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Stereoselective Synthesis of 1-Substituted Homotropanones, including Natural Alkaloid (−)-Adaline

The stereocontrolled synthesis of 1-substituted homotropanones, using chiral N-tert-butanesulfinyl imines as reaction intermediates, is described. The reaction of organolithium and Grignard reagents with hydroxy Weinreb amides, chemoselective N-tert-butanesulfinyl aldimine formation from keto aldehy...

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Detalles Bibliográficos
Autores principales:	Hernández-Ibáñez, Sandra, Sirvent, Ana, Yus, Miguel, Foubelo, Francisco
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	MDPI 2023
Materias:	Article
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10005508/ https://www.ncbi.nlm.nih.gov/pubmed/36903657 http://dx.doi.org/10.3390/molecules28052414

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