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  1. 2441
    “…The metal‐free catalyst tris(2,4,6‐trifluorophenyl)borane has demonstrated its extensive applications in the 1,2‐hydroboration of numerous unsaturated reagents, namely alkynes, aldehydes and imines, consisting of a wide array of electron‐withdrawing and donating functionalities. A range of over 50 borylated products are reported, with many reactions proceeding with low catalyst loading under ambient conditions. …”
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    Tris(2,4,6‐trifluorophenyl)borane: An Efficient Hydroboration Catalyst
  2. 2442
    “…Due to the presence of electron donating and electron withdrawing character on formyl sugars which makes the molecule more susceptible to nucleophilic attack. …”
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    Synthesis, Antiviral, and Antimicrobial Evaluation of Benzyl Protected Diversified C-nucleosides
  3. 2443
    “…As a consequence, its charge transport and photovoltaic properties in a blend with the usual P3HT electron-donating polymer have been investigated.…”
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    An Electron-Transporting Thiazole-Based Polymer Synthesized Through Direct (Hetero)Arylation Polymerization
  4. 2444
    “…In an attempt to improve the binding of the aldehyde hydrate in the active site to boost aldehyde-oxidase activity, two active-site residues were exchanged for hydrogen-bond-donating and -accepting amino acids. Enhanced over-oxidation was demonstrated and Michaelis–Menten kinetics were performed to corroborate these findings.…”
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    Rational Engineering of a Flavoprotein Oxidase for Improved Direct Oxidation of Alcohols to Carboxylic Acids
  5. 2445
    “…Compounds that possess a number of hydrogen-bond-accepting and/or -donating groups like phenolics and quinones show extensive interactions with the targets. …”
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    Comparative Molecular Docking of Antitrypanosomal Natural Products into Multiple Trypanosoma brucei Drug Targets
  6. 2446
    “…Their anti-oxidative properties are found to be related to an inductive effect on endogenous free-radical scavenging enzymes such as catalase and glutathione peroxidase and the inherent electron-donating ability of flavonoids.…”
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    Herba Epimedii: Anti-Oxidative Properties and Its Medical Implications
  7. 2447
    “…A range of benzoate esters were screened, including derivatives with electron-donating and -withdrawing groups in the para- position. …”
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    Iridium-Catalysed ortho-Directed Deuterium Labelling of Aromatic Esters—An Experimental and Theoretical Study on Directing Group Chemoselectivity
  8. 2448
    “…The crucial structural elements that determine dye formation are electron‐donating groups present in the starting tetrazine unit. …”
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    Bioorthogonal Fluorescence Turn‐On Labeling Based on Bicyclononyne−Tetrazine Cycloaddition Reactions that Form Pyridazine Products
  9. 2449
    “…The reaction tolerates substitution in ortho-, meta- and para-substitution as well as electron-donating and electron-withdrawing groups. The S-cyclopropylation of a thiophenol was also accomplished using potassium cyclopropyl trifluoroborate.…”
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    Synthesis of aryl cyclopropyl sulfides through copper-promoted S-cyclopropylation of thiophenols using cyclopropylboronic acid
  10. 2450
    “…The facile synthesis of a rare two-coordinate acyclic silylene (R(2)Si:) that is stabilized using a bulky vinylic N-heterocyclic olefin ligand and the strongly σ-donating hypersilyl group [Si(SiMe(3))(3)](–) is reported. …”
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    A vinyl silylsilylene and its activation of strong homo- and heteroatomic bonds
  11. 2451
    “…Unpromoted Pt is competent with benzylic substrates bearing either electron-donating or electron-withdrawing substituents. Use of both K(2)CO(3) and Bi additives accelerates the rate of alcohol oxidation and affords high yields with challenging heterocyclic alcohols.…”
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    Platinum-Based Heterogeneous Catalysts for Nitrile Synthesis via Aerobic Oxidative Coupling of Alcohols and Ammonia
  12. 2452
    “…Corresponding decaarylated WNGs containing electron-withdrawing and -donating groups were synthesized from decaborylated WNG using Suzuki–Miyaura cross-coupling reactions to afford the red-emissive warped nanographene derivative.…”
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    Two-step synthesis of a red-emissive warped nanographene derivative via a ten-fold C–H borylation
  13. 2453
    “…[Image: see text] A series of spiropyran (SP)-based magnetic resonance imaging (MRI) contrast agents have been synthesized and evaluated for changes in relaxivity resulting from irradiation with visible light. Both electron-donating and electron-withdrawing substituents were appended to the SP ring in order to study the electronic effects on the photochromic and relaxivity properties of these photoswitchable MRI contrast agents. …”
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    Synthesis and Comparative Evaluation of Photoswitchable Magnetic Resonance Imaging Contrast Agents
  14. 2454
    “…To the best of our knowledge, this is the first report of an n-type non-toxic semiconductor for organic transistors that uses sulpho-salicylic acid—a stable, electron-donating compound with reduced toxicity—grafted on a ferrite core–shell and a green synthesis method. …”
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    Sulpho-Salicylic Acid Grafted to Ferrite Nanoparticles for n-Type Organic Semiconductors
  15. 2455
    “…The reaction is sensitive to the electronic nature of the substituents on the benzene ring of the triarylantimony difluorides: an electron-donating group showed higher reactivity than an electron-withdrawing group. …”
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    Palladium-Catalyzed C–H Arylation of Benzofurans with Triarylantimony Difluorides for the Synthesis of 2-Arylbenzofurans
  16. 2456
    “…Furthermore, these compounds show a narrow energy gap (1.75–2.38 eV), and high Ea values increasing for polymers, which prove their electron-donating nature and semiconductor properties. The measurements were enhanced by theoretical modeling.…”
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    2,1,3-Benzothiadiazole Small Donor Molecules: A DFT Study, Synthesis, and Optoelectronic Properties
  17. 2457
    “…Due to their remarkable electronic features, recent years have witnessed the emergence of carbones L(2)C, which consist in two donating L ligands coordinating a central carbon atom bearing two lone pairs. …”
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    Complexes of Dichlorogermylene with Phosphine/Sulfoxide-Supported Carbone as Ligand †
  18. 2458
    “…Herein, we computationally explore the effect of incorporating electron accepting and electron donating units on CPP photophysical properties at the CAM-B3LYP/6-311G** level. …”
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    Effect of curvature and placement of donor and acceptor units in cycloparaphenylenes: a computational study
  19. 2459
    “…The reaction can be extended to a wide range of substrates, and the target products can be synthesized smoothly, regardless of the presence of electron-donating and electron-withdrawing groups. The proposed strategy is a new direction in the field of rearrangement reactions.…”
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    Pd-Catalyzed Rearrangement Reaction of N-Tosylhydrazones Bearing Allyl Ethers Into Trans-Olefin-Substituted Sulfonylhydrazones
  20. 2460
    “…For other examined complexes, a stronger electron-donating substituent may lead to a higher hydrogen evolution efficiency, suggesting that the formation of a Co(iii) hydride intermediate is the rate-limiting step.…”
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    Electronic effects on polypyridyl Co complex-based water reduction catalysts
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