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Spin polarization assisted facile C–H activation by an S = 1 iron(iv)–bisimido complex: a comprehensive spectroscopic and theoretical investigation
High valent iron terminal imido species (Fe[double bond, length as m-dash]NR) have been shown to be key reactive intermediates in C–H functionalization. However, the detailed structure–reactivity relationship in Fe[double bond, length as m-dash]NR species derived from studies of structurally well-ch...
Autores principales: | , , , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
The Royal Society of Chemistry
2023
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10016330/ https://www.ncbi.nlm.nih.gov/pubmed/36937578 http://dx.doi.org/10.1039/d2sc06273a |