“…In the first mol­ecule, the two phenyl rings make dihedral angles of 84.98 (11)° and the five-membered ring makes dihedral angles of 84.80 (12) and 73.00 (12)° with the phenyl rings; the corresponding angles for the second mol­ecule are 86.74 (11), 81.20 (13) and 71.36 (12)°. …”
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“…There exist dissimilar dihedral angles within the two mol­ecules, for example the carboxylate and isopropyl groups make dihedral angles of 59.6 (4) and 71.7 (3)° in the two molecules. …”
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“…The pyrazole and pyrimidine rings form dihedral angles of 6.2 (3) and 8.3 (3)° with each other and the dihedral angles between the pyrazole and benzene rings are 54.9 (2) and 58.6 (2)°. …”
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“…The acetamide groups make nearly equal dihedral angles of 25.4 (3) and 25.7 (3)° with the parent benzene rings. …”
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“…The sulfonyl group make dihedral angles of 44.89 (13) and 59.16 (12)° with the adjacent aniline groups. …”
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“…The asymmetric unit of the title compound, C(14)H(12)N(2)O(4), contains two mol­ecules that differ principally in the orientation of the acetamide substituent to the adjacent benzene ring with dihedral angles of 44.77 (7) and 19.06 (7)°. The dihedral angles between the benzene rings are 64.46 (4) and 80.84 (4)°. …”
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“…The asymmetric unit of title compound, C(12)H(15)BrN(2)O(4)S, contains two mol­ecules (A and B), with slightly different conformations: the bromo­phenyl rings and the SO(2) planes of the sulfonyl groups are oriented at dihedral angles of 50.2 (2) (mol­ecule A) and 58.24 (7)° (mol­ecule B), and the ethyl acetate groups make dihedral angles of 63.99 (19)° (A) and 65.35 (16)° (B) with their bromo­phenyl groups. …”
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“…In the two ordered mol­ecules, the furan and naphthalene rings are oriented at dihedral angles of 11.05 (12) and 32.2 (5)°. In the disordered mol­ecule, the furan rings with major and minor occupancies are oriented at dihedral angles of 41.4 (2) and 26.6 (13)°, respectively, with the corresponding naphthalene ring. …”
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“…The prop-2-enamide fragment and the nitro group make dihedral angles of 20.42 (6) and 13.54 (17)°, respectively, with the benzene ring. …”
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“…In the asymmetric unit of the title compound, C(15)H(16)N(2)O(5)S(2), there are two symmetry-independent mol­ecules which adopt similar conformations, with dihedral angles between the aromatic rings of 59.30 (8) and 61.81 (8)°, and dihedral angles between acetamide group and the benzene ring of 77.08 (10) and 78.40 (10)°. …”
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“…The asymmetric unit of the title compound, C(12)H(7)NO(3)S, contains two independent mol­ecules with different geometric­al configurations. The dihedral angles between the benzene and pyridine rings in the two mol­ecules are 3.7 (2) and 5.40 (19)°. …”
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“…In the other mol­ecule the deviations are 0.0455, 0.0007 and 0.0143 Å, respectively, and the dihedral angles are 5.01 (14), 4.53 (16) and 3.38 (13)°, respectively. …”
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“…There are two independent mol­ecules in the asymmetric unit of the title compound, C(17)H(20)N(2), in which the dihedral angles between the aromatic rings are 30.34 (11) and 41.44 (8)°. …”
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“…The benzene rings are oriented at a dihedral angle of 39.22 (10)°. In the crystal, a very weak C—H⋯π inter­action occurs.…”
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“…In the mol­ecule of the title compound, C(6)H(3)ClINO(2), the nitro group is disordered over two sites with occupancies of 0.506 (6) and 0.494 (6). The dihedral angles between the benzene ring and the two disordered components of the nitro group are 29.0 (2) and 51.0 (3)°. …”
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“…The dihedral angle between the dichloro­benzene and phenyl rings is 88.57 (5)°. …”
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“…The dihedral angle between the benzene and pyridine rings is 5.53 (7)°. …”
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“…The asymmetric unit of the title compound, C(7)H(6)BrNO(2), consists of two mol­ecules having a small variation of bond lengths and angles. The title compound forms dimers through pairs of O—H⋯O hydrogen bonds involving the carboxyl­ate groups. …”
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“…The nitro groups make dihedral angles of 4.2 (5)° and 60.21 (11)° with the benzene ring. …”
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“…The asymmetric unit of the title compound, C(15)H(14)ClNO(2), contains two mol­ecules with significantly different conformations: the dihedral angles between the 4-chloro­aniline and 3,4-dimeth­oxy­phenyl (excluding C atoms) moieties are 19.68 (7) and 45.54 (4)°. …”
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