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1641“…These five regimes exhibit different rate equations for methane combustion due to the reaction rate constants and diverse dominant adsorbed species for these different kinetically relevant steps. …”
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1642“…In the molecular machine F1-ATPase, the stepping rotation is described for individual steps by forward and back reaction rate constants, some of which depend strongly on the rotation angle. …”
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1643por Shao, Ying-Ying, Ye, Wei-Dong, Sun, Chun-Yan, Liu, Chun-Lin, Wang, Qi, Chen, Chun-cheng, Gu, Jia-Yun, Chen, Xiao-Qing“…Among all the hybrids, FeOCN-4 with a 4 wt% Fe(3)O(4) content gives the highest reaction rate, which is 6.7 times as high as that in pure g-C(3)N(4.) …”
Publicado 2018
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1644por Gerke, Christoph, Zabala Gutierrez, Irene, Méndez-González, Diego, Cruz, M. Carmen Iglesias-de la, Mulero, Francisca, Jaque, Daniel, Rubio-Retama, Jorge“…Those reactive groups are able to specifically react with dibenzocyclooctyne (DBCO) groups in a click-type fashion, reaching second-order reaction rate constants as high as 1.9 M(–1)·s(–1), which makes this reaction highly suitable for in vivo applications. …”
Publicado 2022
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1645“…The effects of sulfur content on TCE dechlorination by S-nZVI were thoroughly investigated in terms of TCE-removal efficiency, H(2) evolution, and reaction rate. X-ray diffraction (XRD) and X-ray Photoelectron Spectroscopy (XPS) characterizations confirmed Fe(0) levels in S-nZVI were larger than for zero-valent iron (nZVI). …”
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1646por Pierzchała, Karolina, Pięta, Marlena, Rola, Monika, Świerczyńska, Małgorzata, Artelska, Angelika, Dębowska, Karolina, Podsiadły, Radosław, Pięta, Jakub, Zielonka, Jacek, Sikora, Adam, Marcinek, Andrzej, Michalski, Radosław“…We have also determined the rate constants of the reaction between HOCl and the probes and they are equal to 1.8 × 10(4) M(−1)s(−1) for coumarin boronic acid (CBA), 1.1 × 10(4) M(−1)s(−1) for fluorescein based boronic acid (FLBA), 3.1 × 10(4) M(−1)s(−1) for 7-(p-aminophenyl)-coumarin (APC), 1.6 × 10(4) M(−1)s(−1) for 3’-(p-aminophenyl)-fluorescein (APF), and 1 × 10(7) M(−1)s(−1) for 4-thiomorpholino-7-nitrobenz-2-oxa-1,3-diazole (NBD-TM). The high reaction rate constant of NBD-TM with HOCl makes this probe the most reliable tool to monitor HOCl formation in the presence of compounds showing HOCl-scavenging activity.…”
Publicado 2022
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1647por Murtaza, Mian Anjum, Irfan, Shafeeqa, Hafiz, Iram, Ranjha, Muhammad Modassar A. N., Rahaman, Abdul, Murtaza, Mian Shamas, Ibrahim, Salam A., Siddiqui, Shahida Anusha“…UAP is an innovative and most efficient technology as its mechanical effects and cavitation change the protein conformation, increase the biological activities of enzymes, and enhance enzymatic hydrolysis reaction rate.…”
Publicado 2022
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1648“…Ultrasound increased the reaction rate by facilitating carbocation formation of glyceridic carbons. …”
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1649“…The measured relative reaction rate coefficient for the He(+) + CH(4) reaction is approximately twice higher than the one for the He(+) + CD(4) reaction. …”
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1650por Rodriguez, Alyssa A., Rafla, Michael A., Welsh, Hannah G., Pennington, Elyse A., Casar, Jason R., Hawkins, Lelia N., Jimenez, Natalie G., de Loera, Alexia, Stewart, Devoun R., Rojas, Antonio, Tran, Matthew-Khoa, Lin, Peng, Laskin, Alexander, Formenti, Paola, Cazaunau, Mathieu, Pangui, Edouard, Doussin, Jean-François, De Haan, David O.“…Here, we report NMR measurements of glycolaldehyde’s aqueous-phase reactions with AS, methylamine, and glycine. Reaction rate constants are smaller than those of respective glyoxal and methylglyoxal reactions in the pH range of 3–6. …”
Publicado 2022
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1651“…RESULTS: The NRS scores at 12 h, 24 h, 48 h, and 72 h post-op in the combined group and FTS group were lower than those in the regular group, and the NRS scores at 12 h and 24 h post-op in the combined group were lower than those in the FTS group (all P < 0.05); the post-op bed activity time, post-op hospitalization time, post-op adverse reaction rate, and post-op complication rate in the combined group and FTS group were shorter or lower than those of the regular group. …”
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1652“…However, the limitations of endogenous H(2)O(2) and intracellular low Fenton-like reaction rate lead to single unsatisfied chemodynamic therapy (CDT) efficacy. …”
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1653“…Furthermore, no significant difference in the adverse reaction rate was observed. CONCLUSION: Acupuncture is safe and effective in treating neurodermatitis. …”
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1654por Kolli, Chandra Sekhar Reddy, Bogireddy, Naveen Kumar Reddy, Martínez-Landeros, Víctor Hugo, Ramírez-Bon, Rafael“…The stability and reusability of the NiO NWs were tested successfully in several reusable cycles, with only a 2% degradation difference. The reaction rate was found to be 0.054 min(−1) for MB (5 μM) and 0.033 min(−1) for MB (10 μM) at pH 11 for 60 min, and the higher activity parameter was calculated to be 3.3 × 10(−3) min(−1) mg(−1) L(−1) due to their hollow structure and effective area of the NiO NWs. …”
Publicado 2022
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1655“…The reaction of C(2)H(2) H-abstraction by O(2) dictates the C(2)H(2) overall reaction rate on the perfect Cu(2)O (111) surface model and the chemisorption of C(2)H(2) is the rate-determining step on the defective Cu(2)O (111) surface model. …”
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1656por Deepthi, V. V. L., Lashin, Maha M. A., Ravi Kumar, N., Raghunath, Kodi, Ali, Farhan, Oreijah, Mowffaq, Guedri, Kamel, Tag-ElDin, El Sayed Mohamed, Khan, M. Ijaz, Galal, Ahmed M.“…These profiles are shown as graphs for various fluid and geometric parameters such as Hall and ion slip parameters, radiation absorption, diffusion thermo, Prandtl number, Schmidt number, and chemical reaction rate. On the other hand, the skin friction coefficient and the Nusselt number are determined by numerical evaluation and provided in tables. …”
Publicado 2022
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1657“…Moreover, the photogenerated electrons in the conduction band of ART transferred to the valence band of CN and combined with the holes in the valence band of CN, forming Z-type heterostructures that significantly improved the efficiency of the photogenerated electron-hole migration and separation, thus increasing the reaction rate. Gaseous and liquid ammonia were used as the target pollutants to investigate the activity of the prepared catalysts, and the results showed that the air wetness and initial concentration of ammonia had a great influence on the degradation of gaseous ammonia. …”
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1658por Öztürk, Betül Özdel, Akdemir, İrem, Azap, Alpay, Çelik, Gülfem, Bavbek, Sevim, Mungan, Dilşad“…Twenty-one HCWs (female: male, 17:4) with a mean age of 40.95 ± 10.09 stated that they had an allergic reaction after a total of 23 vaccine injections. Accordingly, the reaction rate was 0.56% among all vaccine doses. The most common reactions were systemic skin reactions (2.7%) consisting of generalized pruritus, diffuse pruritic erythema, urticaria, and maculopapular rash. …”
Publicado 2022
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1659“…We found cumulative caspase-9 activity rather than reaction rate inversely regulated caspase-3 execution times for apoptotic cell death. …”
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1660“…Interestingly, the HP-CuO catalyst expressed workable CO conversion kinetics with a reaction rate of c.a.35 μmol s(–1) g(–1) at 150 °C and apparent activation energy (E(a)) of 82 kJ mol(–1). …”
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