“…At the same time, there are many polymerization reactions in thermal decomposition process, which may greatly affect the reaction rate and path. The higher the degree of polymerization, the larger equilibrium value of potential energy, the less energy release of thermal decomposition. …”
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“…Process optimization is achieved with a 2.4‐fold increased yield of 94±7 %, a 3.9‐fold increased reaction rate of 324±67 μm h(−1), and a coulombic efficiency of up to 68±7 %, while maintaining an excellent enantioselectivity of >99 %. …”
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“…The propagating polymer waves driven by reaction rate and persistent UV initiation are observed in situ. …”
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“…Under optimum conditions, the reaction rate, 6″-regioselectivity, and maximum substrate conversion were as high as 12.6 mM/h, 100%, and 100%, respectively. …”
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“…Use of the appropriate photocatalyst, ligand amount and solvents can match the reaction rate required by any simple catalytic cycle. …”
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“…Based on the change in the reaction rate of different formation reactions, OH* distributions can be divided into three regions: intense section near the nozzle, transition section in the middle of the flame, and secondary section downstream the flame, whereas CH* only exists in the first two regions. …”
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“…The values of the reaction rate constants were found to be 0.0480 h(−1) for ZnO, and 0.1072 h(−1) for ZnO:MoO(3), respectively.…”
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“…It was found that the overall reaction rate constants of •OH-initial reaction of SMX and TMP are 1.28 × 10(8) M(−1) s(−1) and 6.21 × 10(8) M(−1) s(−1) at 298 K, respectively. …”
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“…The highest carbon conversion reaction rate of 1.1 × 10(–4) mol/g could be obtained at the ratio of CaO to fuel carbon and the reaction temperature of 1.5 and 600 °C, respectively. …”
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“…Additionally, we study the hybridization kinetics of DNA duplex formation and the formation of hairpin stems, finding that the reaction rate k(on) is increased by the crowding effect, while k(off) is changed only moderately. …”
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“…More scaffold Au atoms are favored for the faster chirality transfer, and the Au‐assisted chirality transfer follows the first‐order kinetics with the reaction rate coefficient of ≈0.3 h(−1) at room temperature. …”
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“…As the acrylic acid content increases, the reaction rate increases, but the total monomers conversion and the solid content of the prepolymer decreases. …”
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“…For the particular system analyzed, the ratio of reaction rate and equilibrium constants of the enzyme–substrate complex are 0.3 and 0.9 pM(−1)h(−1) for β-glucuronidase in phosphate buffered saline and lysogeny broth, respectively. …”
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“…Therefore, both chemical reaction rate and mass transfer rate are enhanced to accelerate primary nucleation and inhibit uncontrolled particle growth, leading to the formation of monodisperse spherical AgNPs. …”
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“…These CNTs were tested in the hydrogenation of phenylacetylene by hydrogen in a batch reactor. The initial reaction rate observed on a CNT/TiO(2) structured catalyst was considerably higher than that on 1 wt% Pd/TiO(2) thin films.…”
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“…Moreover, MTG-catalyzed post-modification of a small fluorescent molecule bearing an amine group also showed pH dependency, where the enzymatic reaction rate was increased at higher pH, which may be because of the higher nucleophilicity of the amine group and the electrostatic interaction between MTG and the self-assembled Fmoc-L(n)QG. …”
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“…The variation regularities of the log reduction and reaction rate constant at various cavitation numbers were established. …”
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“…The distance between them was closer, the local concentration of H1 and H2 in intra-CHA was theoretically approximately 808-times higher than that in free-CHA, and the initial reaction rate was enhanced 15.6 fold. Due to the spatial confinement effect, the reaction kinetics for target-catalyzed signal generation were significantly improved. …”
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“…The generation of a ternary [Cu(II)–Aβ–catechol] species determines the efficiency of the oxidation, although the reaction rate is ruled by reoxidation of the Cu(I) complex. …”
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“…The results show that it is easier for the multijet scheme to form a full and stable vortex structure pair in the recirculation zone under lean conditions than the single-jet scheme, and it has a uniform reaction rate to form larger combustion zones, which makes it easier to achieve flame stabilization. …”
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