Iron-Catalyzed Coupling of Alkenes and Enones: Sakurai–Michael-type Conjugate Addition of Catalytic Allyliron Nucleophiles

[Image: see text] The iron-catalyzed coupling of alkenes and enones through allylic C(sp(3))–H functionalization is reported. This redox-neutral process employs a cyclopentadienyliron(II) dicarbonyl catalyst and simple alkene substrates to generate catalytic allyliron intermediates for 1,4-addition...

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Detalles Bibliográficos
Autores principales: Scrivener, Sarah G., Wang, Yidong, Wang, Yi-Ming
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10006348/
https://www.ncbi.nlm.nih.gov/pubmed/36847432
http://dx.doi.org/10.1021/acs.orglett.3c00139

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10006348/
https://www.ncbi.nlm.nih.gov/pubmed/36847432
http://dx.doi.org/10.1021/acs.orglett.3c00139

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