Mostrando 1 - 20 Resultados de 32 Para Buscar 'neptunismo~', tiempo de consulta: 4.54s Limitar resultados
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    “…Here, utilizing diphosphoniomethanide precursors we report the synthesis and characterization of transuranium-carbene derivatives, namely, diphosphonio-alkylidene- and N-heterocyclic carbene–neptunium(III) complexes that exhibit polarized-covalent σ(2)π(2) multiple and dative σ(2) single transuranium-carbon bond interactions, respectively. …”
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    “…The title compound, NpCuSe(2), is the first ternary neptunium transition-metal chalcogenide. It was synthesized from the elements at 873 K in an evacuated fused-silica tube. …”
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    por Chotkowski, Maciej
    Publicado 2018
    “…Redox interaction of reduced technetium forms and technetium(VII) with neptunium(III), neptunium(IV) and neptunium(VI) have been investigated using electrochemical and spectroscopic (Vis–NIR) techniques. …”
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    “…The synthesis of a tetravalent neptunium amidinate [NpCl((S)‐PEBA)(3)] (1) ((S)‐PEBA=(S,S)‐N,N′‐bis‐(1‐phenylethyl)‐benzamidinate) is reported. …”
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    “…Neptunium complexes in the formal oxidation states II, III, and IV supported by cyclopentadienyl ligands are explored, and significant differences between Np and U highlighted as a result. …”
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    “…Here, we show that the alphaproteobacterium Hyphomonas neptunium, which proliferates by bud formation at the tip of a stalk-like cellular extension, segregates its chromosomes in a unique two-step process. …”
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    “…The structural data obtained at the uranium L(III)-edge and the neptunium L(III)-edge indicate the formation of bidentate edge-sharing surface complexes, which are known as the main sorption species on abiotic ferrihydrite. …”
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    “…The cell design is presented together with in situ XAS measurements performed during neptunium redox reactions. Cycling experiments on the NpO(2) (2+)/NpO(2) (+) redox couple were applied to qualify the cell electrodynamics using XANES measurements and its ability to probe modifications in the neptunyl hydration shell in a 1 mol l(−1) HNO(3) solution. …”
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    “…We have therefore investigated CtrA regulation in the morphologically complex stalked budding alphaproteobacterium Hyphomonas neptunium. Compared to relatives dividing by binary fission, H. neptunium shows distinct changes in the role and regulation of various pathway components. …”
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