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2081“…We find that perceived veracity significantly predicts how likely a user is to react, with higher perceived veracity leading to higher reaction rates. Additionally, we confirm that fake news is inherently more likely to be shared than other types of news. …”
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2082por Gemen, Julius, Białek, Michał J., Kazes, Miri, Shimon, Linda J.W., Feller, Moran, Semenov, Sergey N., Diskin-Posner, Yael, Oron, Dan, Klajn, Rafal“…We also studied the light-induced covalent dimerization of encapsulated anthracenes and found large effects of confinement on reaction rates. By coupling the photodimerization with the rapid guest exchange, we developed a new way to modulate fluorescence using external irradiation.…”
Publicado 2022
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2083“…A Langmuir–Hinshelwood mechanism is accounted to report reaction rates, half-lives, and reactive uptake coefficients for the system under variable relative humidity levels. …”
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2084“…Despite using only simple descriptors calculated from ground state wavefunctions, this model demonstrates excellent correlation with previously measured S(N)Ar reaction rates, and is able to accurately predict site selectivity for multihalogenated substrates: 91% prediction accuracy across 82 individual examples. …”
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2085“…We show that this method is applicable for the prediction of reaction rates for multielectron/multiproton transfer reactions, extending the findings from previous work focused on single electron/proton reactions.…”
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2086“…Our work identifies the key experimental parameters controlling reaction rates in pulsed heterogeneous catalysis and provides specific recommendations to explore its potential in real experiments, paving the way to a more energy-efficient and process-intensive operation of catalytic reactors.…”
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2087por Mitosch, Karin, Beyß, Martin, Phapale, Prasad, Drotleff, Bernhard, Nöh, Katharina, Alexandrov, Theodore, Patil, Kiran R., Typas, Athanasios“…By measuring label incorporation into Salmonella metabolites with liquid chromatography–mass spectrometry (LC–MS), and combining it with metabolic modeling, we identify relevant carbon sources used by Salmonella, uncover routes of their metabolization, and quantify relative reaction rates in central carbon metabolism. Our results underline the importance of the Entner–Doudoroff pathway (EDP) and the phosphoenolpyruvate carboxylase for intracellularly proliferating Salmonella. …”
Publicado 2023
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2088por Alshahrani, Saeed, Al-Majid, Abdullah Mohammed, Alamary, Abdullah Saleh, Ali, Mohamed, Altowyan, Mezna Saleh, Ríos-Gutiérrez, Mar, Yousuf, Sammer, Barakat, Assem“…An MEDT study of the key 32CA reaction between in situ generated azomethine ylide (AY) and chalcones explained the low reaction rates and the total selectivities observed. The supernucleophilic character of AY and the strong electrophilicity of chalcones favor these reactions through a highly polar two-stage one-step mechanism in which bond formation at the β-conjugated carbon of the chalcones is more advanced. …”
Publicado 2023
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2089“…With the advent of microwave equipment, heating by microwaves was rapidly introduced as standard method in organic chemistry laboratories, mainly because of the convenient possibility to operate at high temperature accompanied by accelerated reaction rates. In the present contribution we discuss the method of heating small, continuously operated reactors by passing electric current directly through the reactor wall as an enabling technology in organic chemistry. …”
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2090por Cardelli, Luca“…In particular we can determine statically that a complex network will emulate a simpler network: it will reproduce its kinetics for all corresponding choices of reaction rates and initial conditions. We use this property to relate the kinetics of many common biological networks of different sizes, also relating them to a fundamental population algorithm. …”
Publicado 2014
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2091por Schreck, John S., Ouldridge, Thomas E., Romano, Flavio, Šulc, Petr, Shaw, Liam P., Louis, Ard A., Doye, Jonathan P.K.“…These results should assist experimentalists in designing sequences to be used in DNA nanotechnology, by putting limits on the suppression of hybridization reaction rates through the use of hairpins and offering the possibility of deliberately increasing dissociation rates by incorporating hairpins into single strands.…”
Publicado 2015
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2092por Ebrahimi, Kourosh Honarmand, Hagedoorn, Peter-Leon, Jacobs, Denise, Hagen, Wilfred R.“…Accurate label-free methods or assays to obtain the initial reaction rates have significant importance in fundamental studies of enzymes and in application-oriented high throughput screening of enzyme activity. …”
Publicado 2015
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2093“…Use of a second nanosecond laser beam, adequately synchronized with the short laser pulse to produce a plasma target, further enhanced the reaction rates. High rates and chains of reactions are essential for most applications.…”
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2094por Baker, Angela K., Sauvage, Carina, Thorenz, Ute R., van Velthoven, Peter, Oram, David E., Zahn, Andreas, Brenninkmeijer, Carl A. M., Williams, Jonathan“…Significantly faster reaction rates allow chlorine radicals to expedite oxidation of hydrocarbons, including methane, and in polluted environments, to enhance ozone production. …”
Publicado 2016
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2095por Mellmer, Max A., Sanpitakseree, Chotitath, Demir, Benginur, Ma, Kaiwen, Elliott, William A., Bai, Peng, Johnson, Robert L., Walker, Theodore W., Shanks, Brent H., Rioux, Robert M., Neurock, Matthew, Dumesic, James A.“…The use of polar aprotic solvents in acid-catalyzed biomass conversion reactions can lead to improved reaction rates and selectivities. We show that further increases in catalyst performance in polar aprotic solvents can be achieved through the addition of inorganic salts, specifically chlorides. …”
Publicado 2019
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2096“…We present the laser and target conditions necessary to achieve these conditions and illustrate the system performance using three-dimensional particle-in-cell simulations, outline potential applications and calculate expected nuclear reaction rates in the D(d,n) and (12)C(p,γ) systems assuming CD, or CH aerogel foams.…”
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2097por Levin, Sune, Fritzsche, Joachim, Nilsson, Sara, Runemark, August, Dhokale, Bhausaheb, Ström, Henrik, Sundén, Henrik, Langhammer, Christoph, Westerlund, Fredrik“…However, they all have limitations such as low throughput, or that they require very low reactant concentrations and/or reaction rates. In response, we present a nanofluidic device for highly parallelized single nanoparticle catalysis in solution, based on fluorescence microscopy. …”
Publicado 2019
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2098por Francàs, Laia, Corby, Sacha, Selim, Shababa, Lee, Dongho, Mesa, Camilo A., Godin, Robert, Pastor, Ernest, Stephens, Ifan E. L., Choi, Kyoung-Shin, Durrant, James R.“…The concentrations and reaction rates of the oxidised states accumulated during catalysis are determined. …”
Publicado 2019
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2099por Shahzad, Muhammad, Abdel-Aty, Abdel-Haleem, Attia, Raghda A.M., Khoshnaw, Sarbaz H.A., Aldila, Dipo, Ali, Mehboob, Sultan, Faisal“…This is an infectious disease and can be modeled as a system of non-linear differential equations with reaction rates. In this paper, we develop the models for coronavirus disease at different stages with the addition of more parameters due to interactions among the individuals. …”
Publicado 2021
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2100por Varlamov, Dmitriy A., Blagodatskikh, Konstantin A., Smirnova, Evgenia V., Kramarov, Vladimir M., Ignatov, Konstantin B.“…We found that the hybrid methods demonstrated higher sensitivity and assay reaction rates than those of the classic LAMP and PCR techniques and can be used to for SARS-CoV-2 detection. …”
Publicado 2020
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