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Binding of exogenous cyanide reveals new active-site states in [FeFe] hydrogenases

[FeFe] hydrogenases are highly efficient metalloenyzmes for hydrogen conversion. Their active site cofactor (the H-cluster) is composed of a canonical [4Fe-4S] cluster ([4Fe-4S](H)) linked to a unique organometallic di-iron subcluster ([2Fe](H)). In [2Fe](H) the two Fe ions are coordinated by a brid...

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Detalles Bibliográficos
Autores principales: Martini, Maria Alessandra, Bikbaev, Konstantin, Pang, Yunjie, Lorent, Christian, Wiemann, Charlotte, Breuer, Nina, Zebger, Ingo, DeBeer, Serena, Span, Ingrid, Bjornsson, Ragnar, Birrell, James A., Rodríguez-Maciá, Patricia
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10016341/
https://www.ncbi.nlm.nih.gov/pubmed/36937599
http://dx.doi.org/10.1039/d2sc06098a

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