“…Four selenoarsenates with different transition-metal complexes [Co(tren)(2)H]AsSe(4) [tren = tris(2-aminoethyl)amine] (1); [Ni(2)(dien)(4)](As(2)Se(5)) (dien = diethylenetriamine) (2); [Zn(tren)](2)(As(2)Se(5)) (3) and [Mn(tren)](2)(As(2)Se(5)) (4) were solvothermally synthesized in a mixed solvent of organic amine and alcohol solution. …”
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“…One-pot reaction of tris(2-aminoethyl)amine (TREN), [Cu(I)(MeCN)(4)]PF(6), and paraformaldehyde affords a mixed-valent [TREN(4)Cu(II)Cu(I)Cu(I)(μ(3)-OH)](PF(6))(3) complex. …”
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“…Two-electron reductive carbonylation of the uranium(VI) nitride [U(Tren(TIPS))(N)] (2, Tren(TIPS)=N(CH(2)CH(2)NSiiPr(3))(3)) with CO gave the uranium(IV) cyanate [U(Tren(TIPS))(NCO)] (3). …”
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“…Catalytic reduction of N(2) to NH(3) by a Ti complex has been achieved, thus now adding an early d‐block metal to the small group of mid‐ and late‐d‐block metals (Mo, Fe, Ru, Os, Co) that catalytically produce NH(3) by N(2) reduction and protonolysis under homogeneous, abiological conditions. Reduction of [Ti(IV)(Tren(TMS))X] (X=Cl, 1A; I, 1B; Tren(TMS)=N(CH(2)CH(2)NSiMe(3))(3)) with KC(8) affords [Ti(III)(Tren(TMS))] (2). …”
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“…We report that reduction of [Th(Tren(TIPS))(OCP)] (2, Tren(TIPS)=[N(CH(2)CH(2)NSiPr(i) (3))](3−)), with RbC(8) via [2+2+1] cycloaddition, produces an unprecedented hexathorium complex [{Th(Tren(TIPS))}(6)(μ‐OC(2)P(3))(2)(μ‐OC(2)P(3)H)(2)Rb(4)] (5) featuring four five‐membered [C(2)P(3)] phosphorus heterocycles, which can be converted to a rare oxo complex [{Th(Tren(TIPS))(μ‐ORb)}(2)] (6) and the known cyclometallated complex [Th{N(CH(2)CH(2)NSiPr(i) (3))(2)(CH(2)CH(2)SiPr(i) (2)CHMeCH(2))}] (4) by thermolysis; thereby, providing an unprecedented example of reductive cycloaddition reactivity in the chemistry of 2‐phosphaethynolate. …”
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“…We report the direct synthesis of the terminal pnictidenes [An(Tren(TCHS))(PnH)][M(2,2,2‐cryptand)] (Tren(TCHS)={N(CH(2)CH(2)NSiCy(3))(3)}(3−); An/Pn/M=Th/P/Na 5, Th/As/K 6, U/P/Na 7, U/As/K 8) and their conversion to the pnictides [An(Tren(TCHS))(PnH(2))] (An/Pn=Th/P 9, Th/As 10, U/P 11, U/As 12). …”
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“…[Image: see text] Deprotonation of [U(Tren(TIPS))(NH(2))] (1) [Tren(TIPS) = N(CH(2)CH(2)NSiPr(i)(3))(3)] with organoalkali metal reagents MR (M = Li, R = Bu(t); M = Na–Cs, R = CH(2)C(6)H(5)) afforded the imido-bridged dimers [{U(Tren(TIPS))(μ-N[H]M)}(2)] [M = Li–Cs (2a–e)]. …”
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“…We report that treatment of [M(Tren(DMBS))(I)] (M = U, 1; Th, 2; Tren(DMBS) = {N(CH(2)CH(2)NSiMe(2)Bu(t))(3)}(3–)) with NaN(3) or KN(3), respectively, affords very rare examples of actinide molecular square and triangle complexes [{M(Tren(DMBS))(μ-N(3))}(n)] (M = U, n = 4, 3; Th, n = 3, 4). …”
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“…Treatment of [U(IV)(N(3))(Tren(TIPS))] (1, Tren(TIPS) = {N(CH(2)CH(2)NSiPr(i)(3))(3)}(3−)) with excess Li resulted in the isolation of [{U(IV)(μ-NLi(2))(Tren(TIPS))}(2)] (2), which exhibits a diuranium(iv) ‘diamond-core’ dinitride motif. …”
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“…The title compound, {(C(6)H(21)N(4))[V(3)O(9)]·H(2)O}(n), crystallizes as a salt with [trenH(3)](3+) cations [tren is tris­(2-amino­eth­yl)amine], and one-dimensional anionic {[V(V)O(3)](−)}(n) (metavanadate) chains along the c-axis direction. …”
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“…Functionalized Tris[2-(dimethylamino) ethyl] amine (Me(6)TREN) ligands tethered-Fe(3)O(4)@Me(6)TREN nanoparticles (NPs) with a size of 150 nm were prepared to achieve classified and easy recovery of heavy metal ions in wastewater. …”
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“…Herein, we report a rare organosodium monomeric complex, namely, [Na(CH(2)SiMe(3))(Me(6)Tren)] (1-Na) (Me(6)Tren: tris[2-(dimethylamino)ethyl]amine) stabilized by a tetra-dentate neutral amine ligand Me(6)Tren. …”
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“…Here, a host molecule composed of a TREN ligand and cyclotriveratrylene moiety was investigated. …”
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“…In separate experiments, trenbolone-enanthate (TREN) prevented the GX-induced increase in serum adiponectin (p≤0.001) in young animals, with Low-dose TREN restoring adiponectin to the level of SHAMs and higher doses of TREN reducing adiponectin to below SHAM concentrations (p≤0.001). …”
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“…In this paper, in an attempt to immobilize the homogeneous [Ni(Me(6)Tren)X]X (X = I, Br, Cl)-type catalyst with porous organic polymer (POP), the heterogeneous catalyst PBTP-Me(6)Tren(Ni) (POP-Ni) was designed and constructed by quaternization of the porous bromomethyl benzene polymer (PBTP) with tri[2-(dimethylamino)ethyl]amine (Me(6)Tren) followed by coordination of the Ni(II) Lewis acidic center. …”
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“…We report the synthesis and characterisation of a family of diuranium(iv)-μ-chalcogenide complexes including a detailed examination of their electronic structures and magnetic behaviours. Treatment of [U(Tren(TIPS))] [1, Tren(TIPS) = N(CH(2)CH(2)NSiPr(i) (3))(3)] with Ph(3)PS, selenium or tellurium affords the diuranium(iv)-sulfide, selenide, and telluride complexes [{U(Tren(TIPS))}(2)(μ-E)] (E = S, 2; Se, 5; Te, 6). …”
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“…Reaction of K(8){Ta(6)O(19)}·16H(2)O with [Ni(tren)(H(2)O)Cl]Cl·H(2)O in different solvents led to the formation of single crystals of the title compound, [Ni(4)Ta(6)O(19)(C(6)H(18)N(4))(4)]·19H(2)O or {[Ni(2)(κ(4)-tren)(μ-κ(3)-tren)](2)Ta(6)O(19)}·19H(2)O (tren is N,N-bis­(2-amino­eth­yl)-1,2-ethanediamine, C(6)H(18)N(4)). …”
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“…The reaction of [Zr(Tren(DMBS))(Cl)] [Zr1; Tren(DMBS)=N(CH(2)CH(2)NSiMe(2)Bu(t))(3)] with NaPH(2) gave the terminal parent phosphanide complex [Zr(Tren(DMBS))(PH(2))] [Zr2; Zr−P=2.690(2) Å]. …”
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“…The synthesis and characterisation is presented of the compounds [An(Tren(DMBS)){Pn(SiMe(3))(2)}] and [An(Tren(TIPS)){Pn(SiMe(3))(2)}] [Tren(DMBS)=N(CH(2)CH(2)NSiMe(2)Bu(t))(3), An=U, Pn=P, As, Sb, Bi; An=Th, Pn=P, As; Tren(TIPS)=N(CH(2)CH(2)NSiPr(i) (3))(3), An=U, Pn=P, As, Sb; An=Th, Pn=P, As, Sb]. …”
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“…The (31)P NMR data for [Th(PH(2))(Tren(TIPS))] (1, Tren(TIPS) = {N(CH(2)CH(2)NSiPr(i)(3))(3)}(3–)), [Th(PH)(Tren(TIPS))][Na(12C4)(2)] (2, 12C4 = 12-crown-4 ether), [{Th(Tren(TIPS))}(2)(μ-PH)] (3), and [{Th(Tren(TIPS))}(2)(μ-P)][Na(12C4)(2)] (4) demonstrate a chemical shift anisotropy (CSA) ordering of (μ-P)(3–) > (=PH)(2–) > (μ-PH)(2–) > (−PH(2))(1–) and for 4 the largest CSA for any bridging phosphido unit. …”
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