Formation of 3-Oxa- and 3-Thiacyclohexyne from Ring Expansion of Heterocyclic Alkylidene Carbenes: A Mechanistic Study

[Image: see text] The rearrangement pathways of two alkylidene carbenes appended to an oxa or thiacyclopentane into the corresponding heterocyclohexynes were elucidated using (13)C-labeling experiments. Both carbenes exhibited a preference for migration of the allylic carbon bound to the heteroatom....

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Detalles Bibliográficos
Autores principales: Anderson, T. E., Thamattoor, Dasan M., Phillips, David Lee
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10012261/
https://www.ncbi.nlm.nih.gov/pubmed/36856659
http://dx.doi.org/10.1021/acs.orglett.3c00042

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10012261/
https://www.ncbi.nlm.nih.gov/pubmed/36856659
http://dx.doi.org/10.1021/acs.orglett.3c00042

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