Stereoselective Synthesis of 1-Substituted Homotropanones, including Natural Alkaloid (−)-Adaline

The stereocontrolled synthesis of 1-substituted homotropanones, using chiral N-tert-butanesulfinyl imines as reaction intermediates, is described. The reaction of organolithium and Grignard reagents with hydroxy Weinreb amides, chemoselective N-tert-butanesulfinyl aldimine formation from keto aldehy...

Descripción completa

Detalles Bibliográficos
Autores principales: Hernández-Ibáñez, Sandra, Sirvent, Ana, Yus, Miguel, Foubelo, Francisco
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2023
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10005508/
https://www.ncbi.nlm.nih.gov/pubmed/36903657
http://dx.doi.org/10.3390/molecules28052414

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10005508/
https://www.ncbi.nlm.nih.gov/pubmed/36903657
http://dx.doi.org/10.3390/molecules28052414

Ejemplares similares