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1201por Owhondah, Raymond O., Walker, Mark, Ma, Lin, Nimmo, Bill, Ingham, Derek B., Poggio, Davide, Pourkashanian, Mohamed“…This work considers models which include between one and three biochemical reactions to investigate if the choice of the reaction rate equation, complexity of the model structure as well as the inclusion of inhibition plays a key role in the ability of the model to describe the methane production from the semi-continuous anaerobic digestion of green waste (GW) and food waste (FW). …”
Publicado 2016
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1202por Granata, Vincenza, Cascella, Marco, Fusco, Roberta, dell'Aprovitola, Nicoletta, Catalano, Orlando, Filice, Salvatore, Schiavone, Vincenzo, Izzo, Francesco, Cuomo, Arturo, Petrillo, Antonella“…Acute adverse reactions are generally rare with the overall adverse reaction rate of 0.3%. The most common adverse reactions were not severe, consisting in skin rash and hives.…”
Publicado 2016
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1203por Papaioannou, Evangelos I., Bachmann, Christoph, Neumeier, Jonas J., Frankel, Daniel, Over, Herbert, Janek, Juergen, Metcalfe, Ian S.“…When Pt is supported on yttria-stabilized zirconia, the reaction rate clearly depends upon the area-specific length of the three-phase boundary, l(tpb). …”
Publicado 2016
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1204por Wang, Zhen, Deng, Yuzhou, Shen, Genli, Akram, Sadia, Han, Ning, Chen, Yunfa, Wang, Qi“…The activity was enhanced further compared with that of the supporter alone (for the supporter, the reaction rate R (214 °C)=0.68×10(−4) mol g(cat) (−1) s(−1) and apparent activation energy E (a)=12.75 kJ mol(−1); for the supporting catalyst, R (214 °C)=1.46×10(−4) mol g(cat) (−1) s(−1), E (a)=10.91 kJ mol(−1)). …”
Publicado 2016
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1205“…Higher 4-nitrophenol reduction reaction rate constants were observed for smaller sizes. …”
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1206“…The damage repair mechanism is modeled by an expanded reaction-rate two-lesion kinetic model, which were calibrated through replicating a radiobiological experiment. …”
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1207por Bahamonde, Ana, Murphy, John J., Savarese, Marika, Brémond, Éric, Cavalli, Andrea, Melchiorre, Paolo“…This mechanistic framework is corroborated by the linear correlation between the reaction rate and the reduction potential of the carbazole unit tethered to the aminocatalyst. …”
Publicado 2017
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1208por Wang, Yuan, Arandiyan, Hamidreza, Tahini, Hassan A., Scott, Jason, Tan, Xin, Dai, Hongxing, Gale, Julian D., Rohl, Andrew L., Smith, Sean C., Amal, Rose“…The hexapod-shaped perovskite catalyst exhibits excellent low temperature methane oxidation activity (T(90%)=438 °C; reaction rate=4.84 × 10(−7) mol m(−2) s(−1)). First principle calculations suggest the fractures, which occur at weak joints within the 3DOM architecture, afford a large area of (001) surface that displays a reduced energy barrier for hydrogen abstraction, thereby facilitating methane oxidation.…”
Publicado 2017
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1209“…Temperature increase enhanced glucoamylase reaction rate more drastically than other enzyme treatments. …”
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1210“…These results are largely independent of the specific reaction-rate constant values, and depend on the topology of the architectures. …”
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1211“…We have systematically compared the laccase-like reactivity of manganese oxide nanomaterials of different crystallinity, including α-, β-, γ-, δ-, and ɛ-MnO(2), and Mn(3)O(4), with 2,2′-azinobis-(3-ethylbenzthiazoline-6-sulfonate) (ABTS) and 17β-estradiol (E2) as the probing substrates. The reaction rate behaviors were examined with regard to substrate oxidation and oxygen reduction to evaluate the laccase-like catalysis of the materials, among which γ-MnO(2) exhibits the best performance. …”
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1212por Damioli, Valentina, Salvadori, Alberto, Beretta, Gian Paolo, Ravelli, Cosetta, Mitola, Stefania“…Co-designing the in vitro experiments with the simulations allows identifying three phases of the receptor dynamics, which are controlled respectively by the high chemical reaction rate, by the mechanical deformation rate, and by the diffusion of free receptors on the membrane. …”
Publicado 2017
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1213“…The water:methanol ratio of the fused microdroplets was varied from 7:3 to 3:7 causing an increase in the reaction rate of chlorophyll a demetallation by 20%. …”
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1214“…Among the two, microwave assisted organic synthesis (MAOS) emerged as a better synthetic tool in terms of faster reaction rate and high yield. Various physicochemical and spectral studies were conducted to characterize the synthesized derivatives including- IR, Mass, (1)H-NMR, (13)C-NMR and elemental analysis. …”
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1215por Li, Zishun, Tang, Xuekun, Liu, Kun, Huang, Jing, Xu, Yueyang, Peng, Qian, Ao, Minlin“…Heterogeneous Fenton-like catalysts with the activation of peroxymonosulfate (PMS), which offer the advantages of fast reaction rate, wide functional pH range and cost efficiency, have attracted great interest in wastewater treatment. …”
Publicado 2018
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1216“…Through this decoupling fabrication strategy, our microfluidic concentrator chip can easily be integrated with a standard multiwell plate, the de facto laboratory standard platform for high-throughput assays, simply by reversible bonding on the bottom of each well. It increases the reaction rate of enzymatic assays by concentrating the enzyme and the reaction product inside each well simultaneously for rapid multiplexed detection.…”
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1217por Delgove, Marie AF, Elford, Matthew T, Bernaerts, Katrien V, De Wildeman, Stefaan MA“…RESULTS: Using reaction engineering, the reaction rate and product formation of the regio‐isomeric branched lactones were improved and the use of co‐solvents and the initial substrate load were investigated. …”
Publicado 2018
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1218“…We demonstrate that controlling for the ryanodine receptor’s maximal kinetic reaction rate may provide a biophysical way of managing aberrant Ca(2+) signals. …”
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1219por Ismail, Eman H., Saqer, Aliyah M. A., Assirey, Eman, Naqvi, Arshi, Okasha, Rawda M.“…Only one hour was required for the complete conversion to Au NPs, suggesting that the reaction rate was higher or comparable to those of nanoparticles synthesized by chemical methods. …”
Publicado 2018
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1220“…By numerically solving the Smoluchowski equation, we show that the presence of such an alternative binding site, even when it is distant from the catalytic center, always increases the reaction rate of a given substrate. However, this increase is only significant for enzyme-substrate reactions heavily influenced by diffusion. …”
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