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Structural snapshots of an Al–Cu bond-mediated transformation of terminal acetylenes
The copper(i) alumanyl derivative, [{SiN(Dipp)}Al–Cu(NHC(iPr))] (SiN(Dipp) = {CH(2)SiMe(2)NDipp}(2); Dipp = 2,6-di-isopropylphenyl; NHC(iPr) = N,N′-di-isopropyl-4,5-dimethyl-2-ylidene), reacts in a stepwise fashion with up to three equivalents of various terminal alkynes. This reactivity results in...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2023
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10016343/ https://www.ncbi.nlm.nih.gov/pubmed/36937577 http://dx.doi.org/10.1039/d3sc00240c |