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2441“…In addition, we apply simulative model checking using temporal logic property libraries, clustering and data analysis, over time series of reaction rates and metabolite concentrations. We extend this to consider the evolution of reaction-oriented properties of subnets over time, including dead subnets and functional subsystems. …”
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2442por Bahar, Burak, Schulz, Wade L., Gokhale, Amit, Spencer, Bryan R., Gehrie, Eric A., Snyder, Edward L.“…Over a 28‐month period we retrospectively analysed platelet utilisation, RBC transfusion trends, and transfusion reaction rates data from all transfused adult patients transfused at the Yale‐New Haven Hospital, New Haven, CT, USA. …”
Publicado 2019
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2443por Opuu, Vaitea, Nigro, Giuliano, Gaillard, Thomas, Schmitt, Emmanuelle, Mechulam, Yves, Simonson, Thomas“…Mutants predicted to have low activation free energies for MetAMP production were found to be active and the predicted reaction rates agreed well with the experimental values. …”
Publicado 2020
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2444por Jang, Wongi, Yun, Jaehan, Ludwig, Luke, Jang, Su Guan, Bae, Jae Young, Byun, Hongsik, Kim, Jun-Hyun“…Although the small supported AuNPs display slightly faster reaction rates than the large encapsulated AuNPs, the apparent activation energies (E(a)) of both composite particles are comparable, implying no obvious correlation with the size of guest AuNPs under the reaction conditions. …”
Publicado 2020
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2445“…Recently, CAs have gained a great deal of attention as biocatalysts for capturing CO(2) from industrial flue gases owing to their extremely fast reaction rates and simple reaction mechanism. However, their general application for this purpose requires improvements to stability at high temperature and under in vitro conditions, and reductions in production and scale-up costs. …”
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2446“…The oxidation products of penicillin G were identified by spectral analysis and spot tests as phenyl acetic acid, 2-formyl-5,5-dimethyl-thiazolidine-4-carboxlate ion, ammonium ion, and carbon dioxide. Reliance of reaction rates on temperature has been explored, and the activation and thermodynamic parameters were estimated and debated. …”
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2447por Zhao, Rui, Mogollón, José M., Abby, Sophie S., Schleper, Christa, Biddle, Jennifer F., Roerdink, Desiree L., Thorseth, Ingunn H., Jørgensen, Steffen L.“…This subsurface cell increase coincides with a markedly higher power supply driven mainly by intensified anammox reaction rates, thereby providing a quantitative link between microbial proliferation and energy availability. …”
Publicado 2020
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2448“…Employing a (13)C‐labeled model, the individual steps of the oxidation sequence could be observed directly by NMR, and the activation energy for the rotation could be estimated to be approximately 2.8 kcal/mol. Reaction rates were solvent dependent, with polar solvents exerting a stabilizing effect on the zwitterion. …”
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2449por Jordan, Jack W., Fung, Kayleigh L. Y., Skowron, Stephen T., Allen, Christopher S., Biskupek, Johannes, Newton, Graham N., Kaiser, Ute, Khlobystov, Andrei N.“…Kinetic analysis enabled by controlled variation of the electron flux in TEM revealed the reaction to be highly flux-dependent, which leads to reaction rates too fast to follow under the standard TEM imaging conditions. …”
Publicado 2021
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2450“…(13)C metabolic flux analysis (MFA) has become an indispensable tool to measure metabolic reaction rates (fluxes) in living organisms, having an increasingly diverse range of applications. …”
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2451“…This work predicts that the two substrates will react with different reaction rates due to accessibility differences of the substrates to the active oxidant, and, as a consequence, these two substrates will also generate different products. …”
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2452“…However, the current ex-planta production approaches have been limited due to slow enzyme kinetics and traditionally laborious genetic engineering methods and require further optimization and development to address the required titers, reaction rates and yield for commercial application. With recent progress in metabolic engineering and the availability of advanced synthetic biology tools, it is envisaged that highly efficient heterologous hosts will soon be engineered to fulfill the growing market demand.…”
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2453“…KCNQ1 inhibition reduced sperm motility, acrosome reaction rates, and protein tyrosine phosphorylation but had no effect on hyperactivation. …”
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2454por Xu, Huixin, Li, Yue, Guo, Jianming, Sui, Yuan, Chen, Baihui, Li, Dalin, Jiang, Jiakang“…OBJECTIVE: To use meta-analysis to systematically compare the efficacy and adverse reaction rates of albumin paclitaxel and docetaxel in the treatment of breast cancer. …”
Publicado 2021
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2455por Vilcocq, Léa, Paez, Ana, Freitas, Victoria D. S., Veyre, Laurent, Fongarland, Pascal, Philippe, Régis“…In a first kinetic approach, a simplified kinetic model was built to compare quantitatively intrinsic reaction rates of both catalysts. The kinetic constant for hydrogenation was 20 times higher for Ru/TiO(2)-R at 120 °C.…”
Publicado 2021
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2456por Xiong, Zhi-bo, Ning, Xing, Zhou, Fei, Yang, Bin, Tu, Yan-wu, Jin, Jing, Lu, Wei, Liu, Zong-hao“…The enhancement in citric acid content is beneficial to improve the SCR reaction rates normalized by the surface area of the catalyst. …”
Publicado 2018
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2457por Chambers, Matthew S., Hunter, Robert D., Hollamby, Martin J., Pauw, Brian R., Smith, Andrew J., Snow, Tim, Danks, Ashleigh E., Schnepp, Zoe“…In this paper, we use in situ wide- and small-angle X-ray scattering (wide-angle X-ray scattering (WAXS) and small-angle X-ray scattering (SAXS)) to demonstrate that the overlapping phases are indeed due to variable reaction rates. While the initial oxide nanoparticles have a small range of diameters, the size range expands considerably and very rapidly during the oxide–nitride transition. …”
Publicado 2022
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2458“…The good-to-excellent yields of the desired products, satisfactory reaction rates, use of water solvent or solvent-free reaction medium, acceptable turnover numbers (TONs) and turnover frequencies (TOFs), along with comfortable recoverability and satisfying reusability of the as-prepared nanocatalyst for at least eight successive runs, and also easy work-up and purification procedures are some of the advantages of the current synthetic protocols.…”
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2459“…Few kinetic parameters, or reaction rates, are known up to date in detail about 1-chloro and 1-fluoro-2,4-dinitrobenzene (ClDNB and FDNB, respectively) with a series of biothiols in aqueous media. …”
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2460por Hahn, Gustavo Drügg, Golovics, Petra Anna, Wetwittayakhlang, Panu, Santa Maria, Dirlene Melo, Britto, Usiara, Wild, Gary Edward, Afif, Waqqas, Bitton, Alain, Bessissow, Talat, Lakatos, Peter Laszlo“…Infusion/injection reaction rates were more common on anti-TNFs (mean rate: 2.51 (CI 95% 1.7–3.4/100 pts-years; p = 0.02). and malignancy rates were higher on VDZ/UST (mean rate: 2.14 (CI 95% 1.6–2.8)/100 pts-years; p = 0.01). …”
Publicado 2022
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