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1521“…Here we show a unique solution to improve the oxygen evolution reaction rate by adjusting the electrolyte composition via the introduction of hexadecyltrimethylammonium hydroxide into an alkaline electrolyte. …”
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1522por Liao, Yangwei, Hu, Hao, Tang, Xiaofeng, Qin, Yang, Zhang, Wei, Dong, Kejun, Yan, Bei, Mu, Yaoqin, Li, Longjie, Ming, Zhihao, Xiao, Xianjin“…Herein, we developed a novel regulation tool named Cap which has two basic functions of subtle regulation of the reaction rate and erasability. Based on these functions, we further developed three advanced functions. …”
Publicado 2022
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1523por Van den Eynden, Dietger, Pokratath, Rohan, Mathew, Jikson Pulparayil, Goossens, Eline, De Buysser, Klaartje, De Roo, Jonathan“…The oxo clusters present a five times higher reaction rate, due to their higher surface area. Since the oxo clusters are the lower limit of downscaling oxide nanocrystals, we present them as appealing catalytic materials, and as atomically precise model systems. …”
Publicado 2022
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1524“…Molecular diffusion in liquids is a key process in numerous systems: it is often the reaction rate limiting factor in biological or chemical reaction. …”
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1525por Xu, Lingyuan, Abd El-Aty, A. M., Zhao, Jing, Lei, Xingmei, Zhang, Xiuyuan, Zhao, Yun, Cui, Xueyan, She, Yongxin, Jin, Fen, Wang, Jing, Jin, Maojun, Hammock, Bruce D.“…The cross-reaction rate with the other seven triazines was less than 1%. …”
Publicado 2022
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1526por Shi, Song, Yang, Piaoping, Dun, Chaochao, Zheng, Weiqing, Urban, Jeffrey J., Vlachos, Dionisios G.“…Here, we synthesize hyper-crosslinked porous polymer (HCPs) with solely -OH or -CH(3) groups on the polymer scaffold to tune the environment of active sites. Reaction rate measurements, spectroscopic techniques, along with DFT calculations show that HCP-OH catalysts enhance the hydrogenation rate of H-acceptor substrates containing carbonyl groups whereas hydrophobic HCP- CH(3) ones promote non-H bond substrate activation. …”
Publicado 2023
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1527“…On the other hand, the reduction of kinesin’s ATP hydrolysis reaction rate by a distal asparagine-to-serine mutation is also known to cause HSP disease. …”
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1528“…The equations of leaching process mechanism model are mainly composed of gold conservation, cyanide ion conservation, and kinetic reaction rate equations. The derivation of the theoretical model involves many unknown parameters and some ideal assumptions, which leads to difficulty and imprecision in establishing the accurate mechanism model of the leaching process. …”
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1529por Finkenzeller, Henning, Iyer, Siddharth, He, Xu-Cheng, Simon, Mario, Koenig, Theodore K, Lee, Christopher F, Valiev, Rashid, Hofbauer, Victoria, Amorim, Antonio, Baalbaki, Rima, Baccarini, Andrea, Beck, Lisa, Bell, David M, Caudillo, Lucía, Chen, Dexian, Chiu, Randall, Chu, Biwu, Dada, Lubna, Duplissy, Jonathan, Heinritzi, Martin, Kemppainen, Deniz, Kim, Changhyuk, Krechmer, Jordan, Kürten, Andreas, Kvashnin, Alexandr, Lamkaddam, Houssni, Lee, Chuan Ping, Lehtipalo, Katrianne, Li, Zijun, Makhmutov, Vladimir, Manninen, Hanna E, Marie, Guillaume, Marten, Ruby, Mauldin, Roy L, Mentler, Bernhard, Müller, Tatjana, Petäjä, Tuukka, Philippov, Maxim, Ranjithkumar, Ananth, Rörup, Birte, Shen, Jiali, Stolzenburg, Dominik, Tauber, Christian, Tham, Yee Jun, Tomé, António, Vazquez-Pufleau, Miguel, Wagner, Andrea C, Wang, Dongyu S, Wang, Mingyi, Wang, Yonghong, Weber, Stefan K, Nie, Wei, Wu, Yusheng, Xiao, Mao, Ye, Qing, Zauner-Wieczorek, Marcel, Hansel, Armin, Baltensperger, Urs, Brioude, Jérome, Curtius, Joachim, Donahue, Neil M, Haddad, Imad El, Flagan, Richard C, Kulmala, Markku, Kirkby, Jasper, Sipilä, Mikko, Worsnop, Douglas R, Kurten, Theo, Rissanen, Matti, Volkamer, Rainer“…The laboratory-derived reaction rate coefficients are corroborated by theory and shown to explain field observations of daytime HIO3 in the remote lower free troposphere. …”
Publicado 2022
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1530“…CONCLUSIONS: Low-temperature plasma radiofrequency ablation in the treatment of early glottis carcinoma is associated with less trauma, short operation time, less bleeding, short hospital stay and low postoperative stress reaction rate. Compared with partial laryngectomy, it has higher safety and better postoperative vocal cord function recovery.…”
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1531“…In experiments adding consistent concentrations of initial bacteria and lactate, it was shown that with the increase of GO additions (0.5–5.0 mg mL(−1)), the first-order reaction rate constants (k) of lactate metabolism and acetate production increased accordingly; in experiments adding consistent concentrations of initial bacteria and GO but different lactate levels (1 to 10 mM), the k values of lactate metabolism did not change significantly. …”
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1532“…Fluorescence sensors targeting boronic acids can achieve this because the amount and localization of (10)B in tumor tissues directly determine BNCT efficacy; however, current sensors are nonoptimal given their slow reaction rate and weak fluorescence (quantum yield < 0.1). …”
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1533por Campos, Felipe A., Bruno, Simone, Fu, Yi, Del Vecchio, Domitilla, Williams, Ruth J.“…A fundamental problem for these Stochastic Chemical Reaction Networks (SCRNs) is to understand the dependence of the stochastic behavior of these systems on the chemical reaction rate parameters. Towards solving this problem, in this paper we develop theoretical tools called comparison theorems that provide stochastic ordering results for SCRNs. …”
Publicado 2023
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1534por Wang, Xianhui, Pei, Chunlei, Zhao, Zhi-Jian, Chen, Sai, Li, Xinyu, Sun, Jiachen, Song, Hongbo, Sun, Guodong, Wang,, Wei, Chang, Xin, Zhang, Xianhua, Gong, Jinlong“…The enhanced surface acidity, coupled with proper lattice oxygen activity, leads to a higher surface reaction rate and moderate oxygen diffusion rate. Consequently, this coupling strategy achieves a robust performance with 49% of propane conversion and 90% of propylene selectivity for at least 300 redox cycles and ultimately demonstrates a potential design strategy for more advanced redox catalysts.…”
Publicado 2023
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1535por Aihara, Takeshi, Aoki, Wataru, Kiyohara, Shin, Kumagai, Yu, Kamata, Keigo, Hara, Michikazu“…In this case, the reaction rate was 8.4 mmol g(–1) min(–1), which is the highest rate among those reported for heterogeneous catalyst systems that do not involve a pretreatment. …”
Publicado 2023
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1536por Chen, Xiaowen, Qin, Xuetao, Jiao, Yueyue, Peng, Mi, Diao, Jiangyong, Ren, Pengju, Li, Chengyu, Xiao, Dequan, Wen, Xiaodong, Jiang, Zheng, Wang, Ning, Cai, Xiangbin, Liu, Hongyang, Ma, Ding“…Here, we report an atomically dispersed Ir catalyst as the bridge between homogeneous and heterogeneous catalysis, which displays an outstanding catalytic performance for n-butane dehydrogenation, with a remarkable n-butane reaction rate (8.8 mol·g(Ir)(−1)·h(−1)) and high butene selectivity (95.6%) at low temperature (450 °C). …”
Publicado 2023
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1537por Alamier, Waleed M., D Y Oteef, Mohammed, Bakry, Ayyob M., Hasan, Nazim, Ismail, Khatib Sayeed, Awad, Fathi S.“…The results followed a zero-order chemical kinetic (R(2) = 0.98) with reaction rate constant k as 0.059 mol L(–1) s(–1). Furthermore, the Ag-NPs were used as antibacterial and antifungal agents against 16 Gram-positive and Gram-negative bacteria as well as 1 fungus. …”
Publicado 2023
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1538por Liu, Zhihe, Tan, Hua, Li, Bo, Hu, Zehua, Jiang, De-en, Yao, Qiaofeng, Wang, Lei, Xie, Jianping“…Herein, we employ atomically precise Au(25) nanoclusters with different ligands (i.e., para-mercaptobenzoic acid, 6-mercaptohexanoic acid, and homocysteine) as paradigm electrocatalysts to demonstrate oxygen evolution reaction rate-determining step switching through ligand engineering. …”
Publicado 2023
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1539“…Postauricular pain disappeared earlier in the experimental group (3.66 ± 1.67 days) than in the control group (6.31 ± 2.34); the difference was statistically significant (P ≤ 0.001). The adverse reaction rate was lower in the experimental group (15.00%) than in the control group (21.66%). …”
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1540“…Preoperative antibiotics did not demonstrate benefit in terms of reduction of minor infections, but they did yield a 6.9% adverse reaction rate, including one case of Clostridium difficile infection warranting hospitalization. …”
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