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3261“…The influence of electron‐donating substituents (OSiMe(3), OPt‐Bu(2), N‐piperidinyl), electron‐withdrawing (OTf, 3,5‐bis‐trifluoromethyl‐phenyl), and of electron‐rich π‐conjugated (2‐thienyl, 4‐tert‐butylphenyl, trimethylsilyl‐ethynyl) substituents on optoelectronic and structural properties of these functionalized DDPs has been investigated via XRD analyses, UV/Vis, PL spectroscopy, and by electroanalytical CV. …”
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3262por Rizwan, Komal, Rasool, Nasir, Hashmi, Muhammad Ali, Noreen, Sadia, Zubair, Muhammad, Arshad, Mahwish, Shah, Syed Adnan Ali“…A series of (E)-4-bromo-N-((3-bromothiophen-2-yl)methylene)-2-methylaniline analogs synthesized in considerable yields through Suzuki cross-coupling reactions. Various electron donating and withdrawing functional moieties were successfully incorporated under the employed reaction conditions. …”
Publicado 2021
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3263por Li, Jie, Gong, Heqi, Zhang, Jincheng, Liu, Hui, Tao, Li, Wang, Yanqing, Guo, Qiang“…Herein, 2,5,8-tris(di(4-fluorophenyl)amine)-1,3,4,6,7,9,9b-heptaazaphenalene (HAP-3FDPA) was designed as an electron acceptor by integrating three bis(4-fluorophenyl)amine groups into a heptazine core, while 1,3-di(9H-carbazol-9-yl)benzene (mCP) possessing two electron-donating carbazole moieties was chosen as the electron donor. …”
Publicado 2021
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3264por Warchoł, Jolanta Karolina, Sobolewska, Paulina, Tylus, Włodzimierz, Petrus, Roman“…The XPS analysis reveals Cr(VI) reduction to a less-toxic Cr(III) by the electron donating N-containing groups and by reaction with Fe(+2) ions on the zeolite external surface.…”
Publicado 2021
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3265por Bernardes, Samuel C., von Rintelen, Kristina, von Rintelen, Thomas, Pepato, Almir R., Page, Timothy J., de Bruyn, Mark“…We conclude that ecological transformations have presented opportunities for the establishment of migrants. The role of donating and receiving migrants has shifted several times according to these transformations. …”
Publicado 2021
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3266por Sohail, Muhammad, Altalhi, Tariq, Al-Sehemi, Abdullah G., Taha, Taha Abdel Mohaymen, S. El-Nasser, Karam, Al-Ghamdi, Ahmed A., Boukhari, Mahnoor, Palamanit, Arkom, Hayat, Asif, A. Amin, Mohammed, Nawawi Bin Wan Ismail, Wan Izhan“…Herein, we propose a novel and feasible strategy to incorporate dihydroxy benzene (DHB) as a conjugated monomer within the framework of urea containing CN (CNU-DHBx) to tune the electronic conductivity and charge separation due to the aromaticity of the benzene ring, which acts as an electron-donating species. Systematic characterizations such as SPV, PL, XPS, DRS, and TRPL demonstrated that the incorporation of the DHB monomer greatly enhanced the photocatalytic CO(2) reduction of CN due to the enhanced charge separation and modulation of the ionic mobility. …”
Publicado 2021
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3267“…Results showed that greater self-reported positive health behaviors (e.g., wearing a facemask, distancing from others) was related to decreased depressive symptoms over time, whereas greater self-reported prosocial behaviors (e.g., donating time or money, thanking an essential worker) was related to decreased loneliness over time. …”
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3268“…Although most studies of MtrCAB-mediated EET have been conducted in Shewanella oneidensis MR-1, recent investigations in Vibrio and Aeromonas species have revealed that the electron-donating proteins that support MtrCAB in Shewanella are not as representative as previously thought. …”
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3269por Tan, Zhi-Rong, Xing, Yu-Qin, Cheng, Jing-Zhao, Zhang, Guang, Shen, Zhao-Qi, Zhang, Yu-Jie, Liao, Guangfu, Chen, Long, Liu, Shi-Yong“…Systematic studies reveal that the enhanced water wettability by the integration of polar BSO(2) with hydrophilic EDOT, the increased electron-donating ability by O–C p–π conjugation, the improved electron transfer by D–A architecture, broad light harvesting, and the nano-sized colloidal character in a H(2)O/NMP mixed solvent rendered BSO(2)–EDOT as one of the best CP photocatalysts toward PHP.…”
Publicado 2022
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3270por Shafran, Yuri M., Hussein, Aqeel A., Beliaev, Nikolai A., Shevyrin, Vadim A., Shityakov, Sergey, Beryozkina, Tetyana V., Bakulev, Vasiliy A.“…On one hand, the electron-donating methyl or methoxy group in the aryl para-position of arylsulfonyl azides favors the production of NH-1,2,3-triazoles together with sulfonamides. …”
Publicado 2022
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3271“…The inclusion of electron-donating groups resulted in a lower optical band gap of the produced dye sensitizers, with “push–pull” promotion of about 1.55 eV. …”
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3272“…It could be inferred that the combination of para- and meta-, as well as the modification of the electron-donating moieties, led to the improvement in potency. …”
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3273por Kushvaha, Saroj Kumar, Francis, Maria, Kumar, Jayasree, Nag, Ekta, Ravichandran, Prathap, Roy, Sudipta, Chandra Mondal, Kartik“…The challenging ligand fields containing mono/di-anionic O(2)N donating atoms and/or chloride ions stabilized the pentacoordinate Ni(ii) ions in 1–2 upon controlling the experimental conditions. …”
Publicado 2021
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3274por Nazir, Uzma, Akhter, Zareen, Janjua, Naveed Kausar, Adeel Asghar, Muhammad, Kanwal, Sehrish, Butt, Tehmeena Maryum, Sani, Asma, Liaqat, Faroha, Hussain, Rizwan, Shah, Faiz Ullah“…Fcub and Fcuc showed better anticorrosion efficiency as compared with Fcua due to the electron donating methoxy and ethoxy group substitutions, respectively. …”
Publicado 2020
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3275“…Substituents alter the electron density distribution in benzene in various ways, depending on their electron withdrawing and donating capabilities, as summarized by the empirical Hammett equation. …”
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3276por Tigreros, Alexis, Aranzazu, Sandra-L., Bravo, Nestor-F., Zapata-Rivera, Jhon, Portilla, Jaime“…In this study, a family of pyrazolo[1,5-a]pyrimidines (PPs) 4a–g has been identified as strategic compounds for optical applications due to several key characteristics such as their simpler and greener synthetic methodology (RME: 40–53%) as compared to those of BODIPYS (RME: 1.31–17.9%), and their tunable photophysical properties (going from ε = 3320 M(−1) cm(−1) and ϕ(F) = 0.01 to ε = 20 593 M(−1) cm(−1) and ϕ(F) = 0.97), in which electron-donating groups (EDGs) at position 7 on the fused ring improve both the absorption and emission behaviors. …”
Publicado 2020
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3277por He, Xinyi, Zhang, Haoyun, Nose, Takumi, Katase, Takayoshi, Tadano, Terumasa, Ide, Keisuke, Ueda, Shigenori, Hiramatsu, Hidenori, Hosono, Hideo, Kamiya, Toshio“…The large‐size Te ion in Sn(Se(1−) (x) Te (x) ) forms weak Sn—Te bonds, leading to the high‐density formation of hole‐donating Sn vacancies and the reduced phonon frequency and enhanced phonon scattering. …”
Publicado 2022
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3278por Fiodorova, Irina, Serevičius, Tomas, Skaisgiris, Rokas, Juršėnas, Saulius, Tumkevicius, Sigitas“…Simple modification of the molecular structure of TADF compounds through the selection of different electron-donating or accepting fragments opens great possibilities to tune the emission properties and rates. …”
Publicado 2022
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3279“…Our calculated results also reveal that compounds with electron donating substituents at the acceptor units show higher value of λ(max). …”
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3280por Lee, Geonho, Park, Jongwook, Jang, Seong Hyun, Lee, Sang Yoon, Seong, Jihyun, Jung, Jae Woong, Kim, Kyobum, Hwang, Tae Gyu, Choi, Jun“…The optimally prepared nanoparticles from 3,6-bis(4-((E)-4-(bis(40-(1,2,2-triphenylvinyl)-[1,10-biphenyl]-4-yl)amino)styryl)phenyl)-2,5-dihexyl-2,5-dihydropyrrolo[3,4-c]pyrrole-1,4-dione (DP-R2) with two functional groups having aggregation-induced emission properties and additional donating groups at the end of the triphenylamine groups were considered to have the greatest potential as a fluorescent probe for bioimaging. …”
Publicado 2022
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