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3141por Luo, Rongshuang, Wang, Zhongyuan, Luo, Dali, Qin, Yumei, Zhao, Chunshen, Yang, Di, Lu, Tian, Zhou, Zhixu, Huang, Zhuyan“…The structure-activity relationships (SARs) indicated that electron-donating groups (EDGs) on phenyl rings are beneficial for improving the antitumor activity; compounds with a hydroxyl substituent at the 2-position of phenyl ring exhibited superior activities than compounds with a substituent at the 4-position. …”
Publicado 2021
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3142“…Herein, we report that a spiropyran conjugated with a hydroxynaphthalene moiety (1) is a new member exhibiting solvent-driven isomerization, even bearing an electron-donating −OH moiety. The dye exists as a colorless spirocyclic (SP) form in nonpolar media. …”
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3143“…For an active semiconducting material of the PFETs, we employed cyclopentadithiophene-alt-benzothiadiazole (CDT-BTZ) that is a D-A-type-conjugated copolymer consisting of a repeated electron-donating unit and an electron-accepting unit, and the other two CDT-based D-A-type copolymer analogues are cyclopentadithiophene-alt-fluorinated-benzothiadiazole (CDT-FBTZ) and cyclopentadithiophene-alt-thiadiazolopyridine (CDT-PTZ). …”
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3144por Zhang, Qian“…Prosocial cartoon is characterized by helping others solve difficulties, including helping, donating, sharing, comforting, and cooperating. The current study examined whether viewing a prosocial cartoon decreases aggression immediately upon exposure and the potential mediating role of aggressive motivation. …”
Publicado 2021
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3145por Angelé-Martínez, Carlos, Goncalves, Leticia Christina Pires, Premi, Sanjay, Augusto, Felipe A., Palmatier, Meg A., Amar, Saroj K., Brash, Douglas E.“…We conclude that (i) the delocalized pi electron cloud that stabilizes the electron-donating activity of many common antioxidants allows the same molecule to prevent an electronically excited species from transferring its triplet-state energy to targets such as DNA and (ii) the most effective class of triplet-state quenchers appear to operate by energy diversion instead of electron donation and dissipate that energy by isomerization.…”
Publicado 2022
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3146por Ridley-Merriweather, Katherine E., Head, Katharine J., Younker, Stephanie M., Evans, Madeline D., Moore, Courtney M., Lindsey, Deidre S., Wu, Cynthia Y., Wiehe, Sarah E.“…Through activities that employed visual interactive tools to facilitate group discussion and self-reflection, the authors examined perspectives and motivations for Asian American women (N = 17) and Latinas (N = 14) toward donating their healthy breast tissue. Findings included three themes that, while common to both groups, were unique in how they were expressed: lack of knowledge concerning breast cancer risks and participation in clinical research, cultural influences in BC risk thinking, and how altruism relates to perceived personal connection to breast cancer. …”
Publicado 2022
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3147por Mantri, Neha, Goel, Akhil D, Joshi, Nitin K, Bhardwaj, Pankaj, Gautam, Vaishali, Gupta, Manoj K“…BACKGROUND: Breastmilk is the baby’s “first vaccine”. Donated human milk (DHM) is the next best alternative when a mother’s milk is not available, as recommended by WHO- UNICEF. …”
Publicado 2022
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3148por Jachak, Mahesh, Bhise, Rupali, Chaturvedi, Ankur, Kamble, Vidula, Shankarling, Ganapati“…This article presents two highly fluorescent donor-π-acceptor (D-π-A) moieties containing an electron-donating carbazole and phenothiazine donors fused with electron-withdrawing pyrrolo-quinoline acceptor dyes, PQC and PQPT. …”
Publicado 2022
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3149por Liu, Yaoyang, Liu, Sheng, Liu, Zhibin, Zhao, Chuang, Li, Chunhui, Zhou, Yu, Jiao, Caishan, Gao, Yang, He, Hui, Zhang, Shaowen“…The electrostatic potential of the ligands indicated that the electron-donating ability of the amide O atoms in L(II) displayed certain differences compared with L(I). …”
Publicado 2021
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3150“…Fluorine is the smallest electron-withdrawing group with an induction effect, but can also act as an electron-donating group owing to its conjugation effect. When the conjugation effect is dominant, the electron-withdrawing ability of additional acceptor DFBT decreases instead. …”
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3151por Waki, Minoru, Shirai, Soichi, Yamanaka, Ken-ichi, Maegawa, Yoshifumi, Inagaki, Shinji“…Efficient photocatalytic water oxidation was achieved by tuning the photochemical properties of the Ru complexes on the BPy-PMO through the incorporation of electron-donating or electron-withdrawing functionalities. The reaction turnover number based on the amount of the Ru complex was improved to 20, which is higher than values previously obtained from PMO systems acting as water oxidation photocatalysts.…”
Publicado 2020
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3152por Rakesh, K. P., Vivek, H. K., Manukumar, H. M., Shantharam, C. S., Bukhari, S. N. A., Qin, Hua-Li, Sridhara, M. B.“…The present investigations demonstrated that compounds 17, 20, 25 and 26 possessing the presence of electron donating (OH and OCH(3)) groups on the phenyl rings are highly potent; whereas compounds 9, 10, 15, 16, 18, 33 and 36 showed moderate activity against Gram-negative bacteria. …”
Publicado 2018
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3153por Kielesiński, Łukasz, Deperasińska, Irena, Morawski, Olaf, Vygranenko, Kateryna V., Ouellette, Erik T., Gryko, Daniel T.“…Arrangement of the electron-donating amino groups at diverse positions on this heterocyclic skeleton makes it possible to obtain π-expanded coumarins with emission either sensitive to, or entirely independent of, solvent polarity with large Stokes shifts. …”
Publicado 2022
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3154“…For the ligand AQ, ortho-selectivity is proposed to be attributed to the decreased steric hindrance and increased electron donating effect of AQ (8-aminoquinoline) which promotes proton-transfer in the ortho-transition state of C–H activation. …”
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3155por Wu, Yu, Ma, Zongchen, Mai, Xiaoyuan, Liu, Xiaoling, Li, Pinglin, Qi, Xin, Li, Guoqiang, Li, Jing“…Most of the derivatives showed stronger antitumor activity and we found that the introduction of electron-donating groups at position C-2 of unsaturated piperidine was beneficial to anticancer activity and unsaturated piperidine was responsible for the antiproliferative activity. …”
Publicado 2022
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3156“…PNDI5 and PNDI10, corresponding to 5% and 10% molar concentrations of DCB, respectively, showed lower crystallization and good miscibility with PBDB-T, a widely used electron-donating copolymer, than the terpolymer based on DCB-free N2200. …”
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3157“…The evidence highlights the need to inform the population about the characteristics of sustainable clothing that positively affect purchase and post-purchase actions such as buying secondhand clothing, repairing, exchanging and donating clothing. This study also suggests that it is important to strengthen the relationship between sustainability and clothing quality among older generations and men.…”
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3158por Ruamps, Mirko, Bastin, Stéphanie, Rechignat, Lionel, Sournia-Saquet, Alix, Vendier, Laure, Lugan, Noël, Mouesca, Jean-Marie, Valyaev, Dmitry A., Maurel, Vincent, César, Vincent“…The mono-oxidation event for these complexes occurs on the NHC ligand, with a spin density mainly located on the diaminoethylene NHC-backbone, and has a dramatic effect on the donating properties of the NHC ligand. Conversely, as the Mn(I) center in the complex [MnCp(CO)(2) ((IMes((NMe2)2))] is easily oxidizable, the latter complex is first oxidized on the metal center to form the corresponding cationic Mn(II) complex, and the NHC ligand is oxidized in a second reversible oxidation wave.…”
Publicado 2022
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3159por Majeed, Shumaila, Waseem, Muhammad Tahir, Junaid, Hafiz Muhammad, Khan, Gul Shahzada, Nawazish, Shamyla, Mahmood, Tariq, Khan, Asad Muhammad, Shahzad, Sohail Anjum“…Rational modification of molecular structure by incorporating electron donating groups can play a potential role for designing aggregation induced emission (AIE) active fluorescent probes. …”
Publicado 2022
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3160“…A series of acyclic and cyclic ylidyltetrylenes featuring various α‐substituents with different σ‐ and π‐donating capabilities have been investigated which demonstrate that particularly π‐accepting boryl groups lead to beneficial properties and low barriers for single‐site activation reactions, above all in the case of silylenes. …”
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