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Gradual Donor Stabilization of a Transient Ferrocene Bridged Bisphosphanyl Phosphenium Cation

[Image: see text] A transient phosphenium cation embedded into a [3]ferrocenophane scaffold was formed via chloride abstraction. The cation has been trapped with phosphane, carbene, and silylene donors resulting in stable adducts or bond activation of the ferrocenophane bridge. In the absence of don...

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Detalles Bibliográficos
Autores principales: Franz, Roman, Szathmári, Balázs, Bruhn, Clemens, Kelemen, Zsolt, Pietschnig, Rudolf
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10015459/
https://www.ncbi.nlm.nih.gov/pubmed/36827512
http://dx.doi.org/10.1021/acs.inorgchem.3c00100