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1541“…The stronger scale solubilization ability and lower acid-rock reaction rate enable microemulsion acid to form a thin and straight main wormhole, thus enhancing the acidizing and plugging removal effect. …”
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1542“…The use of the Van’t hoff rule with [Formula: see text] for accelerated lifetime tests would lead to an estimation of longer lifetimes than realistic. A reaction rate constant around 1.47 appears more appropriate. …”
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1543“…Fourier transform infrared (FTIR) spectroscopy and nuclear magnetic resonance (NMR) analyses were performed to characterize the effect of Co incorporation on the glass structure, and the results showed that the substitution promoted the transformation of [BO(3)] into [BO(4)] units, which endow the glass with higher chemical durability and lower reaction rate with the simulated body fluid (SBF), thereby achieving sustained and controlled Co(2+) ion release. …”
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1544por Qin, Chenxi, Ma, Yanfei, Zhang, Zhizhi, Du, Yingjie, Duan, Sidi, Ma, Shuanhong, Pei, Xiaowei, Yu, Bo, Cai, Meirong, He, Ximin, Zhou, Feng“…Intriguingly, SLU-adhesive/photothermal nanoparticles (carbon nanotubes) hybrid materials can significantly reduce the time required for complete curing from 24 h to 40 min using near-infrared laser radiation due to unique thermal-response of the chemical reaction rate. The excellent adhesion property and self-adaptive adhesion procedure allow SLU-adhesive materials to demonstrate great potential for broad applications in underwater sand stabilization, underwater repair, and even adhesion failure detection as a self-reporting adhesive. …”
Publicado 2023
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1545por Sewnet, Agidew, Alemayehu, Esayas, Abebe, Mulualem, Mani, Dhakshnamoorthy, Thomas, Sabu, Lennartz, Bernd“…The g-C(3)N(4)/Ag–TiO(2) nanocomposite exhibited an apparent reaction rate constant 13.16, 4.7, and 1.33 times higher than that of TiO(2), Ag–TiO(2), and g-C(3)N(4), respectively. …”
Publicado 2023
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1546por Zhang, Lin, Peng, Li, Lu, Yuanchao, Ming, Xin, Sun, Yuxin, Xu, Xiaoyi, Xia, Yuxing, Pang, Kai, Fang, Wenzhang, Huang, Ning, Xu, Zhen, Ying, Yibin, Liu, Yingjun, Fu, Yingchun, Gao, Chao“…However, it still suffers from limited reaction rate, controllability, and massive consumption of energy/reactants, particularly for the synthesis on specific substrates. …”
Publicado 2023
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1547“…The total adverse reaction rate was significantly lower in the experimental group as compared with the reference group(P<0.05). …”
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1548por Anthuparambil, Nimmi Das, Girelli, Anita, Timmermann, Sonja, Kowalski, Marvin, Akhundzadeh, Mohammad Sayed, Retzbach, Sebastian, Senft, Maximilian D., Dargasz, Michelle, Gutmüller, Dennis, Hiremath, Anusha, Moron, Marc, Öztürk, Özgül, Poggemann, Hanna-Friederike, Ragulskaya, Anastasia, Begam, Nafisa, Tosson, Amir, Paulus, Michael, Westermeier, Fabian, Zhang, Fajun, Sprung, Michael, Schreiber, Frank, Gutt, Christian“…Overall, protein denaturation-aggregation-gelation and LDL-aggregation follows Arrhenius-type time-temperature superposition (TTS), indicating an identical mechanism with a temperature-dependent reaction rate. However, above 75 °C TTS breaks down and temperature-independent gelation dynamics is observed, demonstrating that the temperature can no longer accelerate certain non-equilibrium processes above a threshold value.…”
Publicado 2023
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1549por Rahman, Mariam Abdul, Mubarak, Nabisab Mujawar, Azmi, Intan Suhada, Jalil, Mohd Jumain“…By employing these optimal conditions, the maximum relative conversion of palm oleic acid to oxirane was achieved at 85%. The reaction rate constants (k) based on the optimized epoxidized oleic acid are determined as follows: k(11) = 20 mol L(−1) min(−1), k(12) = 2 mol L(−1) min(−1), and k(2) = 20 mol L(−1) min(−1). …”
Publicado 2023
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1550por González-Jiménez, Mario, García-Santos, M. Pilar, Bermejo Tesón, Blanca, Fuentes de Arriba, Ángel L., Arenas Valgañón, Jorge, Calle, Emilio, Casado, Julio“…We determined the kinetic parameters and reaction mechanisms for the reactions, studying the influence of the reactants concentration, pH, temperature, and ionic strength on the reaction rate. In all cases, the favoured reaction product was a stable nitroso-compound. …”
Publicado 2023
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1551por Li, Zichuang, Lu, Yangfan, Li, Jiang, Xu, Miao, Qi, Yanpeng, Park, Sang-Won, Kitano, Masaaki, Hosono, Hideo, Chen, Jie-Sheng, Ye, Tian-Nan“…These catalysts enable ammonia production through multiple reaction pathways. The reaction rate of Co/SrNH is as high as 1686.7 mmol·g(Co)(−1)·h(−1) and the TOFs reaches above 500 h(−1) at 400 °C and 0.9 MPa, outperforming other reported Co-based catalysts as well as the benchmark Cs-Ru/MgO catalyst and industrial wüstite-based Fe catalyst under the same reaction conditions. …”
Publicado 2023
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1552“…AgNPs synthesis process by investigating the influence of reaction parameters such as concentration of tea leaf extract (1 ppm–50 ppm), reaction temperature (30 °C-60 °C), reaction time (5 min–100 min), and reaction rate (400 rpm–800 rpm) through absorption UV–Vis spectroscopy, TEM transmission electron microscopy, and spectroscopy X-ray. …”
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1553“…[Image: see text] In the process of matrix acidizing, reducing the reaction rate between hydrochloric acid and carbonate rock to increase oil and gas production has become one of the biggest challenges in reservoir stimulation. …”
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1554por Mohammed, Widad, Matalkeh, Maha, Al Soubaihi, Rola Mohammad, Elzatahry, Ahmed, Saoud, Khaled M.“…The results indicate that NiO/Ag/TiO(2) has superior MB photodegradation efficiency with a high reaction rate constant and low degradation time (93.15% within 60 min) compared to Ag/TiO(2), NiO/TiO(2), and bare TiO(2). …”
Publicado 2023
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1555por Meng, Hao, Yang, Yusen, Shen, Tianyao, Yin, Zhiming, Wang, Lei, Liu, Wei, Yin, Pan, Ren, Zhen, Zheng, Lirong, Zhang, Jian, Xiao, Feng-Shou, Wei, Min“…A binary function correlation between the CH(3)OH reaction rate and surface concentrations of Cu(0) and Cu(+) is established based on kinetic studies. …”
Publicado 2023
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1556por Yuan, Wei, Chen, Letian, Yuan, Chuting, Zhang, Zidan, Chen, Xiaokai, Zhang, Xiaodong, Guo, Jingjing, Qian, Cheng, Zhao, Zujin, Zhao, Yanli“…Thanks to the supramolecular confine effect, the [2 + 2] cycloaddition reaction rate of the supramolecular solution is 10.5 times higher than that of the monomeric solution. …”
Publicado 2023
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1557“…RESULTS: We present four (one for each NDP) rational polynomial models of RNR activity as a function of substrate and reaction rate modifier concentrations. The new models avoid the complications of the earlier model without compromising curve fits to recent data. …”
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1558por Lindskog, Maria, Kim, MyungSook, Wikström, Martin A, Blackwell, Kim T, Kotaleski, Jeanette Hellgren“…Ordinary differential equations describing the biochemical reactions were implemented in a single compartment model using the software XPPAUT. Reaction rate constants were obtained from the biochemical literature. …”
Publicado 2006
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1559“…The simulator was coupled, in the framework of an inverse modeling strategy, with an optimization algorithm and an experimental time series, obtained by the Fluorescence Recovery after Photobleaching (FRAP) technique, to estimate biomolecule mass transport and reaction rate parameters. In the inverse algorithm, an adaptive method was implemented to calculate sensitivity matrix. …”
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1560Publicado 1992“…Saturation curves for Itail were predicted on the assumption of reversible veratridine binding to open Na channels during the pulse with reaction rate constants determined previously in the same type of cell at single Na channels comodified with BDF 9145. …”
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