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3041“…Due to the strong electron-donating ability of the DTP-based fused-ring core, SNIC-F showed a strong intramolecular-charge transfer (ICT) effect and thus gave a narrow band gap of 1.32 eV. …”
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3042“…The effects of substituting electron withdrawing and electron donating functional groups on the electronic and optical properties of angular naphthodithiophene (aNDT) were studied. …”
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3043por Vasić, Jelena, Dimić, Dušan, Antonijević, Marko, Avdović, Edina H., Milenković, Dejan, Nakarada, Đura, Dimitrić Marković, Jasmina, Molnar, Maja, Lončarić, Melita, Bešlo, Drago, Marković, Zoran“…Four 3-methoxycarbonylcoumarin derivatives with substituents of different electron-donating/electron-withdrawing abilities (Br, NO(2), OH, and OMe) were investigated structurally by NMR, IR, and UV-VIS spectroscopies and density functional theory methods. …”
Publicado 2023
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3044por Hadjikyprianou, Eleni, Petrides, Sotiris, Kourtellaris, Andreas, Tasiopoulos, Anastasios J., Georgiades, Savvas N.“…The nature of the azachalcone substituent played a significant role in the reactivity of the dienophiles, with electron-withdrawing (EW) substituents enhancing conversion and electron-donating (ED) ones exhibiting the opposite effect. …”
Publicado 2023
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3045“…These compounds are potential antioxidants due to their capabilities such as scavenging free radicals, donating hydrogen atoms, and chelating metal cations. …”
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3046“…UV-vis absorption titrations were used to measure the relationship between the association constant for formation of this complex and the H-bond acceptor properties of the pyridine involved in the intramolecular H-bond. Electron-donating substituents on the pyridine increase the strength of the intermolecular H-bond between PFTB and the amide. …”
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3047“…The developed protocol can be extended to various substituted benzyl alcohols having both the electron withdrawing and electron donating groups to afford moderate to excellent yield of the products. …”
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3048por Grimm, Jonathan B., Tkachuk, Ariana N., Patel, Ronak, Hennigan, S. Thomas, Gutu, Alina, Dong, Peng, Gandin, Valentina, Osowski, Anastasia M., Holland, Katie L., Liu, Zhe J., Brown, Timothy A., Lavis, Luke D.“…We discovered that the auxochrome substituent strongly affects the lactone–zwitterion equilibrium, providing a roadmap for the rational design of improved rhodamine dyes. Electron-donating auxochromes, such as julolidine, work in tandem with fluorinated pendant phenyl rings to yield bright, red-shifted fluorophores for live-cell single-particle tracking (SPT) and multicolor imaging. …”
Publicado 2023
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3049“…Moreover, while push–pull combinations enhance the NLO contrast for both redox switches, they prefer a different arrangement in terms of electron-donating and electron-withdrawing functional groups. …”
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3050por Kincaid, Kristi, Beckman, Jeff, Zivkovic, Aleksandra, Halcomb, Randall L., Engels, Joachim W., Kuchta, Robert D.“…The bases consisted of a benzimidazole ring with one or two exocyclic substituent(s) that are either electron-donating (methyl and methoxy) or electron-withdrawing (trifluoromethyl and dinitro). …”
Publicado 2005
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3051“…Each virus produced was identical with the virus donating RNA, in (a) neutralization by homotypic antiserum, (b) resistance to ribonuclease treatment, and (c) failure to be adsorbed or replicated by nonprimate cells, even of the strain producing the virus from RNA. …”
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3052por Wu, Hong, Min, Jinrong, Lunin, Vladimir V., Antoshenko, Tatiana, Dombrovski, Ludmila, Zeng, Hong, Allali-Hassani, Abdellah, Campagna-Slater, Valérie, Vedadi, Masoud, Arrowsmith, Cheryl H., Plotnikov, Alexander N., Schapira, Matthieu“…We solved the structures of the catalytic domains of GLP, G9a, Suv39H2 and PRDM2, four of the eight known human H3K9 methyltransferases in their apo conformation or in complex with the methyl donating cofactor, and peptide substrates. We analyzed the structural determinants for methylation state specificity, and designed a G9a mutant able to tri-methylate H3K9. …”
Publicado 2010
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3053“…METHODOLOGY: The role of thioredoxin reductase 1 in RKO cells was evaluated by attenuating endogenous thioredoxin reductase 1 expression with siRNA and then either inducing a selenium-deficient thioredoxin reductase or treatment with distinct redox challenges including, hydrogen peroxide, an oxidized lipid, 4-hydroxy-2-nonenol, and a nitric oxide donating prodrug. Thioredoxin redox status, cellular viability, and effector caspase activity were measured. …”
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3054“…While research has been conducted on the priorities expressed by recipient communities, relatively less has been done to assess those of the donating country. To investigate people's beliefs about the disease burden in high-income countries, we compared publicly available data from U.S. surveys of people's perceptions of the leading causes of death in developing countries against measures of the actual disease burden from the World Health Organization. …”
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3055“…And the contents of unknown compounds (1), (2), (3), (4) and (5) in the HR were altered by fermentation. Electron donating activity (EDA, %) value of FHR was higher than HR for DPPH radical scavenging activity and H2O2 scavenging activity, respectively. …”
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3056por Haddad, Yara, Vallerand, Diane, Brault, Antoine, Spénard, Jean, Haddad, Pierre S.“…We explored the therapeutic effect of NCX 1000, a derivative of ursodeoxycholic acid (UDCA) with nitric oxide (NO) donating properties, alone or in combination with vitamin E, in an experimental model of NASH in the rat. …”
Publicado 2011
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3057por Barzegar, Abolfazl“…Altogether, the electron donating potency of DIP to reduce ferric ion, having the low anodic oxidation peak potential, producing long lived stable DIP(•) radicals and protecting myoblast cells from oxidation, proposed the excellent “chain-breaking antioxidant” potency via electron-transfer mechanism of this vasodilator DIP drug in polar aqueous medium.…”
Publicado 2012
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3058por Ziarani, Ghodsi Mohammadi, Faramarzi, Sakineh, Asadi, Shima, Badiei, Alireza, Bazl, Roya, Amanlou, Massoud“…DISCUSSION: The compounds with electron donating group and higher hydrophobic interaction with active site of enzyme prevents hydrolysis of substrate. …”
Publicado 2013
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3059por Cazares-Körner, Cindy, Pires, Isabel M., Swallow, I. Diane, Grayer, Samuel C., O’Connor, Liam J., Olcina, Monica M., Christlieb, Martin, Conway, Stuart J., Hammond, Ester M.“…Reduction of the bioreductive group nitro moiety, under hypoxic conditions, reveals an electron-donating substituent that leads to fragmentation of the molecule, affording the active inhibitor. …”
Publicado 2013
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3060“…The extract exhibited appreciable reducing power signifying hydrogen donating potential. DPPH radical scavenging assay revealed substantial free radical scavenging activity (42–90%) in the extracts. …”
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