“…The pH of CO(2)–H(2)O binary system, as calculated based on gas–liquid equilibrium, charge balance and chemical equilibrium equations, ranged from 3.49 to 3.70 depending on the reaction conditions, indicating effective acid catalysis. …”
Enlace del recurso
Enlace del recurso
Enlace del recurso

“…The restrictions of the analytical solution, namely, the local chemical equilibrium assumption, are discussed.…”
Enlace del recurso
Enlace del recurso
Enlace del recurso

“…The research was focused on determining the sorbents surface properties (by XRF (X-ray fluorescence) method and potentiometric titration in order to determine the properties of surface groups—Chemical Equilibrium Model (CEM) and Ion Exchange Model (IExM) models were applied here). …”
Enlace del recurso
Enlace del recurso
Enlace del recurso

“…The development of artificial nanoscale motors that can use energy from a source to perform tasks requires systems capable of performing directionally controlled molecular movements and operating away from chemical equilibrium. Here, the design, synthesis and properties of pseudorotaxanes are described, in which a photon input triggers the unidirectional motion of a macrocyclic ring with respect to a non‐symmetric molecular axle. …”
Enlace del recurso
Enlace del recurso
Enlace del recurso

“…The second part addresses important applications of thermodynamics, covering phase transitions, mixtures and solutions (including the Kirkwood-Buff approach and solvation thermodynamics), chemical equilibrium, and the outstanding properties of water.This textbook is unique in two aspects. …”
Enlace del recurso

“…We also explore the effect of early chemical equilibrium on the photon observables. [1] A. Kurkela, A. …”
Enlace del recurso

“…The chemical equilibrium between self-ionized and molecular water dictates the acid–base chemistry in aqueous solutions, yet understanding the microscopic mechanisms of water self-ionization remains experimentally and computationally challenging. …”
Enlace del recurso
Enlace del recurso
Enlace del recurso

“…Glucose was first added to glucose-free suspensions, and its entry into the cells followed; then C14-glucose was added after attainment of chemical equilibrium, and the tracer equilibration similarly followed. …”
Enlace del recurso
Enlace del recurso

“…Williamson et al reported a method to estimate this ratio by cytosolic lactate/pyruvate (L/P) based on the principle of chemical equilibrium. Numerous studies used L/P ratio to estimate the cytosolic free NAD/NADH ratio by assuming that the conversion in cells was at near-equilibrium but not verifying how near it was. …”
Enlace del recurso
Enlace del recurso
Enlace del recurso

“…To obtain detailed insight into this transfer process, we designed a novel model of Fa transfer dynamics from coronary plasma through the endothelial cells and interstitium to the cardiomyocyte, applying standard physicochemical principles on diffusion and on the chemical equilibrium of Fa binding to carrier proteins Cp, like albumin in plasma and interstitium and Fatty Acid-Binding Proteins within endothelium and cardiomyocytes. …”
Enlace del recurso
Enlace del recurso
Enlace del recurso

“…These water quality results, in conjunction with copper chemical equilibrium modeling, show pH and dissolved carbon both significantly impact the total dissolved copper concentration and should be measured to assess reuse potential. …”
Enlace del recurso
Enlace del recurso
Enlace del recurso

“…An unfavourable chemical equilibrium between O(2) and the Fe(II) complex occurs that leads to the Fe(III)-peroxo complex upon reduction, similarly to heme enzymes such as P450. …”
Enlace del recurso
Enlace del recurso
Enlace del recurso

“…We identify a chemical equilibrium between opposite but not mirror-image-related twisting molecular geometries of the pure enantiomer, and accordingly two competing aggregation pathways. …”
Enlace del recurso
Enlace del recurso
Enlace del recurso

“…This is particularly true for systems that are out of chemical equilibrium and show complex dynamic behaviour, such as multi-stability, oscillations and chaos. …”
Enlace del recurso
Enlace del recurso
Enlace del recurso

“…Overall, PC-SAFT proved its excellent capabilities toward predicting chemical equilibrium composition in the homogeneous composition range of the investigated systems as well as liquid–liquid phase behavior. …”
Enlace del recurso
Enlace del recurso
Enlace del recurso

“…Evolution by natural selection will have taken place in Earth’s fluid envelope; both air and water display scale invariance and are far from chemical equilibrium, a complex condition driven by the Gibbs free energy arising from the entropy difference between the incoming solar beam and the outgoing infrared radiation to the cold sink of space acting on the initial conditions within evolving boundary conditions. …”
Enlace del recurso
Enlace del recurso
Enlace del recurso

“…A combustion model that utilized Chemical Equilibrium with Applications was conducted as well and was shown to be in good agreement with the experimental results.…”
Enlace del recurso
Enlace del recurso
Enlace del recurso

“…X-ray microtomography was used to image, at a resolution of 6.6 µm, the pore-scale arrangement of residual carbon dioxide ganglia in the pore-space of a carbonate rock at pressures and temperatures representative of typical formations used for CO(2) storage. Chemical equilibrium between the CO(2), brine and rock phases was maintained using a high pressure high temperature reactor, replicating conditions far away from the injection site. …”
Enlace del recurso
Enlace del recurso
Enlace del recurso

“…METHODS: Mechanistic multi-surface chemical equilibrium modeling was applied for obtaining soil-specific predictions of metal and PS speciation upon interaction of the PS 2’-deoxymugineic acid (DMA) with 6 soils differing in availability of Fe and other metals. …”
Enlace del recurso
Enlace del recurso
Enlace del recurso

“…The calculations using the NASA Chemical Equilibrium with Applications (CEA) software indicated that the heat of reaction for the components stored under the moisture-rich conditions is reduced by more than 50%. …”
Enlace del recurso
Enlace del recurso
Enlace del recurso