“…The combination of electron-withdrawing or electron-donating functions in the organic spacers with suitable solvothermal synthesis conditions allowed modulating the structuration level (2D or 3D), vacancies, physico-chemical properties and Lewis acidity strength of the metal–organic structures. …”
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“…In vitro cytotoxicity study on all synthesized compounds demonstrated that introduction of the aryl chain in the R(3) as well as the low electron-donating group in the R(1) of DHPMs contributed to the anti-proliferative potency. …”
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“…Control of the reactivity of hydride (H(–)) in crystal structures has been a challenge because of its strong electron-donating ability and reactivity with protic species. …”
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“…Therefore, a reconsideration was assigned to the possible capacity of oxidative enzymes and the respective challenges encountered during their applications in wastewater treatment, and ultimately, the prospects of laccase, a polyphenol oxidase that oxidizes aromatic and inorganic substrates with electron-donating groups in treatment aromatic contaminants of wastewater, in real wastewater situations, since it is assumed to be a vehicle for a greener community. …”
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“…In this methodology, the surface of graphene oxide is modified using the amine functional groups which help stabilization and distribution of Pd NPs very well and increases the surface electron density of NPs by electron donating from amine groups. This developed catalyst shows a high catalytic activity toward the Suzuki coupling and carbonylative Suzuki–Miyaura coupling reactions at mild reaction conditions. …”
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“…The infrared absorbance showed the existence of intermolecular hydrogen bonds between the PCL’s carbonyl groups and the GO’s hydrogen-donating groups, which is in line with the apparent reduction in molecular weight at higher GO contents, indicated by the results of the gel permeation chromatography (GPC), and the thermal property analysis. …”
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“…Empathic concern was also related to donating a larger proportion of earnings to charity after the MRI session. …”
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“…The formation of the dihydro analogs correlated with the electron density on the aromatic ring: Electron-donating groups favored the 4H- benzo[d][1,3]oxazin-4-ones, while electron-withdrawing groups tended to favor the dihydro product. …”
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“…Here, we show that the formate dehydrogenase electron-donating complex, FdnGHI, also clusters at the cell poles under nitrate-respiring conditions. …”
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“…The compounds exhibited potency that increased with increasing electron donating group in p-position (OH > OMe > Cl) due to extended conjugated systems. …”
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“…In line with this, various C-5-substituted 2,7-anhydrosialic acid derivatives bearing both electron-donating and -withdrawing protecting groups were synthesized and subjected to different Lewis acid-catalyzed solvent-free ring-opening reactions at room temperature in the presence of acetic anhydride. …”
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“…The LC separator enables abundant electron-donating groups and is expected to induce chemical binding of polysulfides to hinder the shuttle effect. …”
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“…Synthetic chemists have integrated different electron donating and electron withdrawing groups to realize these complex molecular systems. …”
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“…We have substituted the 5th and 5′th positions of the acceptor unit and the 2nd position of the donor unit with various electron-withdrawing and electron-donating groups to study various structural and electronic properties of the compounds. …”
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“…This protocol was successfully employed for the synthesis of various flavoring ketones such as raspberry ketone and ginger ketone with almost complete conversion and 82% isolated yield. The para-donating groups on the benzylic alcohol showed a high rate of reaction. …”
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“…The antimicrobial action expanded by expanding the electron donating group in position 2 and 5 for Pyrido[2,3-d]pyrimidin-4-one core. …”
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“…The description of substituents as electron donating or withdrawing leads to a perceived dominance of through‐bond influences. …”
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“…This is the first computational study that maps the conformational change to the preferential hydrogen bond donating capacity of one of the secondary hydroxyl groups of CD, in consensus with an NMR experiment. …”
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“…I mention that as a coronavirus convalescent, I am donating plasma regularly.…”
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“…Selectivity is therefore based on similar electronic factors to classical S(N)Ar chemistry, which implies the destabilisation of transition states featuring electron‐donating groups in either ortho or para positions. …”
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