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1901por Ben Gharbia, Imen, Kefi, Riadh, El Glaoui, Meher, Jeanneau, Erwann, Ben Nasr, Cherif“…The crystal packing is influenced by O—H⋯Cl, N—H⋯Cl, N—H⋯O, C—H⋯O and C—H⋯Cl hydrogen bonds, resulting in structure with an open-framework architecture.…”
Publicado 2008
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1902“…The two methoxy groups are coplanar with the attached benzene ring [C—O—C—C torsion angles = −1.1 (5) and 3.2 (4)°].…”
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1903por NizamMohideen, M., Thenmozhi, S., SubbiahPandi, A., Selvam, N. Panneer, Perumal, P. T.“…The crystal structure is characterized by intermolecular N—H⋯O, O—H⋯O, C—H⋯O and C—H⋯π hydrogen bonds.…”
Publicado 2009
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1904“…In the crystal, the molecules interact via C—H⋯O, C—H⋯Cl and C—H⋯π interactions.…”
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1905“…In the title compound, C(18)H(29)N(3)O, a polysubstituted guanidine, the torsion angles indicate that the guanidine unit and the carbonyl group are almost perpendicular to one another [O—C—N—C= −7.40 (18), C—N—C—N= −97.21 (15) and 86.41 (13)°]. …”
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1906“…The methoxy group lies almost in the plane of the benzene ring [C–O–C–C torsion angle = 2.7 (2)°]. In the crystal structure, intermolecular N—H⋯O hydrogen bonds link the molecules into chains along [010].…”
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1907“…In the crystal structure of the title compound, C(13)H(11)NO(3)S, the conformation of the N—H bond in the C—SO(2)—NH—C(O)—C segment is anti to the C=O bond. The molecule is twisted at theN atom with a dihedral angle of 86.5(1)° between the sulfonyl benzene ring and the —SO(2)—NH—C=O segment. …”
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1908“…The components of the adduct are linked by intermolecular O—H⋯N hydrogen bonds and further connected by a combination of C—H⋯O, C—H⋯F and F⋯F [2.859 (2) Å] interactions.…”
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1909por Saravanan, B., Dhayalan, V., Mohanakrishnan, A. K., Chakkaravarthi, G., Manivannan, V.“…The crystal structure exhibits weak intermolecular C—H⋯O, C—H⋯π and π–π [centroid–centroid distances = 3.620 (1)–3.794 (1) Å] interactions.…”
Publicado 2009
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1910“…In the title compound, [Zn(C(15)H(11)N(2)O(2))(2)(C(2)H(8)N(2))], the Zn(II) atom is coordinated in a distorted tetrahedral geometry. Intramolecular N—H⋯O, C—H⋯O and C—H⋯N hydrogen bonds occur. In the crystal, molecules are linked by intermolecular N—H⋯O hydrogen bonds, forming a three-dimensional network.…”
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1911por Caracelli, Ignez, Zukerman-Schpector, Julio, Vieira, Adriano S., Stefani, Hélio A., Tiekink, Edward R. T.“…The 1,3-dioxin-4-one ring in the title compound, C(16)H(16)O(3), is in a half-boat conformation with the quaternary O—C(CH(3))(2)—O atom lying 0.546 (1) Å out of the plane defined by the remaining five atoms. …”
Publicado 2009
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1912por Khan, F. Nawaz, Manivel, P., Prabakaran, K., Hathwar, Venkatesha R., Ng, Seik Weng“…The cyclohexyl ring adopts a chair conformation with the ketonic group occupying an equatorial position; the four-atom –C(O)–C ketonic unit is twisted out of the plane of the phenylene ring by 34.9 (1)°.…”
Publicado 2009
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1913“…2-Hydroxypyridine when treated with concentrated sulfuric acid is sulfonated at the 3-position to yield the title hydrated salt, H(3)O(+)·C(5)H(4)NO(3)S(−)·2H(2)O. In the crystal structure, the cations, anions and uncoordinated water molecules are linked by extensive O—H⋯O and N—H⋯O hydrogen bonds into a three-dimensional network. …”
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1914“…The 3,5-methoxy groups in the title compound, C(16)H(23)NO(4), are almost coplanar with the aromatic ring, whereas the 4-methoxy group is bent out of this plane. The three CH(3)—O—C—C torsion angles are −1.51 (18), 0.73 (19) and 75.33 (15)°. …”
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1915“…The title organic salt, C(4)H(6)N(3)O(+)·C(4)H(3)O(4) (−)·C(4)H(5)N(3)O, was synthesized from cytosine base and maleic acid. …”
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1916“…The central –CH=N—N=CH– fragment is planar, but as a whole the molecule is not: the benzyloxy group is rotated about the O—C bond by 69.3 (2)° with respect to the plane of the benzylidene hydrazine unit.…”
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1917“…In the crystal structure, an O⋯C short contact of 2.917 (3) Å is observed.…”
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1918“…In the title compound, C(10)H(9)N(3)O, the organic rings linked to the ether O atom make a dihedral angle of 76.8 (1)° and the C—O—C angle is widened to 119.07 (15)°. In the crystal, adjacent molecules are connected by an N—H⋯N hydrogen bond, generating a chain running parallel to the b axis. …”
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1919“…The crystal structure is stabilized by intermolecular N—H⋯O, C—H⋯O and C—H⋯N hydrogen bonding, and C—H⋯π interactions.…”
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1920“…These chains are connected by hydrophobic interactions, forming infinite layers and N—H⋯O=C contacts between molecules of adjacent layers give rise to a three-dimensional structure.…”
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