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  1. 2021
    por Pekař, Miloslav
    Publicado 2022
    “…Even in the case of self-balancing diffusion, such extents do not directly replace reaction rates. Concentration changes caused by reactions (not by diffusion) are properly described by rates of independent reactions, which are instantaneous descriptors. …”
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    Reaction-Diffusion Systems: Self-Balancing Diffusion and the Use of the Extent of Reaction as a Descriptor of Reaction Kinetics
  2. 2022
    “…The synthetic protocol benefits largely from microwave (MW) activation, which enhances reaction rates. The mechanism has been interrogated with the aid of density functional theory (DFT) calculations, which sheds light into the origin of the regioselectivity and points to a predictive formulation of reactivity involving competing pathways of mesoionic cycloadditions.…”
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    Switchable Cycloadditions of Mesoionic Dipoles: Refreshing up a Regioselective Approach to Two Distinctive Heterocycles
  3. 2023
    “…The metabolic fluxome, which includes both intracellular and extracellular metabolic reaction rates (fluxes), therefore provides a powerful, integrated description of cellular phenotype. …”
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    Isotope-Assisted Metabolic Flux Analysis: A Powerful Technique to Gain New Insights into the Human Metabolome in Health and Disease
  4. 2024
    por Massimi, C., Altstadt, S., Andrzejewski, J., Audouin, L., Barbagallo, M., Bécares, V., Bečvář, F., Belloni, F., Berthoumieux, E., Billowes, J., Bisterzo, S., Bosnar, D., Brugger, M., Calviani, M., Calviño, F., Cano-Ott, D., Carrapiço, C., Castelluccio, D.M., Cerutti, F., Chiaveri, E., Cosentino, L., Chin, M., Clai, G., Colonna, N., Cortés, G., Cortés-Giraldo, M.A., Cristallo, S., Diakaki, M., Domingo-Pardo, C., Duran, I., Dressler, R., Eleftheriadis, C., Ferrari, A., Finocchiaro, P., Fraval, K., Ganesan, S., García, A.R., Giubrone, G., Gonçalves, I.F., González-Romero, E., Griesmayer, E., Guerrero, C., Gunsing, F., Hernández-Prieto, A., Jenkins, D.G., Jericha, E., Kadi, Y., Käppeler, F., Karadimos, D., Kivel, N., Koehler, P., Kokkoris, M., Kopecky, S., Krtička, M., Kroll, J., Lampoudis, C., Langer, C., Leal-Cidoncha, E., Lederer, C., Leeb, H., Leong, L.S., Lo Meo, S., Losito, R., Mallick, A., Manousos, A., Marganiec, J., Martínez, T., Mastinu, P.F., Mastromarco, M., Mendoza, E., Mengoni, A., Milazzo, P.M., Mingrone, F., Mirea, M., Mondelaers, W., Musumarra, A., Paradela, C., Pavlik, A., Perkowski, J., Pignatari, M., Piersanti, L., Plompen, A., Praena, J., Quesada, J.M., Rauscher, T., Reifarth, R., Riego, A., Robles, M.S., Rubbia, C., Sabaté-Gilarte, M., Sarmento, R., Saxena, A., Schillebeeckx, P., Schmidt, S., Schumann, D., Tagliente, G., Tain, J.L., Tarrío, D., Tassan-Got, L., Tsinganis, A., Valenta, S., Vannini, G., Van Rijs, I., Variale, V., Vaz, P., Ventura, A., Vermeulen, M.J., Vlachoudis, V., Vlastou, R., Wallner, A., Ware, T., Weigand, M., Weiß, C., Wynants, R., Wright, T., Žugec, P.
    Publicado 2017
    “…With this information experimental upper limits of the reaction rates for 22 Ne( α,n ) 25 Mg and 22 Ne( α,γ ) 26 Mg were established, potentially leading to a significantly higher (α,n)/(α,γ) ratio than previously evaluated. …”
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    Neutron spectroscopy of $^{26}$Mg states: constraining the stellar neutron source $^{22}$Ne($\alpha, n$)$^{25}$Mg
  5. 2025
    por Sengupta, Turbasu, Khanna, Shiv N.
    Publicado 2023
    “…Our calculation further reveals that by using this strategy, the barrier heights of CO(2) hydrogenation can be reduced to ~0.12 eV or possibly even lower, providing unique opportunities to control the reaction rates by using different combinations of donor/acceptor ligands.…”
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    Converting CO(2) to formic acid by tuning quantum states in metal chalcogenide clusters
  6. 2026
    “…As a novel and green technique, sonochemistry has emerged as a promising method for organic synthesis with several advantages over conventional methods, including enhancing reaction rates, improving yields, and reducing the use of hazardous solvents. …”
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    Synthesis of Imidazole-Based Molecules under Ultrasonic Irradiation Approaches
  7. 2027
    por Pulkkinen, Otto, Metzler, Ralf
    Publicado 2015
    “…We present a universal correction to the Michaelis-Menten equation for the reaction-rates. The relevance and validity of this correction for enzymatic reactions and intracellular gene-regulation is demonstrated. …”
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    Variance-corrected Michaelis-Menten equation predicts transient rates of single-enzyme reactions and response times in bacterial gene-regulation
  8. 2028
    “…Recently, the importance of quantifying temperature has been highlighted, as it correlates with biochemical reaction rates. Several methods for detecting intracellular temperature have recently been established. …”
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    Detection of Temperature Difference in Neuronal Cells
  9. 2029
    “…This combined approach reveals that, in the remainder layer, the β-stability has high correlation with node degree difference and overlapping coefficient. Moreover, when reaction rates are considered as node strength, we find that, at lower temperatures, nuclide half-life scales reciprocally with its out-strength. …”
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    Multilayer Network Analysis of Nuclear Reactions
  10. 2030
    “…Reaction pathways are effectively one dimensional and so long that they are observable in a microscope. Reaction rates are so slow that transitions are recorded on video. …”
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    Transition state theory demonstrated at the micron scale with out-of-equilibrium transport in a confined environment
  11. 2031
    “…We present an organocatalyst that is activated by a chemical signal, enabling temporal control over reaction rates and the formation of materials. Using self-immolative chemistry, we design a deactivated aniline organocatalyst that is activated by the chemical signal hydrogen peroxide and catalyses hydrazone formation. …”
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    Chemical signal activation of an organocatalyst enables control over soft material formation
  12. 2032
    “…This paper provides novel CRN designs for the construction of asynchronous logic, arithmetic and control flow elements based on a bi-molecular reaction motif with catalytic reactions and uniform reaction rates. We model and validate the designs for the deterministic and stochastic semantics using Microsoft’s GEC tool and the probabilistic model checker PRISM, demonstrating their ability to emulate the function of asynchronous components under low molecular count.…”
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    Chemical reaction network designs for asynchronous logic circuits
  13. 2033
    “…We modelled a system of reactions representing transitions between the conformational substates of the channel with parameters, concentrations of the substates and reaction rates extracted from simulations reported in the literature, based on electrophysiological recordings in a whole-cell configuration. …”
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    Hypothesized diprotomeric enzyme complex supported by stochastic modelling of palytoxin-induced Na/K pump channels
  14. 2034
    “…The efficiency of this approach has been compared to the previously established enzymatic regeneration system using the two auxiliary enzymes flavin reductase (PrnF) and alcohol dehydrogenase (ADH). The reaction rates of some of the tested mimics were found to exceed that of the enzymatic system. …”
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    Straightforward Regeneration of Reduced Flavin Adenine Dinucleotide Required for Enzymatic Tryptophan Halogenation
  15. 2035
    “…All azides show similar reaction rates with the sterically non‐demanding cyclooctyne BCN. …”
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    Chemoselectivity of Tertiary Azides in Strain‐Promoted Alkyne‐Azide Cycloadditions
  16. 2036
    “…Here, we predict growth of Arabidopsis thaliana accessions by employing genomic prediction of reaction rates estimated from accession-specific metabolic models. …”
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    Integrating molecular markers into metabolic models improves genomic selection for Arabidopsis growth
  17. 2037
    por Sočan, Jaka, Purg, Miha, Åqvist, Johan
    Publicado 2020
    “…The calculations yield temperature dependent reaction rates in good agreement with experiment, and also elicit the anomalous rate optimum for the cold-adapted enzyme, which occurs about 15 °C below the melting point. …”
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    Computer simulations explain the anomalous temperature optimum in a cold-adapted enzyme
  18. 2038
    “…In this paper, we present an automated method for estimating reaction rates in tethered molecular circuits that takes the geometry of the tethered species into account. …”
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    Structure sampling for computational estimation of localized DNA interaction rates
  19. 2039
    “…Reaction rates of common organic reactions have been reported to increase by one to six orders of magnitude in aqueous microdroplets compared to bulk solution, but the reasons for the rate acceleration are poorly understood. …”
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    Can electric fields drive chemistry for an aqueous microdroplet?
  20. 2040
    por Choi, K., Choi, Hoyun, Kahng, B.
    Publicado 2022
    “…Numerical simulations are performed on networks with reaction rates estimated from empirical data. The temporal pattern of the accumulated number of confirmed cases is then reproduced. …”
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    COVID-19 epidemic under the K-quarantine model: Network approach
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