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90861“…In this review, we summarize research efforts to realize Na-based organic materials for novel battery chemistries. Na is a more abundant element than Li, thereby contributing to less costly materials with limited to no geopolitical constraints while organic electrode materials harvested from biomass resources provide the possibility of achieving renewable battery components with low environmental impact during processing and recycling. …”
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90862por Fernandez‐Castano Romera, Marcos, Lafleur, René P. M., Guibert, Clément, Voets, Ilja K., Storm, Cornelis, Sijbesma, Rint P.“…The work expands current knowledge about the design principles and chemistries needed to achieve fully synthetic, biomimetic soft matter with on‐demand, targeted mechanical properties.…”
Publicado 2017
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90863Construction and in vivo assembly of a catalytically proficient and hyperthermostable de novo enzymepor Watkins, Daniel W., Jenkins, Jonathan M. X., Grayson, Katie J., Wood, Nicola, Steventon, Jack W., Le Vay, Kristian K., Goodwin, Matthew I., Mullen, Anna S., Bailey, Henry J., Crump, Matthew P., MacMillan, Fraser, Mulholland, Adrian J., Cameron, Gus, Sessions, Richard B., Mann, Stephen, Anderson, J. L. Ross“…Although catalytic mechanisms in natural enzymes are well understood, achieving the diverse palette of reaction chemistries in re-engineered native proteins has proved challenging. …”
Publicado 2017
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90864por Dou, Hongjing, Li, Mei, Qiao, Yan, Harniman, Robert, Li, Xiaoyu, Boott, Charlotte E., Mann, Stephen, Manners, Ian“…Here we show the preparation of a series of crystallizable diblock copolymers with appropriate wettability and chemical reactivity, and demonstrate their self-assembly into size-specific cylindrical micelle building blocks for the hierarchical construction of mechanically robust colloidosomes with a range of membrane textures, surface chemistries and optical properties. The colloidosomes can be structurally elaborated post assembly by in situ epitaxial elongation of the membrane building blocks to produce microcapsules covered in a chemically distinct, dense network of hair-like outgrowths. …”
Publicado 2017
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90865“…These nanofilaments, however, are very often nonreactive and thus difficult to utilize in subsequent chemistries. In response, we have developed a single-step procedure to grow (SiHCl(3)-based) silicone nanofilaments with selective reactivity that are intrinsically superhydrophobic. …”
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90866“…Overall, the new trifunctional scaffold combines CuAAC and hydrazone chemistries, offering a broader chemical space for the development of bioactive compounds.…”
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90867“…The purpose of this study was to evaluate the stability of PEG-albumin scaffold systems formed using PEG polymers with three different functionalized end chemistries by quantifying in vitro system swellability to determine the most promising PEG crosslinking polymer for wound healing applications. …”
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90868“…They provide interesting attributes to current electrochemical biosensing due to their intrinsic low toxicity, high solubility in many solvents, excellent electronic properties, robust chemical inertness, large specific surface area, abundant edge sites for functionalization, great biocompatibility, low cost, and versatility, as well as their ability for modification with attractive surface chemistries and other modifiers/nanomaterials. In this review article, the use of GQDs and CDs as signal tags or electrode surface modifiers to develop electrochemical biosensing strategies is critically discussed through the consideration of representative approaches reported in the last five years. …”
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90869“…We show that the luminescence is linked to a specific ilmenite source used in historic TITANOX pigments, is not present in pigments produced by more advanced chemistries, and provides dating information. Facile Raman-based detection of this luminescence, along with characteristic peaks of rutile, anatase, calcium sulfate, or barium sulfate, can identify the type of titanium white pigment and narrow its manufacture date range.…”
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90870por Van Steenberge, Paul H. M., Sedlacek, Ondrej, Hernández-Ortiz, Julio C., Verbraeken, Bart, Reyniers, Marie-Françoise, Hoogenboom, Richard, D’hooge, Dagmar R.“…The proposed research strategy is generic and extendable to a broad range of copolymerization chemistries, including reversible deactivation radical polymerization.…”
Publicado 2019
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90871por Ribeiro, Lucas Ferreira, Amarelle, Vanesa, Alves, Luana de Fátima, Viana de Siqueira, Guilherme Marcelino, Lovate, Gabriel Lencioni, Borelli, Tiago Cabral, Guazzaroni, María-Eugenia“…Protein engineering emerged as a powerful approach to generate more robust and efficient biocatalysts for bio-based economy applications, an alternative to ecologically toxic chemistries that rely on petroleum. On the quest for environmentally friendly technologies, sustainable and low-cost resources such as lignocellulosic plant-derived biomass are being used for the production of biofuels and fine chemicals. …”
Publicado 2019
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90872“…The direct involvement of methionine-derived metabolites in diverse chemistries such as transsulfuration and methylation reactions comes from the elegant positioning and safe handling of sulfur through these molecules. …”
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90873por Pereira, Sara B., Sousa, Aureliana, Santos, Marina, Araújo, Marco, Serôdio, Filipa, Granja, Pedro, Tamagnini, Paula“…This requires a better understanding of the EPS biosynthetic pathways and their relationship with central metabolism, as well as to exploit the available polymer functionalization chemistries. Considering all this, we provide an overview of the characteristics and biological activities of cyanobacterial EPS, discuss the challenges and opportunities to improve the amount and/or characteristics of the polymers, and report the most relevant advances on the use of cyanobacterial EPS as scaffolds, coatings, and vehicles for drug delivery.…”
Publicado 2019
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90874por Zhou, Guangmin, Yang, Ankun, Wang, Yifei, Gao, Guoping, Pei, Allen, Yu, Xiaoyun, Zhu, Yangying, Zong, Linqi, Liu, Bofei, Xu, Jinwei, Liu, Nian, Zhang, Jinsong, Li, Yanxi, Wang, Lin-Wang, Hwang, Harold Y., Brongersma, Mark L., Chu, Steven, Cui, Yi“…These studies demonstrate a powerful in situ optical battery platform for unraveling the complex reaction mechanism of sulfur chemistries and for exploring the rich material properties of the liquid sulfur, which shed light on the applications of liquid sulfur droplets in devices such as microlenses, and potentially other electrotunable and optoelectronic devices.…”
Publicado 2020
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90875por Morillas-Becerril, Lucía, Peta, Elektra, Gabrielli, Luca, Russo, Venera, Lubian, Elisa, Nodari, Luca, Ferlin, Maria Grazia, Scrimin, Paolo, Palù, Giorgio, Barzon, Luisa, Castagliuolo, Ignazio, Mancin, Fabrizio, Trevisan, Marta“…To target cancer stem cells, anti-CD44v6 antibody and hyaluronic acid (HA) were conjugated to amine-functionalized PEGylated ORMOSIL nanoparticles through thiol-maleimide and amide coupling chemistries, respectively. Specific binding and uptake of conjugated nanoparticles were studied on cells overexpressing the CD44v6 receptor. …”
Publicado 2020
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90876por Zou, Weike, Jin, Binjie, Wu, Yi, Song, Huijie, Luo, Yingwu, Huang, Feihe, Qian, Jin, Zhao, Qian, Xie, Tao“…The TIN concept enriches the design of polymers, with potential expansion into other materials with variations in dynamic covalent chemistries, isomerizable topologies, and programmable macroscopic properties.…”
Publicado 2020
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90877por Yan, Yong, Carrington, Elliot J., Pétuya, Rémi, Whitehead, George F. S., Verma, Ajay, Hylton, Rebecca K., Tang, Chiu C., Berry, Neil G., Darling, George R., Dyer, Matthew S., Antypov, Dmytro, Katsoulidis, Alexandros P., Rosseinsky, Matthew J.“…The resulting control optimizes noncovalent interactions to differentiate the uptake and structure response of host–guest pairs with similar chemistries.…”
Publicado 2020
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90878“…In addition to novel battery chemistries often scientifically reviewed, advanced battery structures via technological innovations that boost battery performance are also worthy of attention. …”
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90879“…These results have inspired the exploration of increasingly exotic chemistries highly divergent from the canonical nucleic acid chemical structure that possess unnatural physiochemical properties. …”
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90880por Lin, Tingzhi, Gu, Yuanyun, Qian, Pengcheng, Guan, Haixing, Walsh, Patrick J., Mao, Jianyou“…Like the generation of transition metal enolates, which have been used to great affect in synthesis and medicinal chemistries, homoenolates and their higher homologues have much potential, albeit largely unrealized. …”
Publicado 2020
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