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  1. 3581
    “…OBJECTIVES: Male infertility caused by exposure to heavy metals is a current global issue. Exposure to cadmium chloride (CdCl(2)) negatively affects the male reproductive system. …”
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  2. 3582
  3. 3583
    “…Theobroma cacao L. can bioaccumulate cadmium (Cd) in the seed and could be in derived food products, it considered a human health risk; therefore, removal of Cd is desirable but not vet technically and economically feasible; only to avoid Cd in cocoa is by selecting lands plots exhibiting lower Cd concentrations in soils, imposing a serious limitation to farmers and regulators. …”
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  4. 3584
    “…The title compound, [Cd(2)(C(2)H(3)O(2))(4)(C(12)H(8)N(2))(2)], consists of dimeric units built up around a crystallographic symmetry centre. Each cadmium(II) unit is chelated by a 1,10-phenanthroline (phen) group and two acetate ligands, one of which also acts as a bridge, linking both seven-coordinated cadmium(II) centres. …”
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  5. 3585
  6. 3586
  7. 3587
  8. 3588
  9. 3589
  10. 3590
    “…In the crystal, mol­ecules are connected into a supra­molecular chain via O—H⋯N hydrogen bonds involving the 4-pyridine­aldazine N atoms not involved in coordination to cadmium. Weak C—H⋯O and C—H⋯N links consolidate the packing.…”
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  11. 3591
  12. 3592
  13. 3593
  14. 3594
  15. 3595
  16. 3596
  17. 3597
    “…Monocrystals of dinuclear μ-1,4-bis­(3-amino­prop­yl)pi­per­a­zine-κ(4) N (1),N (1′):N (4),N (4′)-bis­[bis­(tri-tert-but­oxy­silane­thiol­ato-κS)cadmium(II)], [Cd(2)(C(12)H(27)O(3)SSi)(4)(C(10)H(24)N(4))] or [Cd(2){SSi(OtBu)(3)}(4)(μ-BAPP)], 1, and polynuclear catena-poly[[bis­(tri-tert-but­oxy­silane­thiol­ato-κS)cadmium(II)]-μ-1,4-bis­(3-amino­prop­yl)pi­per­a­zine-κ(2) N (1′):N (4′)], [Cd(C(12)H(27)O(3)SSi)(2)(C(10)H(24)N(4))]( n ) or [Cd{SSi(OtBu)(3)}(2)(μ-BAPP)]( n ), 2, with 1,4-bis­(3-amino­prop­yl)pi­per­a­zine (BAPP) and tri-tert-but­oxy­silane­thiol­ate ligands, were obtained from the same ratio of reactants, but with different solvents used for the crystallization processes. …”
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  18. 3598
  19. 3599
  20. 3600
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