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3381“…Herein, we present a novel polymer architecture based on poly(2-oxazoline)s bearing protected thiol functionalities, which can be selectively liberated by irradiation with UV light. Whereas free thiol groups can suffer from oxidation or other spontaneous reactions that degrade polymer performance, this strategy with masked thiol groups offers the possibility of photodeprotection on demand with spatio-temporal control while maintaining polymer integrity. …”
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3382“…The second and third transitions were associated with the Industrial Revolution and with market liberalization, global trade and automation, respectively. …”
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3383por Ovchinnikov, Stepan V, Bikmetov, Dmitry, Livenskyi, Alexei, Serebryakova, Marina, Wilcox, Brendan, Mangano, Kyle, Shiriaev, Dmitrii I, Osterman, Ilya A, Sergiev, Petr V, Borukhov, Sergei, Vazquez-Laslop, Nora, Mankin, Alexander S, Severinov, Konstantin, Dubiley, Svetlana“…Under stress conditions, the antitoxin is degraded liberating the active toxin. Though thousands of various toxin–antitoxins pairs have been predicted bioinformatically, only a handful has been thoroughly characterized. …”
Publicado 2020
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3384“…NLRP1 and CARD8 activators induce the proteasome‐mediated destruction of the N‐terminal fragment, liberating the C‐terminal fragment to form an inflammasome. …”
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3385“…The dominance of the concerted mechanism can be explained through the specific structure of the key transition state, avoiding the liberation of the highly reactive, and thus unstable carbene lone pair, whereas activating the substrate through hydrogen‐bonding interactions. …”
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3386por Imam, Ashraf, Tzukert, Keren, Merhav, Hadar, Imam, Riham, Abu-Gazala, Samir, Abel, Roy, Elhalel, Michal Dranitzki, Khalaileh, Abed“…Nevertheless, we should reassess the need for induction therapy across the board for ordinary patients and the more liberal use of mammalian target of rapamycin inhibitors in transplant patients with proven infection.…”
Publicado 2020
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3387“…Acid dissociation, and thus liberation of excess protons in small water droplets, impacts on diverse fields such as interstellar, atmospheric or environmental chemistry. …”
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3388por Stanley, Phiona“…The paper is theorized with reference to postcolonial theory, critical medical ethics, and liberation theology.…”
Publicado 2021
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3389por McGregor, Nicholas G. S., Turkenburg, Johan P., Mørkeberg Krogh, Kristian B. R., Nielsen, Jens Erik, Artola, Marta, Stubbs, Keith A., Overkleeft, Herman S., Davies, Gideon J.“…α-l-Arabinofuranosidases from glycoside hydrolase family 51 use a stereochemically retaining hydrolytic mechanism to liberate nonreducing terminal α-l-arabinofuranose residues from plant polysaccharides such as arabinoxylan and arabinan. …”
Publicado 2020
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3390por Sugiyama, Atsushi, Miura, Makoto, Oshikiri, Yoshinobu, Kim, Yena, Morimoto, Ryoichi, Miura, Miki, Osaka, Tetsuya, Mogi, Iwao, Yamauchi, Yusuke, Aogaki, Ryoichi“…As a result, from the pair annihilation of the vacancies with opposite signs, beyond 7 T, excess heat production up to 25 kJ·mol(−1) in average at 15 T was observed, which was attributed to the liberation of the solvation energy stored in a pair of the vacancy cores with a 0.32 nm radius, i.e., 112 kJ·mol(−1). …”
Publicado 2020
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3391por Hawkins, W. Anthony, Smith, Susan E., Newsome, Andrea Sikora, Carr, John R., Bland, Christopher M., Branan, Trisha N.“…Hypervolemia and volume overload are associated with organ dysfunction, delayed liberation from mechanical ventilation, and increased mortality. …”
Publicado 2019
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3392por Mendes, Renata de S., Pelosi, Paolo, Schultz, Marcus J., Rocco, Patricia R. M., Silva, Pedro L.“…The use of conservative as compared to liberal fluid strategies may increase the number of ventilator-free days and survival, as well as reduce organ dysfunction. …”
Publicado 2020
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3393“…An appealing antiviral drug target is the coronavirus 3C-like protease (3CLpro) that is responsible for the processing of the viral polyproteins and liberation of functional proteins essential for the maturation and infectivity of the virus. …”
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3394por Yao, Shenglai, Szilvási, Tibor, Xiong, Yun, Lorent, Christian, Ruzicka, Ales, Driess, Matthias“…Remarkably, upon one‐electron reduction of 2 with C(8)K and liberation of N(2) and adamantane, the two silylene subunits are regenerated to furnish the isolable bis(silylene)‐stabilized N(I) complex as an anion of 3 with the nido‐C(2)B(10) cluster cage. …”
Publicado 2020
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3395“…On heating each complex, the primary thermal events were dehydration and liberation of the respective phenolic acid component, the mass loss for the latter step enabling determination of the host-guest stoichiometry. …”
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3396por Walters, Jessica L. H., Anderson, Amanda L., Martins da Silva, Sarah J., Aitken, R. John, De Iuliis, Geoffry N., Sutherland, Jessie M., Nixon, Brett, Bromfield, Elizabeth G.“…Through pharmacological inhibition studies, we identified a protective role for phospholipase enzymes in the liberation of peroxidised polyunsaturated fatty acids from the human sperm membrane. …”
Publicado 2020
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3397“…However, in Study Two, the temporal framing condition interacted with political orientation to instead undermine the certainty about climate change among political liberals in the past-focused condition. Together, these studies present the first evidence of backfire from temporal frames, and do not support the efficacy of past comparisons for increasing conservatives’ environmentalism. …”
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3398“…The innovations include a vastly expanded repertoire of ion channels, the emergence of cilia and pseudopodia, endomembranes as intracellular capacitors, a flexible plasma membrane and the relocation of chemiosmotic ATP synthesis to mitochondria, which liberated the plasma membrane for more complex electrical signalling involved in sensing and reacting. …”
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3399“…On the other hand, the simultaneous introduction of the C(60) molecules and the liberation of the guest are produced by a single step wet procedure; the latter being potentially useful when materials that are not stable at high temperatures are employed for filling.…”
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3400por Abbasnezhad, Navideh, Kebdani, Mohamed, Shirinbayan, Mohammadali, Champmartin, Stéphane, Tcharkhtchi, Abbas, Kouidri, Smaine, Bakir, Farid“…This case includes simultaneously three mechanisms: burst-release, diffusion and osmotic pressure, identified beforehand here as being able to contribute to the drug liberation. For this purpose, authors coded the Sequential Quadratic Programming Algorithm to solve the problem of non-linear optimization. …”
Publicado 2021
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