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1841“…The molecule of the title compound, C(14)H(16)N(2)O(2), is located on a crystallographic twofold rotation axis. The central O—C—C—O bridge adopts a gauche conformation. One of the amine H atoms is disordered over two equally occupied positions. …”
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1842por Bednarek, Gabriela, Kusz, Joachim, Ratuszna, Alicja, Ossowski, Jerzy, Sułkowski, Wiesław W.“…The molecules are hydrogen bonded into a three-dimensional framework, with the hydroxy O atoms acting as acceptors in N—H⋯O hydrogen bonds and as donors in O—H⋯O=C interactions.…”
Publicado 2008
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1843“…The title compound, C(13)H(7)ClN(4)O·C(2)H(6)O, was synthesized by the reaction of 4-chlorobenzaldehyde, malononitrile and 10% sodium hydroxide solution in an aqueous medium. …”
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1844por Ahmad, Matloob, Latif Siddiqui, Hamid, Zia-ur-Rehman, Muhammad, Tizzard, Graham John, Ahmad, Saeed“…The enolic H atom is involved in intramolecular O—H⋯O hydrogen bonding besides the weaker C—H⋯O=S and C—H⋯O=C interactions.…”
Publicado 2008
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1845“…The crystal packing is stabilized by O—H⋯N, C—H⋯O, C—H⋯π and π–π interactions [centroid–centroid separations = 3.732 (1) and 3.569 (1) Å].…”
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1846“…In the crystal, the molecules are linked by N—H⋯O, C—H⋯O and C—H⋯N interactions, resulting in chains.…”
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1847“…In the crystal structure, molecules are linked by intermolecular N—H⋯O, C—H⋯Cl and C—H⋯O hydrogen bonds, forming chains running along the b axis.…”
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1848“…The crystal structure is stabilized by intermolecular N—H⋯O, C—H⋯N and C—H⋯O hydrogen bonds.…”
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1849“…A short intermolecular O⋯C contact of 2.8994 (18) Å is alsopresent in the crystal structure, but no π–π contacts are observed.…”
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1850“…In the title compound, C(16)H(23)NO(5), the H—N—O—C torsion angle is 98.6 (1)°, which is of a similar magnitude to other N,O-diacylhydroxylamines. …”
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1851“…In the title compound, [Co(C(13)H(8)F(2)O)(C(3)H(9)P)(3)], the cobalt(0) atom is coordinated by three trimethylphosphine ligands and a π-coordinated carbonyl group of the 2,6-difluorobenzophenone ligand in a distorted tetrahedral geometry. …”
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1852por Babu, C. Suneel Manohar, Kavitha, Helen P., Arulmozhi, R., Vennila, Jasmine P., Manivannan, V.“…The crystal packing is stabilized by weak intermolecular C—H⋯O, C—H⋯Cl and π–π [centroid–centroid distance = 3.8782 (16) Å] interactions.…”
Publicado 2009
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1853“…In the title compound, C(17)H(17)N(3)O(3), the 3-methoxybenzaldehyde group and the benzotriazole fragment are connected through a flexible oxypropyl chain. The O—C—C—C torsion angle in the central link is −63.9 (2)°, while the plane of the benzene ring of the 3-methoxybenzaldehyde substituent forms a dihedral angle of 56.4 (4)° with the benzotriazole plane.…”
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1854“…The crystal structure contains N—H⋯N hydrogen bonds between two unique molecules within layers and antiparallel C—O⋯O—C interactions [O⋯O = 3.06 (3) Å] between the two molecules of the asymmetric unit.…”
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1855por Pereira Silva, P. S., Parveen, Mehtab, Khanam, Zakia, Ali, Akhtar, Ramos Silva, M.“…In the title compound, C(12)H(10)I(2)O(4), the methoxy groups are twisted considerably with respect to the plane of the aromatic ring [CH(3)—O—C—C torsion angles = −85.9 (3) and −92.8 (3)°]. …”
Publicado 2010
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1856“…In the unique part of the molecule, the four-atom –O–CH(2)–C(= O)–O– chain between the benzene ring and the tert-butyl group assumes a zigzag conformation [O—C—C—O torsion angle = −162.3 (1)°].…”
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1857“…The amide group is twisted with respect to the benzene ring [N–C(=O)–C–C torsion angle = −30.8 (4)°]. In the crystal, C(4) chains propagating in [100] are formed by intermolecular N–H⋯O hydrogen bonds. …”
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1858“…In the title compound, C(15)H(13)NO(2), all atoms of the carbazole group are coplanar (r.m.s. deviation = 0.005 Å), and the dihedral angle between this plane and C—O—C plane of oxane group is 57.1 (4)°. The crystal packing is stabilized by an N—H⋯O hydrogen bond, resulting in infinite supramolecular chains along [001].…”
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1859“…Two molecules are connected by N—H⋯S=C hydrogen bonds into a centrosymmetric dimer. An additional N—H⋯O=C hydrogen bond to the acetone solvent molecule and some weak C—H⋯π interactions reinforce the crystal structure.…”
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1860“…In the title compound, C(12)H(12)O(3), the methoxy and prop-2-ynyloxy groups are nearly coplanar with the attached benzene ring [C—O—C—C torsion angles = 1.2 (3) and 2.2 (3)°, respectively]. …”
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