“…The following considerations may help to guide experiments. (1) The standard Gibbs energy for the homolysis reaction RSNO → RS(•) + NO(•)(aq) is +110 ± 5 kJ mol(–1). (2) The electrode potential of the RSNO, H(+)/RSH, NO(•)(aq) couple is −0.20 ± 0.06 V at pH 7. (3) Thiol nitrosation by NO(2)(–) is favorable by 37 ± 5 kJ mol(–1) at pH 7. (4) N(2)O(3) is not involved in in vivo nitrosation mechanisms for thermodynamic — its formation from NO(2)(–) costs 59 kJ mol(–1) — or kinetic — the reaction being second-order in NO(2)(–) — reasons. (5) Hemoglobin (Hb) cannot catalyze formation of N(2)O(3), be it via the intermediacy of the reaction of Hb[FeNO(2)](2+) with NO(•) (+81 kJ mol(–1)) or reaction of Hb[FeNO](3+) with NO(2)(–) (+88 kJ mol(–1)). (6) Energetically and kinetically viable are nitrosations that involve HNO(2) or NO(•) in the presence of an electron acceptor with an electrode potential higher than −0.20 V. …”
Enlace del recurso
Enlace del recurso
Enlace del recurso

“…In this study, we used the doubly-labeled water method to measure total daily energy expenditure (kCal/day) in Hadza hunter-gatherers to test whether foragers expend more energy each day than their Western counterparts. …”
Enlace del recurso
Enlace del recurso
Enlace del recurso

“…To understand this, we use Adaptive-Poison-Boltzmann-Solver Methods along with our home-built automation to workout net as well as associated component energy terms such as desolvation energy, bridge energy and background energy for 275 salt-bridges from 20 extremely halophilic proteins. …”
Enlace del recurso
Enlace del recurso
Enlace del recurso

Enlace del recurso
Enlace del recurso

Enlace del recurso
Enlace del recurso
Enlace del recurso

“…An alteration of energy balance is the immediate cause of the so-called cachexia. …”
Enlace del recurso
Enlace del recurso
Enlace del recurso

Enlace del recurso
Enlace del recurso
Enlace del recurso

“…The energy-sparing spring theory of the foot’s arch has become central to interpretations of the foot’s mechanical function and evolution. …”
Enlace del recurso
Enlace del recurso
Enlace del recurso

“…The association between species richness and ecosystem energy availability is one of the major geographic trends in biodiversity. …”
Enlace del recurso
Enlace del recurso
Enlace del recurso

“…Detailed dynamics of the system is monitored by means of a vibrometer by observing a piece of silicon floating above the electrodes. The energy of a single event is estimated as 0.3 μJ and a significant part of this energy is transformed into mechanical work moving the piece. …”
Enlace del recurso
Enlace del recurso
Enlace del recurso

“…Furthermore, aggregation and corresponding structural order of polymer and fullerene domains result in energetic relaxations of molecular energy levels toward smaller energy gaps as compared to the situation for amorphous phases existing in homogeneously intermixed polymer:fullerene blends. …”
Enlace del recurso
Enlace del recurso
Enlace del recurso

“…Enthalpies and free energies of reaction for small neutral and charged beryllium deuterides BeD, BeD(2), and BeD(3) that have been calculated are reported for a temperature range of 0 K to 1000 K. …”
Enlace del recurso
Enlace del recurso
Enlace del recurso

“…The following papers by Richard Lieber (Skeletal Muscle as an Actuator), Thomas Roberts (Elastic Mechanisms and Muscle Function), Silvia Blemker (Skeletal Muscle has a Mind of its Own: a Computational Framework to Model the Complex Process of Muscle Adaptation) and Sabrina Lee (Muscle Properties of Spastic Muscle (Stroke and CP) are summaries of their representative contributions for the session on skeletal muscle mechanics, energetics and plasticity at the 2016 Biomechanics and Neural Control of Movement Conference (BANCOM 2016). …”
Enlace del recurso
Enlace del recurso
Enlace del recurso

“…Passivity is a fundamental concept in thermodynamics that demands a quantum system’s energy cannot be lowered by any reversible, unitary process acting on the system. …”
Enlace del recurso
Enlace del recurso
Enlace del recurso

“…An extensive computational study of the stochastic sliding process along the energetic landscapes obtained from the database shows that the funnel can significantly enhance the probability of TFs to find their target sequences when sliding in their proximity. …”
Enlace del recurso
Enlace del recurso
Enlace del recurso

“…Acryloyl based novel energetic monomers having nitro acrylates and nitro triazole acrylates were synthesized and further used for polymerization. …”
Enlace del recurso
Enlace del recurso
Enlace del recurso

“…Pyridine derivatives based on the addition of trinitromethyl functional groups were synthesized by the reaction of N(2)O(4) with the corresponding pyridinecarboxaldoximes, then they were converted into dinitromethylide hydrazinium salts. These energetic compounds were fully characterized by IR and NMR spectroscopy, elemental analysis, differential scanning calorimetry (DSC), and X-ray crystallography. …”
Enlace del recurso
Enlace del recurso
Enlace del recurso

“…Neural circuits regulating social behavior – as well as psychopathological processes – are also influenced by mitochondrial energetics. An integrative view of stress as an energy-driven process opens new opportunities to study mechanisms of adaptation and regulation across the lifespan.…”
Enlace del recurso
Enlace del recurso
Enlace del recurso

Enlace del recurso
Enlace del recurso
Enlace del recurso

“…Foraging in endothermic insects is energy-intensive and the question arises how much energy bees invest in a resource without any metabolically usable energy. …”
Enlace del recurso
Enlace del recurso
Enlace del recurso