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1por Goodwin, Conrad A. P., Wooles, Ashley J., Murillo, Jesse, Lu, Erli, Boronski, Josef T., Scott, Brian L., Gaunt, Andrew J., Liddle, Stephen T.“…Here, utilizing diphosphoniomethanide precursors we report the synthesis and characterization of transuranium-carbene derivatives, namely, diphosphonio-alkylidene- and N-heterocyclic carbene–neptunium(III) complexes that exhibit polarized-covalent σ(2)π(2) multiple and dative σ(2) single transuranium-carbon bond interactions, respectively. …”
Publicado 2022
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2“…The title compound, NpCuSe(2), is the first ternary neptunium transition-metal chalcogenide. It was synthesized from the elements at 873 K in an evacuated fused-silica tube. …”
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3por Chotkowski, Maciej“…Redox interaction of reduced technetium forms and technetium(VII) with neptunium(III), neptunium(IV) and neptunium(VI) have been investigated using electrochemical and spectroscopic (Vis–NIR) techniques. …”
Publicado 2018
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4por Au, Mia, Borschevsky, Anastasia, Chrysalidis, Katerina, Crosa-Rossa, Raphaël, Düllmann, Christoph, Heinke, Reinhard, Jaradat, Asar, Kaja, Magdalena, Marsh, Bruce, Moore, Iain, Raggio, Andrea, Rothe, Sebastian, Stegemann, Simon, van Eerten, Darcy, Walther, ClemensEnlace del recurso
Publicado 2022
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5por Fichter, Sebastian, Kaufmann, Sebastian, Kaden, Peter, Brunner, Tobias S., Stumpf, Thorsten, Roesky, Peter W., März, Juliane“…The synthesis of a tetravalent neptunium amidinate [NpCl((S)‐PEBA)(3)] (1) ((S)‐PEBA=(S,S)‐N,N′‐bis‐(1‐phenylethyl)‐benzamidinate) is reported. …”
Publicado 2020
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7“…Neptunium complexes in the formal oxidation states II, III, and IV supported by cyclopentadienyl ligands are explored, and significant differences between Np and U highlighted as a result. …”
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11por Jung, Alexandra, Raßbach, Anne, Pulpetta, Revathi L., van Teeseling, Muriel C. F., Heinrich, Kristina, Sobetzko, Patrick, Serrania, Javier, Becker, Anke, Thanbichler, Martin“…Here, we show that the alphaproteobacterium Hyphomonas neptunium, which proliferates by bud formation at the tip of a stalk-like cellular extension, segregates its chromosomes in a unique two-step process. …”
Publicado 2019
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12Complexation and redox chemistry of neptunium, plutonium and americium with a hydroxylaminato ligandpor Su, Jing, Cheisson, Thibault, McSkimming, Alex, Goodwin, Conrad A. P., DiMucci, Ida M., Albrecht-Schönzart, Thomas, Scott, Brian L., Batista, Enrique R., Gaunt, Andrew J., Kozimor, Stosh A., Yang, Ping, Schelter, Eric J.Enlace del recurso
Publicado 2021
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13por Krawczyk-Bärsch, Evelyn, Scheinost, Andreas C., Rossberg, André, Müller, Katharina, Bok, Frank, Hallbeck, Lotta, Lehrich, Jana, Schmeide, Katja“…The structural data obtained at the uranium L(III)-edge and the neptunium L(III)-edge indicate the formation of bidentate edge-sharing surface complexes, which are known as the main sorption species on abiotic ferrihydrite. …”
Publicado 2020
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14por Krawczyk-Bärsch, Evelyn, Scheinost, Andreas C., Rossberg, André, Müller, Katharina, Bok, Frank, Hallbeck, Lotta, Lehrich, Jana, Schmeide, KatjaEnlace del recurso
Publicado 2021
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15por Shephard, Jacob J., Berryman, Victoria E. J., Ochiai, Tatsumi, Walter, Olaf, Price, Amy N., Warren, Mark R., Arnold, Polly L., Kaltsoyannis, Nikolas, Parsons, SimonEnlace del recurso
Publicado 2022
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17por Au, M., Athanasakis-Kaklamanakis, M., Nies, L., Heinke, R., Chrysalidis, K., Köster, U., Kunz, P., Marsh, B., Mougeot, M., Schweikhard, L., Stegemann, S., Gracia, Y. Vila, Düllmann, Ch.E., Rothe, S.“…Neptunium and plutonium were laser-ionized and extracted as 30-keV ion beams. …”
Publicado 2023
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18por Husar, Richard, Dumas, Thomas, Schlegel, Michel L., Schlegel, Daniel, Guillaumont, Dominique, Solari, Pier-Lorenzo, Moisy, Philippe“…The cell design is presented together with in situ XAS measurements performed during neptunium redox reactions. Cycling experiments on the NpO(2) (2+)/NpO(2) (+) redox couple were applied to qualify the cell electrodynamics using XANES measurements and its ability to probe modifications in the neptunyl hydration shell in a 1 mol l(−1) HNO(3) solution. …”
Publicado 2022
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20por Leicht, Oliver, van Teeseling, Muriel C. F., Panis, Gaël, Reif, Celine, Wendt, Heiko, Viollier, Patrick H., Thanbichler, Martin“…We have therefore investigated CtrA regulation in the morphologically complex stalked budding alphaproteobacterium Hyphomonas neptunium. Compared to relatives dividing by binary fission, H. neptunium shows distinct changes in the role and regulation of various pathway components. …”
Publicado 2020
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