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Binding of exogenous cyanide reveals new active-site states in [FeFe] hydrogenases
[FeFe] hydrogenases are highly efficient metalloenyzmes for hydrogen conversion. Their active site cofactor (the H-cluster) is composed of a canonical [4Fe-4S] cluster ([4Fe-4S](H)) linked to a unique organometallic di-iron subcluster ([2Fe](H)). In [2Fe](H) the two Fe ions are coordinated by a brid...
Autores principales: | , , , , , , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
The Royal Society of Chemistry
2023
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10016341/ https://www.ncbi.nlm.nih.gov/pubmed/36937599 http://dx.doi.org/10.1039/d2sc06098a |