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Phosphazene Functionalized Silsesquioxane-Based Porous Polymer as Thermally Stable and Reusable Catalyst for Bulk Ring-Opening Polymerization of ε-Caprolactone

The bulk ring-opening polymerization (ROP) of ε-caprolactone using phosphazene-containing porous polymeric material (HPCP) has been studied at high reaction temperatures (130–150 °C). HPCP in conjunction with benzyl alcohol as an initiator induced the living ROP of ε-caprolactone, affording polyeste...

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Detalles Bibliográficos
Autores principales: Piskun, Yuliya A., Ksendzov, Evgenii A., Resko, Anastasiya V., Soldatov, Mikhail A., Timashev, Peter, Liu, Hongzhi, Vasilenko, Irina V., Kostjuk, Sergei V.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10007598/
https://www.ncbi.nlm.nih.gov/pubmed/36904533
http://dx.doi.org/10.3390/polym15051291