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2501“…The synthesis and characterization of a series of dibenzhydryl-based α-diimine Ni(II) complexes bearing a range of electron-donating or -withdrawing groups are described. Polymerization with ethylene is investigated in detail, involving the activator effect, influence of polymerization conditions on catalyst activity, thermal stability, polymer molecular weight and melting point. …”
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2502“…As expected, electron-withdrawing groups were found to decrease the rate of glycosylation, whereas electron-donating groups resulted in the opposite outcome, underscoring the influence on the reaction rate exerted by a participating group. …”
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2503“…High functional group tolerance is observed under both catalytic conditions where arylboronic acids and esters having electron-withdrawing and electron-donating substituents afforded fluoranthene products in good yields (up to 78%). …”
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2504“…The homolytic cleavage of Ar substituent (or Ar–H) is facilitated by the strong electron-donating ability of the oxygen anion. A set of free-radical reactions involved in the alkali-catalyzed aromatization have been established.…”
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2505“…This modification is mediated by the metabolite S-adenosyl methionine (SAM), which is also the methyl-donating substrate of histone methyltransferases. Therefore, SAM levels that are influenced by several nutrients, enzymes, and metabolic cofactors also have a potential impact on histone methylation. …”
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2506por Measey, John, Visser, Vernon, Dgebuadze, Yury, Inderjit, Li, Bo, Dechoum, Michele, Ziller, Silvia R., Richardson, David M.“…Emerging economies, such as Brazil, Russia, India, China, and South Africa (BRICS), are responsible for donating many of the world’s invasive species that have the potential to reach nearly all terrestrial biomes. …”
Publicado 2019
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2507por Olesińska, Magdalena, Wu, Guanglu, Gómez-Coca, Silvia, Antón-García, Daniel, Szabó, Istvan, Rosta, Edina, Scherman, Oren A.“…We show that the modular design and synthesis of a new class of π-conjugated viologen derivatives with rigid aromatic or heteroaromatic bridging units as well as electron donating molecular recognition motifs enable their self-assembly into 2 : 2 complexes with CB[8]. …”
Publicado 2019
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2508“…The great affinity of gold surface for numerous electron-donating groups has largely contributed to the rapid development of functionalized gold nanoparticles (Au-NPs). …”
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2509“…Two types of naphthalimide derivatives were synthesized by introducing a carbazole group and an n-butyl, respectively, into the naphthalimide system. The electron-donating ability of two kinds of derivatives was investigated by the electrochemical method. …”
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2510“…Helping a friend move house, donating to charity, volunteering assistance during a crisis. …”
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2511por Singh, Himanshu Kumar, Kamal, Arsala, Kumari, Savita, Kumar, Dhirendra, Maury, Suresh Kumar, Srivastava, Vandana, Singh, Sundaram“…Strangely, the mild conditions, environment-friendly, and enumerating tolerance of an extensive range of both electron-donating and electron-withdrawing groups are additional features of the approach.…”
Publicado 2020
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2512“…Isolable stable silylenes remain scarce, and in most hitherto reported examples, the silicon center is stabilized by electron-donating substituents (e.g., heteroatoms such as nitrogen), which results in electronic perturbation. …”
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2513“…It was found that 4,4′-dicarboxylic derivatives of substrates with electron-donating methyl groups and short linkers (from one to three methylene groups) can be prepared using this method. …”
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2514“…While the geometric features of the carbenaporphyrin ligand strongly resemble those of porphyrin, DFT calculations reveal a stronger electron‐donating ability of the new ligand.…”
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2515“…The radical nature of the reaction facilitates nucleophilic substitution even in the presence of strong electron‐donating groups and enables de‐tert‐butylation required for the complete annulation. …”
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2516por Boylan, Amy, Nguyen, Thien S., Lundy, Brian J., Li, Jian-Yuan, Vallakati, Ravikrishna, Sundstrom, Sasha, May, Jeremy A.“…Thus, reaction rates are increased by the closer proximity of inductive electron-withdrawing elements, but if resonance effects are involved, then increased rates are observed with electron-donating ability. Evidence for these trends in isomeric substrates is presented, and the application of these insights has allowed for reaction conditions that provide improved reactivity with previously problematic substrates.…”
Publicado 2021
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2517“…It has been found that the methyl group (electron‐donating substituent) on the conjugated double bond of the ylides facilitates the formation of C5 segments. …”
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2518por Herbert, Katie M., Getty, Patrick T., Dolinski, Neil D., Hertzog, Jerald E., de Jong, Derek, Lettow, James H., Romulus, Joy, Onorato, Jonathan W., Foster, Elizabeth M., Rowan, Stuart J.“…The equilibrium of the thiol addition to benzalcyanoacetate-based Michael-acceptors can be directly tuned by controlling the electron-donating/withdrawing nature of the Michael-acceptor. …”
Publicado 2020
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2519“…Excited-state symmetry breaking is investigated in a series of symmetric 9,10-dicyanoanthracenes linked to electron-donating groups on the 2 and 6 positions via different spacers, allowing for a tuning of the length of the donor–acceptor branches. …”
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2520por Altaf, Yasir, Ullah, Sana, Khan, Farhan A., Maalik, Aneela, Rubab, Syeda Laila, Hashmi, Muhammad Ali“…This computational investigation is based on density functional theory and aims to explore the photophysical behavior of some of the reported aminobenzanthrones in addition to many unreported dyes containing different electron-donating substituents. Significant changes in the dipole moment and the overall structure of the dyes upon solvation in ethanol have been observed. …”
Publicado 2021
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