.6% (550ºC) and 23.8% (650ºC) in the formation of nitrogenates compounds in relation to sample A. …”
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“…Our analytical results indicated that seven key VOCs, including C(4)H(8)O(2), C(13)H(22)O, C(11)H(22)O, C(2)H(4)O(2), C(7)H(14)O, C(6)H(12)O, and C(5)H(8)O, are sufficient to detect the lung cancer patients with higher mean classification accuracy (92%) and lower standard error (0.03) compared to other combinations. …”
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“…A RANO (0,1, 1, 10 e 30 uM, a 25(O)C) em uma série de frequências de estimulação teve impacto pouco significativo sobre ambos os tipos de células, mas a RANO (30uM) a 35(O)C minimizou o encurtamento dos sarcômeros em ~21% para células do endocárdio. …”
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“…RESULTS: Baseline data suggested that after adding 240 mL of freshly boiled water to an unwarmed mug containing a tea bag, the median temperature of a standard cup of tea was 82ºC (range 81-84ºC). Optimal palatability and agreed universal drinking temperature of 61ºC was achieved at 400 (range 360-420) seconds with 30 mL of cow’s milk and 370 (330-450) seconds with 40 mL of milk. …”
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“…Here, we have decorated imidazole- and triazole-derived carbenes with phenol substituents to access higher-valent Mn(iii) complexes [Mn(O,C,O)(acac)], where acac = acetylacetonato, and O,C,O = bis(phenolate)imidazolylidene (1) or bis(phenolate)triazolylidene (2). …”
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“…The carboxyl group is coplanar with the thia­zole ring [O—C—C—C and O—C—C—S torsion angles of −0.7 (4) and 0.6 (3)°, respectively]. …”
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“…The title compound, C(16)H(22)O(3), is bent with a dihedral angle of 75.3 (1)° between the mean planes of the benzene ring and a group encompassing the ester functionality (O=C—O—C). In the crystal, the mol­ecules are linked into infinite chains held together by weak C—H⋯O hydrogen-bonded inter­actions between an H atom on the benzene ring of one mol­ecule and an O atom on the ketone functionality of an adjacent mol­ecule. …”
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“…In the title complex, [Mn(C(16)H(14)N(4)O)(C(2)H(5)OH)(2)(H(2)O)](C(6)H(2)N(3)O(7))(2)·2C(2)H(5)OH, the Mn(II) ion is in a distorted octa­hedral coordination environment, defined by an MnN(2)O(4) donor set. …”
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“…The title compound, [Fe(C(2)H(5)O)(C(36)H(44)N(4))], contains a five-coordinate iron–porphyrin complex with an axial eth­oxy ligand. …”
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