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  1. 2621
    “…These interactions were investigated using bidentate ancillary ligands with electron donating and withdrawing substituents. The π‐ligands span from ethylene to larger terminal and internal alkenes and alkynes. …”
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    Binding Interactions in Copper, Silver and Gold π‐Complexes
  2. 2622
    “…[Image: see text] Inspired by mechanistic proposals for N(2) reduction at the nitrogenase FeMo cofactor, we report herein a new, strongly σ-donating heteroscorpionate ligand featuring two weak-field pyrazoles and an alkyl donor. …”
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    Four-Coordinate Fe N(2) and Imido Complexes Supported by a Hemilabile NNC Heteroscorpionate Ligand
  3. 2623
    “…Finally, the increased antioxidative ability was verified due to the hydrogen donating ability of the surviving anthocyanins. This study indicates the reliability of ultrasonic treatment for providing superior colorfastness during Sanhua plum wine aging, which is also of great potential in processing different fruit wines.…”
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    Color Stability Enhancement and Antioxidation Improvement of Sanhua Plum Wine under Circulating Ultrasound
  4. 2624
    “…According to our calculations, the electron-donating behaviour of the H(2)S molecule is halved under compressive strains. …”
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    Unravelling the physisorption characteristics of H(2)S molecule on biaxially strained single-layer MoS(2)
  5. 2625
    “…This is attributed to the synergistic effect of the electron-donating properties of cellulose material and the large specific surface area of AC materials. …”
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    Power Output Enhancement of Natural Rubber Based Triboelectric Nanogenerator with Cellulose Nanofibers and Activated Carbon
  6. 2626
    “…The results show that the λ(max) is dependent on the substituents at the benzylidene ring, and both electron donating substituents and electron withdrawing substituents cause a bathochromic shift. …”
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    Substituent Effects on the Ultraviolet Absorption Properties of 2,4-Dihydroxy Dibenzophenone
  7. 2627
    “…Various functional groups, including allyl, alkynyl, ketone, ester, nitro et al. were tolerated and acted as a C8 directing group. The electron-donating 6-diethylamino, as C2-directing group substituent, can switch the regioselectivity of purine from 8- to 2-position, enabling the synthesis of 8- and 2-cyano 6-dialkylaminopurines from corresponding 6-chloropurine in different reaction order. …”
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    Direct Regioselective C-H Cyanation of Purines
  8. 2628
    “…The equilibrium between different tautomers in these systems could be controlled via the substitution effect, and the relative content of the amide form varied from 74% for the strong electron-donating NMe [Formula: see text] substituent to 38% for the strong electron-accepting NO [Formula: see text] group in the phenyl ring. …”
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    Tautomeric Equilibrium in 1-Benzamidoisoquinoline Derivatives
  9. 2629
    “…Introduction of strong electron-donating groups allowed obtaining a hydrazone switch of pK(a) = 6 suitable for application in (19)F MRI as contrast agents.…”
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    Tuning the pH of Activation of Fluorinated Hydrazone-Based Switches—A Pathway to Versatile (19)F Magnetic Resonance Imaging Contrast Agents
  10. 2630
    “…Although endorsement of the Call to Action was associated with a lower likelihood of donating to candidates who oppose firearm safety policies, the overall pattern was not consistent with professional societies’ advocacy for firearm safety.…”
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    Association of Physician Organization–Affiliated Political Action Committee Contributions With US House of Representatives and Senate Candidates’ Stances on Firearm Regulation
  11. 2631
    “…The presence of Ag nanoparticles in the NR-CF@Ag composite is found to improve the electrical power output of the TENG by promoting the electron donating ability of the cellulose filler, resulting in the higher positive tribo-polarity of NR. …”
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    Ag–Cellulose Hybrid Filler for Boosting the Power Output of a Triboelectric Nanogenerator
  12. 2632
    “…One major diastereoisomer is formed using triarylphosphines substituted with neutral or electron‐donating substituents of the aryl group, while those with electron‐withdrawing substituents favor the other diastereoisomer. …”
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    Influence of Achiral Phosphine Ligands on a Synergistic Organo‐ and Palladium‐Catalyzed Asymmetric Allylic Alkylation
  13. 2633
    “…In this paper, we report metallic iron particles with an electron-donating material as a catalyst for ammonia synthesis. …”
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    Low-Temperature Ammonia Synthesis on Iron Catalyst with an Electron Donor
  14. 2634
    “…The existing examples require either a strong π‐donating group or an extra ligand for B‐coordination, which nevertheless suppresses or completely turns off the Lewis acidity. …”
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    Boosting Ring Strain and Lewis Acidity of Borirane: Synthesis, Reactivity and Density Functional Theory Studies of an Uncoordinated Arylborirane Fused to o‐Carborane
  15. 2635
    “…Our activation strain analyses reveal that the base accelerates the DA reaction via two distinct electronic mechanisms: i) by the HOMO‐raising effect, which enhances the normal electron demand orbital interaction; and ii) by donating charge into 3‐hydroxy‐2‐pyrone which accumulates in its reactive region and promotes strongly stabilizing secondary electrostatic interactions with N‐methylmaleimide.…”
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    How Bases Catalyze Diels‐Alder Reactions
  16. 2636
    “…The scope of the method is more than 30 examples, including compounds with both electron-withdrawing and electron-donating groups, as well as diverse functionalities. …”
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    Synthesis of 3-(Pyridin-2-yl)quinazolin-2,4(1H,3H)-diones via Annulation of Anthranilic Esters with N-pyridyl Ureas †
  17. 2637
    “…We describe the case of a platelet donor who developed an allergy, while donating at a transfusion facility, due to an ethylene oxide-sterilized apheretic kit. …”
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    Does First-Use Syndrome Happen During Apheresis? A Case Report
  18. 2638
    “…The aromaticity measured by HOMA and NICS(1)(zz) indices is increased by π-electron-donating substituents whereas π-electron-withdrawing substituents decrease the calculated aromatic character and ultimately lead to non-planar boat or chair structures. …”
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    DFT Study of 1,4-Diazonium-3,6-diolates: Monocyclic Representatives of Unexplored Semi-Conjugated Heterocyclic Mesomeric Betaines
  19. 2639
    “…XPS and DFT calculations revealed that the sulfonic acid group of SMKL had an electron-donating ability and was easily adsorbed on the positively charged surface of calcite, which hindered the adsorption of sodium oleate on calcite. …”
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    Improved Flotation Separation of Scheelite from Calcite by Sulfomethylated Kraft Lignin
  20. 2640
    por Deng, Longfei, Liang, Ping, Cui, Hongjuan
    Publicado 2022
    “…Over the past two decades, increasing studies have shown that lentiviral vectors (LVs) modified with different glycoproteins from a donating virus, a process referred to as pseudotyping, have altered tropism and display cell-type specificity in transduction, leading to selective tumor cell killing. …”
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    Pseudotyped lentiviral vectors: Ready for translation into targeted cancer gene therapy?
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