Exploring Rhenium Arene Piano-Stool Chemistry with [Re(η(6)-C(6)H(6))(NCCH(3))(3)](+): A Powerful Semi-Solvated Precursor

[Image: see text] Thermal treatment of the Re(III) hydride complex [ReH(η(5)-C(6)H(7))(η(6)-C(6)H(6))](+) in CH(3)CN results in the formation of [Re(η(6)-C(6)H(6))(NCCH(3))(3)](+). This semi-solvated complex is remarkably stable under an ambient atmosphere and exhibits a fast CH(3)CN self-exchange,...

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Detalles Bibliográficos
Autores principales: Bolliger, Robin, Siebenmann, Lukas, Wolf, Emily, Ross, Megan, Meola, Giuseppe, Blacque, Olivier, Braband, Henrik, Alberto, Roger
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10015454/
https://www.ncbi.nlm.nih.gov/pubmed/36853095
http://dx.doi.org/10.1021/acs.inorgchem.2c04346

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10015454/
https://www.ncbi.nlm.nih.gov/pubmed/36853095
http://dx.doi.org/10.1021/acs.inorgchem.2c04346

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