“…Phosphenium and arsenium ions are fiercely reactive cationic species, the stabilization of which has been so far achieved in the condensed phase by dispersing the positive charge through electromeric conjugation with at least one electron‐rich substituent (frequently amido groups). Although observed in the gas phase, the isolation of dicoordinate phosphenium and arsenium ions lacking such stabilizing ligands has eluded chemists for decades. …”
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“…The Cerviray AI(®) system (AIDOT, Seoul, Korea) was used to interpret the cervical images. …”
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“…A new mononuclear Dy(iii) complex, with the formula [Dy(Hcpt)(3)]·2H(2)O (1), has been successfully prepared via self-assembly between Dy(iii) ions and 2-cyano-N′-(1-(pyridin-2-yl)amido)acetyl (Hcpt) ligand. X-ray diffraction study shows that the Dy(iii) ion is nine-coordinated by three Hcpt ligands with a tridentate chelating mode, leading to an approximately monocapped square-antiprismatic (C(4v)) geometry. …”
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“…The presence of a chelating C–N ligand combining a mesoionic carbene ligand along with an amido functionality in the Ir(III) complex is essential to attain the photocatalytic transformation. …”
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“…[Image: see text] The reaction of amido-substituted stannylenes with phospha-Wittig reagents (Me(3)PPR) results in release of hexamethyldisilazane and tethering of the resulting −CH(2)PMe(2)PR fragment to the tin center to give P-donor stabilized stannylenes featuring four-membered Sn,C,P,P heterocycles. …”
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“…Three reactor segments were chosen: stoichiometric for the hydrolysis step, kinetic for acido-aceto-methanogenesis, and equilibrium for hydrogenotrophic methane production. …”
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“…**References** [1] Tangaro at al. , Laniakea: an open solution to provide Galaxy “on-demand” instances over heterogeneous cloud infrastructures, GigaScience, Volume 9, Issue 4, April 2020, giaa033, https://doi.org/10.1093/gigascience/giaa033 [2] Salomoni, D., Campos, I., Gaido, L. et al. INDIGO-DataCloud: a Platform to Facilitate Seamless Access to E-Infrastructures. …”
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“…We did not recover significant differences in scleral appearance or irido-scleral contrast between domesticated and wild forms, suggesting that conjunctival depigmentation, unlike cutaneous pigmentation disorders, is not a general correlate of domestication. …”
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“…In this contribution we present reactivity studies of a rare example of a titanium salt, in the form of [μ(2)-K(OEt(2))](2)[(PN)(2)Ti[triple bond, length as m-dash]N](2) (1) (PN(–) = N-(2-(diisopropylphosphino)-4-methylphenyl)-2,4,6-trimethylanilide) to produce a series of imide moieties including rare examples such as methylimido, borylimido, phosphonylimido, and a parent imido. …”
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“…Goniowash is a novel surgical technique to remove pseudoexfoliation material from the irido-corneal angle to decrease intraocular pressure. …”
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“…N K-edge X-ray absorption spectroscopy performed on 3 and 4 reveals a common low-energy absorption present only for 3 and 4 (395.4 eV) that was assigned via TDDFT as an N 1s promotion into a predominantly N-localized, singly occupied orbital, akin to metal-supported iminyl complexes reported for iron. On the continuum of imido (i.e., NR(2−)) to iminyl (i.e., (2)NR(−)) formulations, the complexes are best described as Ni(II)-bound iminyl species given the N K-edge and TDDFT results. …”
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“…Management included initial observation 54.9%, iridectomy/excision biopsy 29.4%, irido-cyclectomy 7.8%, plaque radiotherapy 7.8%, proton beam radiotherapy 7.8%, and ultimately enucleation 17.6%. …”
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“…[Image: see text] The oxidation state of the redox noninnocent tetra-amido macrocyclic ligand (TAML) scaffold was recently shown to affect the formation of nitrene radical species on cobalt(III) upon reaction with PhI=NNs [ N. …”
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“…The title salt, C(14)H(14)N(3)O(4)S(2) (+)·Cl(−) [systematic name: 2-(4-hy­droxy-2-methyl-1,1-dioxo-1,2-benzo­thia­zine-3-amido)-5-methyl-1,3-thia­zol-3-ium chloride] is the hydro­chloride derivative of meloxicam, a drug used to treat pain and inflammation in rheumatic disorders and osteoarthritis. …”
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“…[Image: see text] To substitute corrosive halogen ligands, we designed and synthesized novel tungsten complexes containing amido ligands, W(DMEDA)(3) (1) and W(DEEDA)(3) (2) (DMEDA = N,N′-dimethylethylenediamido; DEEDA = N,N′-diethylethylenediamido). …”
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“…SPM and PSD differed from one another in their characteristic antigenic proteins. Comparison with amido-black stained gel blots showed that in both cases most of these did not correspond to known abundant proteins of SPM or PSDs revealed by conventional biochemical techniques. …”
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“…A facile synthesis of a highly preorganized tripodal enterobactine-type ligand 1a-H(3) consisting of a chiral C(3)-symmetric macrocyclic peptide and three tridentate 2-amido-8-hydroxyquinoline coordinating units is presented. …”
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“…The Cu(II) atoms are coordinated by one phenolate O atom, one imine N atom, one amido N atom and one carboxyl­ate O atom. The Cd(II) atom is connected via the carboxyl­ate groups, forming a heterotrinuclear Cu(II)–Cd(II)–Cu(II) system. …”
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“…The title compound, {[Cd(C(19)H(13)N(4)O(4))(2)(H(2)O)(2)]·4H(2)O}(n) or {[Cd(BBA)(2)(H(2)O)(2)]·4H(2)O}(n), where BBA is 3,5-bis­(iso­nicotin­amido)­benzoate, is isotypic with its Mn isologue [Chen et al. (2009 ▶). …”
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