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1401por Kataoka, Kotaro, Nishijima, Takahiro, Nagasawa, Atsushi, Okamoto, Akiko, Yonezawa, Noriyuki“…The title compound, C(19)H(15)NO(5), has an intramolecular C—H⋯O=C hydrogen bond between a naphthalene H atom and the O atom of the carbonyl group. …”
Publicado 2010
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1402“…The asymmetric unit of the title compound, C(6)H(13)N(2)O(+)·C(8)H(7)O(2) (−)·0.5H(2)O, comprises two isonipecotamide cations, two phenylacetate anions and a water molecule of solvation. …”
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1403“…The hydroxy and methoxy groups lie in the plane of the benzene ring to which they are bound [O—C—C—C = 179.96 (11)° and C—O—C—C = −177.96 (12)°]. …”
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1404“…Two independent molecules comprise the asymmetric unit of the title compound, C(20)H(16)ClNO, which differ in the orientation of the chalcone residue with respect to the quinoline ring [the C—C—C(=O)—C torsion angles are 69.5 (2) and 86.0 (2)°]. …”
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1405“…The two methoxy groups at the meta positions are essentially coplanar with the attached benzene rings [C—O—C—C torsion angles = −0.97 (14) and 179.47 (9)°], whereas the methoxy group at the para position is twisted from the attached ring with a C—O—C—C torsion angle of −104.48 (11)°. …”
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1406por Siddegowda, M. S., Jasinski, Jerry P., Golen, James A., Yathirajan, H. S., Swamy, M. T.“…An extensive array of intermolecular O—H⋯O, O—H⋯N and N—H⋯O hydrogen bonds and weak intermolecular N—H⋯O, C—H⋯O and C—H⋯π interactions dominate the crystal packing.…”
Publicado 2011
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1407“…Intermolecular weak C—H⋯O hydrogen bonding, and C=O⋯C=O [O⋯C = 3.058 (3) Å] and C=O⋯π [O⋯centroid = 3.328 (2) Å] interactions occur in the crystal structure.…”
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1408por Anthal, Sumati, Banerjee, Bubun, Brahmacharia, Goutam, Kant, Rajni, Gupta, Vivek K.“…In the title molecule, C(22)H(24)OSi, the Si—O—C angle is 139.79 (11)°, the O—C—C angles of the triphenylmethoxy group are in the range 106.13 (13)–109.22 (14)° and the O—Si—C angles of the trimethylsilyloxy group are in the range 103.08 (10)–113.53 (10)°. …”
Publicado 2012
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1409por Chantrapromma, Suchada, Ruanwas, Pumsak, Boonnak, Nawong, Chantrapromma, Kan, Fun, Hoong-Kun“…The methoxy groups at the ortho and para positions are slightly twisted from the benzene ring to which they are bound [C—O—C—C = 21.9 (3) and −171.93 (18)°, respectively], whereas the methoxy group at the meta position is almost coplanar [C—O—C—C = 3.5 (3)°]. …”
Publicado 2012
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1410por Fun, Hoong-Kun, Promdet, Premrudee, Horkaew, Jirapa, Karalai, Chatchanok, Chantrapromma, Suchada“…The methoxy group of the 4-methoxyphenyl fragment deviates slightly [C(methyl)—O—C—C = 10.0 (4)°] with respect to the benzene ring, whereas the ethoxy group of the 3-ethoxy-4-hydroxyphenyl fragment is is almost coplanar [C—O—C—C(methyl) = 178.5 (2)°]. …”
Publicado 2012
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1411por Ferreira, Marcelle de Lima, de Souza, Marcus V. N., Wardell, Solange M. S. V., Tiekink, Edward R. T., Wardell, James L.“…One methoxy group, surrounded on either side by the other methoxy groups, is almost normal to the benzene ring to which it is connected [C—O—C(ar)—C(ar) torsion angle = 81.64 (15)°]. In the crystal, N—H⋯O, C—H⋯O and π–π interactions [between quinoline residues; centroid–centroid distance = 3.4375 (8) Å] link molecules into a three-dimensional architecture.…”
Publicado 2012
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1412por El-Azab, Adel S., Abdel-Aziz, Alaa A.-M., Al-Omar, Mohamed A., Ng, Seik Weng, Tiekink, Edward R. T.“…The 2-tolyl ring is approximately orthogonal to this plane [dihedral angle = 83.03 (7)°] as is the acetonitrile group [C—O—C—C torsion angle = 79.24 (14)°] which is also syn to the methyl substituent of the tolyl group. …”
Publicado 2012
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1413“…By introducing the molecular orbital concept, the dominant fluorescence was found to originate from the electronic transitions among/between the non-oxidized carbon regions and the boundary of oxidized carbon atom regions, where all three kinds of functionalized groups C-O, C = O and O = C-OH were participating. In the visible spectral range, the ultrafast fluorescence of graphene oxide was observed for the first time.…”
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1414“…Maximum fecundity occurred in thermal treatments of 21 to 25ºC and the theoretical minimum thermal requirement for population stability was approximately 17ºC. …”
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1415por Zukerman-Schpector, Julio, Hino, Camila Lury, Moran, Paulo J. S., de Paula, Bruno R. S., Ng, Seik Weng, Tiekink, Edward R. T.“…The methoxy substituents of the central benzene ring are either almost coplanar [C—C—O—C = 3.54 (15) and 177.70 (9)°] or perpendicular [C—C—O—C = 80.08 12)° for the central substituent]. …”
Publicado 2013
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1416“…The 4-methoxy substituent is almost co-planar with the benzene ring [C—C—O—C torsion angle = 5.4 (1)°], while the methoxy groups at positions 2 and 3 [C—C—O—C torsion angles of 122.6 (4) and −66.1 (4)°, respectively] are twisted away from the mean plane of the benzene ring in anticlinical and synclinical conformations, respectively. …”
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1417por Aoki, Toshiaki, Ohnishi, Kensuke, Kimoto, Masaaki, Fujieda, Satoshi, Kuramochi, Kouji, Takeuchi, Toshifumi, Nakazaki, Atsuo, Watanabe, Nobuo, Sugawara, Fumio, Arai, Takao, Kobayashi, Susumu“…The intramolecular cyclization at 80 ºC proceeded with minimal racemization of the stereogenic center at C-12 on neoechinulin A, even though the cyclization at 110 ºC caused partial racemization. …”
Publicado 2010
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1418“…The carboxylate group assumes an extended conformation with respect to the pyrimidine ring, which can be seen from the O=C—O—C torsion angle of 3.2 (4) °. In the crystal, molecules are linked via C—H⋯O and C—H⋯N hydrogen bonds, forming slabs lying parallel to (100).…”
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1419por Caracelli, Ignez, Olivato, Paulo R., Traesel, Henrique J., Valença, Jéssica, Rodrigues, Daniel N. S., Tiekink, Edward R. T.“…In the title β-thiocarbonyl compound, C(16)H(16)O(3)S, the adjacent methoxy and carbonyl O atoms are synperiplanar [the O—C—C—O torsion angle is 19.8 (4)°] and are separated by 2.582 (3) Å. …”
Publicado 2015
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