An Innovative Structural Rearrangement in Imine Palladacycle Metaloligand Chemistry: From Single-Nuclear to Double-Nuclear Pseudo-Pentacoordinated Complexes

Treatment of the double nuclear complex 1a, di-μ-cloro-bis[N-(4-formylbenzylidene)cyclohexylaminato-C6, N]dipalladium, with Ph(2)PCH(2)CH(2))(2)PPh (triphos) and NH(4)PF(6) gave the single nuclear species 2a, 1-N-(cyclohexylamine)-4-N-(formyl)palladium(triphos)(hexafluorophasphate). Reaction of 2a w...

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Detalles Bibliográficos
Autores principales: al Janabi, Basma, Reigosa, Francisco, Alberdi, Gemma, Ortigueira, Juan M., Vila, José M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2023
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10005383/
https://www.ncbi.nlm.nih.gov/pubmed/36903573
http://dx.doi.org/10.3390/molecules28052328

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10005383/
https://www.ncbi.nlm.nih.gov/pubmed/36903573
http://dx.doi.org/10.3390/molecules28052328

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