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  1. 1901
    “…Both direct electron transfer from the metal to the enzyme as well as mediated electron transfer is feasible, although the latter excels by higher reaction rates. The general applicability of this new chemoenzymatic reduction method is demonstrated, and current limitations are outlined.…”
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    Metals in Biotechnology: Cr‐Driven Stereoselective Reduction of Conjugated C=C Double Bonds
  2. 1902
    “…Here we demonstrate a catalytic hydrogenation of alkenes that affords the thermodynamic alkane products with remarkably broad functional group compatibility and rapid reaction rates at standard temperature and pressure.…”
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    Simple, Chemoselective Hydrogenation with Thermodynamic Stereocontrol
  3. 1903
    “…High‐level DFT calculations provided mechanistic insights and enabled rational catalyst improvements, leading to interlocked catalysts that surpass their non‐interlocked counterparts in terms of reaction rates and stereoselectivities.…”
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    Heterobifunctional Rotaxanes for Asymmetric Catalysis
  4. 1904
    “…This method provides the combined advantages of versatile surface adsorption with density control using polyelectrolytes and of the covalent and orthogonal immobilization of biomolecules with higher reaction rates and improved yields of click chemistry. …”
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    Clickable poly-l-lysine for the formation of biorecognition surfaces
  5. 1905
    por Sohail, Muhammad, Tanaka, Fujie
    Publicado 2023
    “…[Image: see text] We demonstrated that the loading amounts and concentrations of reactant 1,3-cyclohexanedione affect reaction rates and outcomes. In certain cases, reactions with higher concentrations of 1,3-cyclohexanedione were slower than those with lower concentrations. …”
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    Limiting the Loading of Reactant 1,3-Cyclohexanedione Enables the Use of Less Catalyst
  6. 1906
    “…Periorbital ACD allergen groups eliciting the highest positive reaction rates were, in descending order: metals, shellac, preservatives, topical antibiotics, fragrances, acrylates, and surfactants. …”
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    Seven Common Allergen Groups Causing Eyelid Dermatitis: Education and Avoidance Strategies
  7. 1907
    “…METHODS: We used a preintervention-postintervention quality improvement design to compare the completion rates, reaction rates, and estimated costs of a 2-day versus 1-day aspirin desensitization. …”
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    One- versus 2-day aspirin desensitization in aspirin exacerbated respiratory disease: A quality improvement project
  8. 1908
    “…As a first step, we investigate reaction rates and mechanistic pathways for cement mineral growth in the absence of CO(2 )by coupling water chemistry with XRD and NMR spectroscopic data. …”
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    Transformation of meta-stable calcium silicate hydrates to tobermorite: reaction kinetics and molecular structure from XRD and NMR spectroscopy
  9. 1909
    “…BACKGROUND: Most modelling efforts of transcriptional networks involve estimations of in vivo concentrations of components, binding affinities and reaction rates, derived from in vitro biochemical assays. …”
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    Integration of transcriptional inputs at promoters of the arabinose catabolic pathway
  10. 1910
    “…Consequently, previous research has focused on finding optimal network structures and reaction rates that respond to pulses or produce stable oscillations. …”
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    Designing synthetic networks in silico: a generalised evolutionary algorithm approach
  11. 1911
    “…The highest degree of TCO loading resulted in significantly increased reaction rates (77-fold enhancement) compared to those with small molecule TCO moieties when using lipophilic tetrazines. …”
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    Trans-Cyclooctene-Functionalized PeptoBrushes with Improved Reaction Kinetics of the Tetrazine Ligation for Pretargeted Nuclear Imaging
  12. 1912
    “…Lastly, we reflect upon the use and limits of reaction rates as a baseline metric by comparing catalytic selectivity at 10 versus 200 mA cm(–2). …”
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    Characterizing CO(2) Reduction Catalysts on Gas Diffusion Electrodes: Comparing Activity, Selectivity, and Stability of Transition Metal Catalysts
  13. 1913
    “…The latter complex, in combination with B(C(6)F(5))(3), reacts with ArO–H substrates via formal hydrogen-atom transfer and exhibits dramatically increased reaction rates over the Mn(V)(O) starting material.…”
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    Activation of a High-Valent Manganese–Oxo Complex by a Nonmetallic Lewis Acid
  14. 1914
    por Rejwan, Idan
    Publicado 2018
    “…In order to prepare and analyze such high accuracy measurements, several calculations have to be performed, such as reaction rates or the alignment between neutron beam and sample. …”
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    Graphical User Interface for the nTOF Transport Code
  15. 1915
    por Senum, Phillip, Riedel, Marc
    Publicado 2011
    “…Given such categories, the computation is exact and independent of the specific reaction rates. The designs are validated through stochastic simulations of the chemical kinetics.…”
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    Rate-Independent Constructs for Chemical Computation
  16. 1916
    “…The benefits of a scalable continuous process in combination with on-demand electrolytic D(2) gas generation were exploited to suppress undesired over-reactions and to maximize reaction rates simultaneously. The novel deuterium-containing chalcone derivatives may have interesting biological effects and improved metabolic properties as compared with the parent compounds.…”
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    Continuous-Flow Synthesis of Deuterium-Labeled Antidiabetic Chalcones: Studies towards the Selective Deuteration of the Alkynone Core
  17. 1917
    “…The highly active exposed crystal facets enable increased mass activity of active sites, lower reaction energy barriers, and enhanced catalytic reaction rates for HER and OER. The formation mechanism and control strategy of the crystal facet, significant contributions as well as challenges and perspectives of facet-engineered catalysts for HER and OER are provided.…”
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    Facet Engineering of Advanced Electrocatalysts Toward Hydrogen/Oxygen Evolution Reactions
  18. 1918
    “…Using numerical simulation of the biosensor action, the influence of the geometry of the outer membrane on the biosensor response was investigated at wide range of analyte concentrations as well as of the reaction rates. The numerical simulation was carried out using finite–difference technique. …”
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    Mathematical Modeling of Plate–gap Biosensors with an Outer Porous Membrane
  19. 1919
    “…The feasibility of carrying out the one-pot synthesis under ultrasonic irradiation with a heterogeneous nanocatalyst could improve the reaction rates and shorten the reaction times.…”
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    A ZnS@N-GQD nanocomposite as a highly effective and easily retrievable catalyst for the sonosynthesis of β-amino carbonyls
  20. 1920
    “…We consider the effects of metastable charged sparticles on Big-Bang Nucleosynthesis (BBN), including bound-state reaction rates and chemical effects. We make a new analysis of the bound states of negatively-charged massive particles with the light nuclei most prominent in BBN, and present a new code to track their abundances, paying particular attention to that of Li7. …”
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    Metastable Charged Sparticles and the Cosmological Li7 Problem
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