Cargando…

Mechanism of Silylation of Vinyl Arenes by Hydrodisiloxanes Driven by Stoichiometric Amounts of Sodium Triethylborohydride—A Combined DFT and Experimental Study

The reactions of vinyl arenes with hydrodisiloxanes in the presence of sodium triethylborohydride were studied using experimental and computational methods. The expected hydrosilylation products were not detected because triethylborohydrides did not exhibit the catalytic activity observed in previou...

Descripción completa

Detalles Bibliográficos
Autores principales: Nowicki, Mateusz, Zaranek, Maciej, Grzelak, Magdalena, Pawluć, Piotr, Hoffmann, Marcin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10003527/
https://www.ncbi.nlm.nih.gov/pubmed/36902355
http://dx.doi.org/10.3390/ijms24054924