Spin polarization assisted facile C–H activation by an S = 1 iron(iv)–bisimido complex: a comprehensive spectroscopic and theoretical investigation

High valent iron terminal imido species (Fe[double bond, length as m-dash]NR) have been shown to be key reactive intermediates in C–H functionalization. However, the detailed structure–reactivity relationship in Fe[double bond, length as m-dash]NR species derived from studies of structurally well-ch...

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Detalles Bibliográficos
Autores principales: Xiong, Jin, Liu, Qing, Lavina, Barbara, Hu, Michael Y., Zhao, Jiyong, Alp, Esen E., Deng, Liang, Ye, Shengfa, Guo, Yisong
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2023
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10016330/
https://www.ncbi.nlm.nih.gov/pubmed/36937578
http://dx.doi.org/10.1039/d2sc06273a

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