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Challenging the Kauzmann paradox using an ultra-stable perfluoropolymer glass with a fictive temperature below the dynamic VFT temperature

Ultra-stable fluoropolymer glasses were created using vacuum pyrolysis deposition that show large fictive temperature T(f) reductions relative to the glass transition temperature T(g) of the rejuvenated material. T(f) was also found to be 11.4 K below the dynamic VFT temperature T(VFT). Glass films...

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Detalles Bibliográficos
Autores principales: El Banna, Amer A., McKenna, Gregory B.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10014873/
https://www.ncbi.nlm.nih.gov/pubmed/36918591
http://dx.doi.org/10.1038/s41598-023-31074-0