“…Herein, acrylated β-cyclodextrin with bile acid is self-assembled into a polymerizable pseudorotaxane via precise host-guest recognition, which is photopolymerized with acrylamide to obtain conductive polymerizable rotaxane hydrogels (PR-Gel). The topological networks of PR-Gel enable all desirable properties in this system due to the large conformational freedom of the mobile junctions, including the excellent stretchability along with superior fatigue resistance. …”
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“…A [2]rotaxane built around a multi‐responsive bis‐acridinium macrocycle has been synthesized. …”
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“…Light-responsive rotaxane-based solid-state materials are ideal scaffolds in order to develop smart materials due to the properties provided by the mechanical bond, such as control over the dynamics of the components upon application of external stimuli. …”
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“…Here we report the synthesis and structural characterization of four [7]rotaxanes formed by coordinating hybrid inorganic–organic [2]rotaxanes to a central {Ni(12)} core. …”
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“…Subsequent stoppering of the interpenetrated assembly allows for the preparation of a lanthanide-functionalized [2]rotaxane in high yield. Following removal of the nitrite anion template, the europium [2]rotaxane host is demonstrated to recognize and sense fluoride selectively.…”
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“…We report the preparation of [2]rotaxanes containing an electrochemically and optically active osmium(II) bipyridyl macrocyclic component mechanically bonded with cationic pyridinium axles. …”
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“…A rotaxane-based Au catalyst was developed and the effect of the mechanical bond on its behavior was studied. …”
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“…[Image: see text] While the current supramolecular syntheses of [2]rotaxanes are generally efficient, the final product always retains the functional groups required for non-covalent preorganization. …”
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“…[Image: see text] The trisradical recognition motif between a 4,4′-bipyridinium radical cation and a cyclo-bis-4,4′-bipyridinium diradical dication has been employed previously in rotaxanes to control their nanomechanical and electronic properties. …”
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“…When excited in the porphyrin band at 402 nm, the RTP emission lifetimes changed obviously. This is the first rotaxane-type molecular shuttle whose shuttling has been encoded by RTP signals.…”
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“…BACKGROUND: Credelio(TM) (lotilaner) is an oral ectoparasiticide from the isoxazoline class developed for the treatment of flea and tick infestations in cats. …”
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“…Starting from a switchable organometallic [2]rotaxane precursor, the employment of a controllable divergent approach allowed for the successful synthesis of a family of rotaxane-branched dendrimers up to the third generation with 21 switchable rotaxane moieties located on each branch. …”
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“…Objectives: To obtain a cross-cultural translation of the GFQ into Spanish and Catalan and to assess the structural properties of the translated versions. …”
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“…Here, a new means to control tacticity by exploiting rotaxane conformational dynamism is described. Dynamic achiral [2]rotaxanes can show high isoselectivity (P(i)=0.8, 298 K) without requiring any chiral additives and enchain by a chain end control mechanism. …”
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“…The three polyurethanes contain rotaxane-based supramolecular mechanoluminophores based on π-extended pyrene, anthracene, or 4-(dicyanomethylene)-2-methyl-6-(4-dimethylaminostyryl)-4H-pyran (DCM) luminophores, respectively, and 1,4,5,8-naphthalenetetracarboxylic diimide as an electronically matched quencher. …”
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“…This could be a general route to very large molecules, and is exemplified here by the synthesis and structural characterization of a [13]rotaxane, containing 150 metal centres. Small angle X-ray scattering combined with atomistic molecular dynamics simulations demonstrate the compound is intact in solution.…”
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“…We trap the protein in the nanopore as a rotaxane-like complex using streptavidin stoppers. …”
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“…Rotaxanes are interlocked molecules in which a molecular ring is trapped on a dumbbell-shaped axle because of its inability to escape over the bulky end groups, resulting in a so-called mechanical bond. …”
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